由於工業與科技的發展，廢棄的溶劑與油類汙染日益增多，因此高效的油水分離材料的需求日益增加。為了降低材料在製作過程與使用後廢棄物造成的二次汙染問題，本研究使用低毒性溶劑、天然材料與可生物分解高分子製備可生物降解的特殊潤濕性油水分離材料。本研究包括兩個主題，分別描述如下：

1.米糠蠟改質棉花與其油水分離應用
米糠蠟改質棉花可以透過浸泡法簡單的改質於棉花基材表面，改質後的棉花具有空氣中疏水與穩定的油下超疏水特性，因此可應用於油水分離。米糠蠟改質棉花以透過重力以及負壓抽濾的方式分離水在油中(water-in-oil)乳化液，其重力過濾與負壓抽濾通量分別為13600 L m-2 h-1 與811000 L m-2 h-1 bar-1，且過濾後濾液的油純度皆能達到99.99 wt%以上。經過分離實驗後的米糠蠟棉花將掩埋於土壤中對其生物分解性進行探討，改質後的棉花能在四週分解30.4 wt%。

2.腰果酚改質棉花與其油水分離應用
腰果酚改質棉花能透過簡單的浸泡改質來製作，透過氫鍵作用力將聚乙烯吡咯酮烷、單寧酸與腰果酚改質於棉花基材表面，以120度高溫交聯後在棉花基材表面形成穩定的疏水化學改質層，改質後的棉花具有穩定的超疏水特性，可以重力過濾與負壓抽濾的方式分離水在油中乳化液，其重力過濾與負壓抽濾通量分別為14000 L m-2 h-1 與1350000 L m-2 h-1 bar-1，分離後的濾液油純度皆能達到99.99 wt%以上，經過分離後的腰果酚改質棉花將掩埋於土壤中對其生物分解性進行探討，改質後的棉花能在四週分解22.8 wt%。
(兩個研究中皆以Span 80為界面活性劑來配置水在油中乳化液)

Abstract
Oily pollutions were growing due to the development of technology. Taking environmental protection as consideration, we prepared biodegradable superwetting material for oil/water separation by using low toxic solvent and natural ingredients. This study includes two subjects and describes as follows, respectively:
1. Preparation of Rice-Bran-Wax modified cotton for emulsion separations.
We prepared rice bran wax modified cotton through a simple dip-coating process. As-prepared rice bran wax modified cotton possessed hydrophobicity and under-oil-superhydrophobicity. It can be used for separating water-in-oil emulsions with high fluxes of 13600 L m-2 h-1 and 811000 L m-2 h-1 bar-1 via gravity-driven and pressure-driven processes, respectively. The oil purity of all filtrates was greater than 99.99 wt%. The rice bran wax modified cotton also showed well biodegradability. The rice bran wax modified cotton reached 30.4 % degradation during the fourth week.

2. Preparation of polyvinylpyrrolidone (PVP)/tannic acid (TA)/Cardanol coated cotton for emulsion separations.
Cardanol is a mainly waste from cashew industrial. We prepared superhydrophobic cotton composite from PVP, TA, Cardanol, and cotton. As-prepared material can be used for separate water-in-oil emulsion with extremely high fluxes of 14000 L m-2 h-1 and 1350000 L m-2 h-1 bar-1via gravity-driven and pressure-driven processes, respectively. The oil purity of all filtrates was greater than 99.99 wt%. The rice bran wax modified cotton also exhibited good biodegradability. The superhydrophobic cotton composite reached 22.8 % degradation during the fourth week.
(Span 80 was used as the surfactant to prepare water-in-oil emulsions)

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