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研究生: 李箕峯
Chi-feng Lee
論文名稱: 以線上光學監控技術量測與分析準分子雷射退火之低溫多晶矽製程參數研究
Investigation of Low Temperature Poly Silicon Analysis Process Parameter during Excimer Laser Annealing Using In-situ Time-Resolved Optical Reflection and Transmission Measurement
指導教授: 鄭正元
Jeng-Ywan Jeng
口試委員: 葉文昌
Wen-chang Yeh
吳忠幟
Chung-Chih Wu
雷添壽
Tien-Shou Lei
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 89
中文關鍵詞: 低溫多晶矽線上光學監控技術準分子雷射退火
外文關鍵詞: excimer laser annealing, in-situ time-resolved measurement, low temperature poly silicon
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  • 本研究運用準分子雷射退火矽膜再結晶特性之線上光學雙檢測雷射系統即時檢測出非晶矽薄膜於準分子雷射退火期間反射率與穿透率之變異性,進而分析相關物理現象和量測矽膜融化時間;此外本研究亦改變矽膜厚度和基板預熱溫度,以分析不同參數對於矽膜再結晶特性之影響性。研究結果發現,矽膜融化時間會隨著準分子雷射能量密度、矽膜厚度、預熱溫度的增加而增長,同時晶粒尺寸亦隨之而變大可達2 μm。由兩種厚度的晶粒尺寸比較,晶粒尺寸相同而矽膜融化時間卻不同,因為不同矽膜厚度會有不同的再結晶機制,由此得知可由線上光學檢測系統得以預知矽膜融化時間,但晶粒尺寸判斷須將矽膜厚度與矽膜融化時間搭配。線上光學檢測系統能夠理解準分子雷射矽膜之再結晶機制和量測矽膜融化時間,因此可以容易製作大粒徑之多晶矽以及提高低溫多晶矽之製程良率。


    An in-situ real-time time-resolved optical reflectivity and transmissi vity (TRORT) monitoring system combining two CW He-Ne laser, a fast digital oscilloscope and three photodiodes is developed for monitoring the melt-phase duration and examine the melting and crystallization behavior during XeF excimer laser annealing(ELA) in this study.
    Using different thickness of a-Si films and preheat temperature during XeF excimer laser annealing. The melt-phase duration to be extend, while thickness of a-Si films, preheat temperature and laser annealing fluence be increased. At the same time the grain size will increase to 2 μm. The grain size measurement of two kinds of thickness is compared, the grain size is the same and the silicon is different in melt-phase duration. Because different thickness of a-Si films will have different crystallization mechanisms. The grain size is judged must match in melt-phase duration and thickness of a-Si films.
    Using two probe lasers TRORT system can examine the melting and crystallization behavior, and measure the melt-phase duration. This technique provides a simple approach for fabrication large-grained poly-Si during ELA and enhances the high yield during in-line large area flat panel displays fabrication using poly-Si TFTs.

    中文摘要 I 英文摘要 II 誌謝 III 目錄 IV 圖索引 VI 表索引 X 第一章 緒論 1 1.1 前言 1 1.2 研究背景與目的 2 第二章 文獻探討 5 2.1 Excimer Laser Crystallization(ELC) 6 2.1.1表面粗糙度效應 8 2.2 線上光學檢測技術 9 2.2.1 Time-Resolved Optical Transmission(TROT), Time-Resolved Optical Reflection(TROR)10 2.2.2 Backside TROR 10 2.2.3 TROT/TROR相關應用 11 2.3 預熱溫度於液態矽膜結晶之影響 16 2.4 不同矽膜厚度於液態矽膜結晶之影響 18 2.5 薄膜沉積技術與提高性能之處理 19 2.6 試片分析 23 2.6.1掃描式電子顯微鏡分析 23 2.6.2 拉曼光譜分析 24 2.6.3 原子力顯微鏡分析 26 第三章 準分子雷射退火之線上光學檢測系統之改善 29 3.1 數位示波器 30 3.2 檢測光源 32 3.3 光感測器 33 3.4 加熱系統 35 3.5 線上光學檢測系統 37 第四章 實驗流程 39 4.1 退火試片準備 39 4.1.1玻璃基板清洗 39 4.1.2 PECVD for a-Si 41 4.1.3 PECVD for SiO2 42 4.1.4 Sputtering for a-Si 43 4.1.5 退火(Annealing) 45 4.2 準分子雷射退火流程 46 4.3 試片分析之實驗過程 51 4.3.1 掃描式電子顯微鏡分析 51 4.3.2 原子力顯微鏡分析 52 4.3.3 拉曼光譜分析 53 第五章 實驗結果54 5.1 雙檢測光源雷射波形訊號探討 54 5.2 不同膜厚對融化時間之影響 63 5.3 不同預熱溫度對融化時間之影響 66 5.4 膜厚、預熱溫度和融化時間之關係 72 5.5 退火試片分析74 5.5.1 SEM 74 5.5.2 Raman 78 5.5.3 AFM 80 5.6 結果討論 82 第六章 結論與未來研究方向83 6.1 結論 83 6.2 未來研究方向 85 參考文獻 86

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