本論文研究目的為建立一結合鋰離子電池(lithium ion battery) 等效電
路及熱動態之模型。模型參數鑑別乃利用交流阻抗分析(Alternative Current
Impedance Spectroscopy,ACIS) 實驗，以最小平方法求出鋰離子電池在不同電量
狀態(State Of Charge) 與不同環境溫度下之內阻(Ri)、極化電阻(Rp)、下壓因
子()、極化電容(Cp)、擴散電容(Cd) 及擴散電阻(Rd) 之變化，建立鋰離子電
池參數模型。並以絕熱及自然散熱等實驗，鑑別出熱模型內熱容值與熱傳係數，
運用不同充放電行程，在不同溫度及SOC 下對鋰離子電池模型進行驗證，並於
各操作條件下溫度與電壓誤差皆小於0.1o C 與35mV。

The purpose of this thesis is to establish the lithium-ion equivalent circuit
model with SOC and temperature effects on its parameter. Model parameter
identification is conducted by alternative current impedance spectroscopy (ACIS)
experiment, which uses the least squares method to obtain the lithium-ion internal
resistance (Ri),Polarization resistance(R),generalized capacitive(A), depression
factor() ,diffusion capacitance (Cd) and diffusion resistance(Rd) at different
SOC and temperatures. The lithium-ion model is then validated against
experimental data under different charge/discharge cycles and thermal conditions.
Thermal dynamic model is identified by adiabatic and natural heat dissipation.
All Temperature and voltage error less than 0.1o C and 35mV.

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