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研究生: 陳玉峰
Chen-Yu-Feng
論文名稱: 綜合式開採甲烷水合物之動態行為研究
Dynamic Behavior Study on the Recovery of Methane Hydrate with Combined Methods
指導教授: 李明哲
Ming-Jer Lee
口試委員: 翁文爐
Wen-Lu Weng
林祥泰
Shiang-Tai Lin
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 143
中文關鍵詞: 甲烷水合物
外文關鍵詞: Methane Hydrate
相關次數: 點閱:175下載:2
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本研究建立的一套具有可視窗高壓設備(高壓釜內部體積約為1.6 L)以探討綜合式開採甲烷水合物過程的動態變化行為。本研究探討在不同介質(純水或海水)中,灌注二氧化碳後甲烷水合物融解與被二氧化碳置換之動態行為,在實驗過程中記錄高壓釜內各時間點溫度與壓力分布變化,釋放氣體中之組成,以及釋放總體積等資料。此外,我們也探討以兩種綜合式開採甲烷水合物的動態行為,其中包括二氧化碳置換結合降壓法和降壓法結合熱刺激,所有之動態數據均全程紀錄。這些實驗數據可用於驗證電腦模擬(如CMG-STARS)之結果。


A visual high-pressure apparatus, with internal volume of 1.6 L, was installed in the present study to investigate dynamic behavior of recovery of methane hydrate with combined methods. This study investigates the dynamic behavior of methane hydrate decomposition and replacement by carbon dioxide injection in different media (pure water or seawater). The temperature responses at different positions, compositions and pressure of released gas mixtures, and total volume of released gas varying with time were collected during the experimental course. We also investigate the dynamic behavior of methane gas production with two combined methods. Those methods include carbon dioxide replacement with depressurization and depressurization with thermal stimulation. All the dynamic data were recorded during the whole experimeatal period. Those experimental data can be provided to verify the simulation results from computer simulators such as CMG-STARS.

致謝 I 摘要 II Abstract III 目錄 IV 表目錄 VII 圖目錄 IX 第一章 緒論 1 1.1前言 1 1.2氣體水合物 5 1.3二氧化碳封存與置換 7 1.4 綜合式開採甲烷水合物 8 1.5文獻回顧 10 1.6本研究重點 12 第二章 甲烷水合物之動態實驗 20 2.1儀器設備 20 2.2氣體水合物實驗裝置 21 2.3實驗藥品 22 2.4實驗步驟 23 2.4.1氣體水合物形成實驗 23 2.4.2二氧化碳置換甲烷水合物之操作 24 2.4.3 綜合式開採甲烷水合物實驗之操作 26 2.5實驗規劃 28 第三章 氣體水合物之形成與相飽和度計算 37 3.1甲烷水合物形成之動態行為觀察 37 3.2相飽和度之計算 37 第四章 二氧化碳置換甲烷水合物之動態行為觀察 48 4.1在279 K下於純水介質中以二氧化碳浸泡週期18 h置換甲烷水合物 48 4.2在279 K下於純水介質中以二氧化碳浸泡週期12 h置換甲烷水合物 50 4.3在279 K於純水介質中以二氧化碳浸泡週期1 h置換甲烷水合物 52 4.4在279 K下於海水介質中以二氧化碳浸泡週期1h置換甲烷水合物 53 4.5在277 K下於海水介質中以二氧化碳浸泡週期1 h置換甲烷水合物 55 4.6在275 K下於海水介質中以二氧化碳浸泡週期1 h置換甲烷水合物 56 4.7置換效率 57 第五章 綜合式開採甲烷水合物之動態行為觀察 84 5.1於海水介質二氧化碳置換法結合減壓法 84 5.2於海水介質降壓法結合熱刺激法 87 5.2.1對照組(降壓法) 87 5.2.1 277 K下降壓法結合海水注射法 88 5.2.3 284 K下降壓法結合海水注射法 93 5.3降壓結合熱刺激法融解甲烷水合物綜合比較 98 第六章 結論與建議 135 6.1結論 135 6.2建議 136 參考文獻 137 符號說明 142

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