本論文主要探討含有2, 6位置蒽或三蝶烯和兩種不同構型的四苯乙烯、三苯胺或二苯酮之高分子的合成及性質與鑑定。以鈴木偶合反應做為高分子聚合反應。通過紫外可見吸收光譜和光致發光光譜對高分子進行分析，表明蒽和三蝶烯分別與不同構型的四苯乙烯聚合的四種高分子呈現不同程度的聚集誘導發光特性。而且因為蒽和三蝶烯的平面和立體的特性，他們和不同構型的四苯乙烯聚合所呈現的高分子量子產率的比較是相反的。透過差示掃描量熱儀、熱重分析證明所有不含三苯胺和二苯酮之高分子均表現出良好的熱穩定性，並利用循環伏安法以及原子力顯微鏡對聚合物薄膜進行電化學性質和形貌之分析。

This thesis investigates the synthesis, properties, and characterization of polymers containing 2,6-anthracene or 2,6-triptycene and two different configurations of tetraphenylethylene, triphenylamine, or benzophenone. The polymer was coupling through Suzuki coupling reaction. Analysis of the polymers through UV-visible absorption spectroscopy and photoluminescence spectroscopy revealed that the four polymer combinations of anthracene and tetraphenylethylene with different configurations of triptycene exhibited varying degrees of aggregation-induced emission effects. Moreover, due to the planar and steric characteristics of anthracene and triptycene, their comparisons of polymer quantum yields with different configurations tetraphenylethylene showed opposite trends. Differential scanning calorimetry and thermogravimetric analysis demonstrated excellent thermal stability for all copolymers without triphenylamine and benzophenone. The electrochemical properties and morphology of the polymer films were analyzed using cyclic voltammetry and atomic force microscopy.

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