應用Fuller 級配曲線探討水泥基質材料之巨微觀性質

研 究 生：謝素蘭
指導教授：黃兆龍 博士
時 間：97年12月

論文摘要

自從全球積極限制CO2的排放量，以降低大氣層暖化衝擊的熱潮下，水泥基質材料必須降低水泥用量，同時提高耐久性，使工程結構能符合世界發展趨勢，達到永續綠建材的目標。本文主要應用Fuller級配曲線模擬水泥基質材料之固體顆粒緻密堆積分佈曲線，以求得最少空隙量Vv，並設計不同膠結漿質與量之水泥基質材料，分別量測工作性、單位重及水化熱等新拌性質，抗壓強度、水泥強度效益、超音波速、表面電阻、氯離子電滲量和硫酸鹽侵蝕等硬固性質，以及SEM、MIP和3D立體表面結構等微觀結構，藉以探討水泥基質材料巨微觀性質。試驗結果顯示，水泥基質材料可藉由強塑劑之用量而改變其工作性；而Fuller級配曲線配比模式設計之水泥基質材料，膠結漿質愈佳，水泥裹漿厚度愈厚時，混凝土早期強度愈高，但晚期強度反而水泥漿用量越少，其硬固性質愈佳。在相同膠結漿「質」條件下，水泥強度效益優於ACI設計法約2.55倍以上，氯離子電滲量低約2.94~7.15倍；耐久性指摽試驗中，則顯示固體粒料堆積愈緻密，膠結料組成愈多，表面電阻及抵抗氯離子滲透能力較佳。

關鍵字：Fuller級配曲線配比模式, 水泥基質材料, 膠結漿質, 裹漿厚度, 耐久性

The study on macro-micro property of cementitious material by used Fuller’s gradation curve

Graduate Student: Su-Lan Hsieh
Thesis Advisor: Chao-Lung Hwang

Abstract

Since global consideration of CO2 emission, energy conservation and structure sustainability, the concrete design nowadays should both reduce the cement content and improve durability. This paper mainly discussed the macro-micro properties of cementitious material. The Fuller’s gradation curve is applied to enable fully packing with all solid particles. Then, the least void volume of paste (Vv) can be obtained. Mixtures with cementitious material of different quality and quantity were designed. Such fresh properties as workability, unit weight and heat of hydration were measured, while harded properties included compressive strength, the strength efficiency of cement, pulse velocity, electrical resistivity, chloride ion permeability and sulfate attack were also measured. SEM, MIP and 3D microscopy were analysied. The results show as the workability of cementitious material will be flowable by simply using SP. Under the same w/b and age, if no imperfection is involved, compressive strength, ultrasonic pulse velocity, electrical resistance, and Chloride Penetration are linear proportion to the coating thickness, and the thinner the coating thickness the better the performance of concrete is specified. Compares in the ACI method, the fuller’s ideal curve method surpasses ACI design of strength efficiency of cement benefit approximately 2.55 above times law, and would reduce the chloride ion permeability of HPC up to about 2.94~7.15 times. Concrete specimens with optimal paste thicknesses are experimented to seek explanations for problems of concrete, if the coating thickness on aggregate is decreased, the durability is increased, such as electrical resistivity, chloride ion permeability and sulfate attack.

Keyword: Fuller’s gradation curve , Cementious material, Cementitious quantity , Coating thickness, Durability

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