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研究生: 許瀞方
Ching-Fang Hsu
論文名稱: 空氣常壓電漿於純鈦製備具生物相容有色氧化鈦薄膜之研究
Surface coloring on titanium for biocompatible titanium oxide layer via air atmospheric pressure plasma
指導教授: 郭俞麟
Yu-Lin Kuo
孫瑛穗
Ying-Sui Sun
口試委員: 張維仁
Wei-Jen Chang
何羽健
Yu-Chien Ho
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 175
中文關鍵詞: 大氣電漿氧化處理牙體植入物CIE 色彩空間生物相容性
外文關鍵詞: atmospheric pressure plasma, oxidation treatment, dental implants, CIE color space, biocompatibility
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  • 摘要 I Abstract II 目錄 III 表目錄 VI 圖目錄 VIII 第1章 緒論 1 1.1 前言 1 1.2 研究背景與目的 3 第2章 文獻回顧 5 2.1 鈦及其合金 5 2.1.1 材料介紹 5 2.1.2 材料應用 11 2.2 氧化發色處理 14 2.2.1 氧化鈦形成機制 17 2.2.2 氧化鈦之應用 21 2.2.3 濕式製程 24 2.2.4 乾式製程 29 2.3 電漿介紹 37 2.3.1 電漿種類介紹 38 2.3.2 電漿反應機制 42 2.3.3 常壓電漿之應用 43 第3章 實驗方法 49 3.1 實驗設計 49 3.2 實驗材料 50 3.3 實驗步驟 52 3.3.1 純鈦發色前處理 52 3.3.2 常壓電漿噴射束發色處理流程 52 3.3.3 生物試驗流程 54 3.4 實驗設備及原理 57 3.4.1 常壓電漿噴射束 57 3.4.2 光學放射光譜儀 59 3.5 材料分析儀器原理 61 3.5.1 色彩光譜儀 61 3.5.2 形狀分析雷射共軛焦兼白光干涉顯微鏡 63 3.5.3 水接觸角 65 3.5.4 X光繞射儀[153][154] 67 3.5.5 場發射掃描式電子顯微鏡 68 3.5.6 X射線光電子能譜儀 69 3.5.7 電化學測試分析 70 3.5.8 多功能分光光譜儀 72 第4章 結果與討論 73 4.1 溫度分析 73 4.2 光學放射光譜儀分析 75 4.3 發色處理 77 4.3.1 試片表面色彩 77 4.3.2 色度分析 80 4.4 表面形貌觀察 84 4.5 粗糙度分析 87 4.6 水接觸角量測 92 4.7 表面元素分析 103 4.7.1 Mapping 103 4.7.2 EDS 106 4.8 X光繞射儀分析 111 4.9 X射線光電子能譜儀分析 116 4.10 電化學動電位極化曲線分析 122 4.11 生物試驗 126 4.11.1 細胞貼附試驗 126 4.11.2 細胞增殖試驗 130 4.11.3 抗菌試驗 132 4.12 常壓電漿氧化機制 135 第5章 結論 137 第6章 未來展望 139 第7章 參考文獻 140 附件 154 附件1、氧化層厚度對應之顏色變化[4] 154 附件2、常見人造光源之顯色指數與色溫對照表 155 附件3、在CIE1931色度圖上之色溫表現 156 附件4、不同砂紙號數及拋光後之試片表面形貌 157 附件5、理想極化曲線示意圖[182] 158

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