研究生: |
王炫程 Hsuan-Cheng Wang |
---|---|
論文名稱: |
應用微接觸轉印技術及導電墨水製作導線於玻璃基板 Fabrication of Conductive Lines on Glass by Using Micro Contact Printing and Conductive Ink |
指導教授: |
郭俞麟
Yu-Lin Kuo |
口試委員: |
鄭逸琳
Yih-Lin Cheng 張天立 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 機械工程系 Department of Mechanical Engineering |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 120 |
中文關鍵詞: | 大氣電漿 、微接觸轉印 、奈米銀粉 、PEDOT:PSS 、石墨烯 |
外文關鍵詞: | atmospheric plasma, micro contact printing, nano silver, PEDOT: PSS, graphene |
相關次數: | 點閱:273 下載:4 |
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本論文以微接觸轉印技術及導電墨水製作導線,並搭配大氣電漿進行PDMS表面親水前處理,與微接觸轉印形成一連續製程。此轉印製程主要特色為製程單純、快速且無需昂貴設備,可直接製作無殘留層之導線於基材上。
研究發現,經由大氣電漿親水處理之PDMS表面水接觸角可由原本的110°降到約1°,藉由提高PDMS表面能可大幅改善其沾墨結果。而隨著靜置於空氣中不同時間及不同溫度下可使PDMS恢復其疏水特性,使其水接觸角提高,並藉由不同製程參數如轉印時間、溫度、壓力,可成功將奈米銀粉導線及PEDOT:PSS摻雜石墨烯導線轉印至玻璃上。實驗並利用X光光電子能譜儀分析,發現PDMS經由大氣電漿處理後表面產生了C-O和O-C=O等親水性官能基,而隨著靜置於室溫下空氣中的時間增長,所產生的親水性官能基會逐漸消失。最後,經由不同熱處理溫度及時間對銀粉進行燒結,發現當銀粉導線線寬66.9µm、厚度170.8nm、量測距離0.1cm,熱處理為200°C、40mins時,得到的電阻率為8.56x10e-6Ω・cm;而當PEDOT:PSS摻雜石墨烯導線線寬136.1µm、厚度262.2nm、量測距離0.1cm時,電阻率為2.39x10e-3Ω・cm。
This study is devoted to fabricate conductive lines by micro contact printing with conductive ink, and PDMS pre-treatment by atmospheric plasma which can be a successive process with micro contact printing. The features of this printing technology are as follow: simple, fast, no expensive equipment requirement, capable of fabricating conductive lines with no residua layer on substrate.
In the experiment, PDMS can soak inks uniformly by increasing its surface energy when surface contact angles of PDMS decrease from 110°to1°C by atmospheric plasma treatment. Besides, conductive lines made by nano silver ink and graphene embedded with PEDOT:PSS can be successfully transferred to glass substrate under different imprinting time, temperature, and pressure with hydrophobic property recovery and surface contact angles increasing of PDMS as a result from being laid in air under different aging time and temperature. Surface analyses by X-ray Photoelectron Spectroscopy was also studied and indicated that C-O and O-C=O functional groups were formed after PDMS atmospheric plasma treatment and disappeared gradually by being laid in air under different aging time. The resistivity of nano silver line with 66.9µm width, 170.8nm thickness, 0.1cm measured distance is 8.56x10e-6Ω・cm when baking temperature is 200°C and baking time is 40mins; the resistivity of graphene embedded with PEDOT: PSS line with 136.1µm width,262.2nm thickness, 0.1cm measured distance is 2.39x10e-3Ω・cm.
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