摘 要
噴射式大氣電漿近年來已廣泛應用於各種產業，本研究主要聚焦於將噴射式大氣電漿運用在製鞋產業各種相關材料的表面處理，藉由噴射式大氣電漿的材料表面清潔與改質特性，期望達到各類高分子聚合物鞋材之間的貼合面清潔，提升表面能與親水性，活化材料表面並以增加親水性官能基達到以水性塗膠完成高分子聚合物鞋材之間鍵結貼合為目的。
本研究中以噴射式大氣電漿透過不同頻率與掃描次數，並且分別以接觸角量測儀分析材料表面性能之變化與時效，場發射掃描式電子顯微鏡觀察材料表面的形貌改變程度，光學放射頻譜儀分析不同電漿參數下所產生的物種含量，並以感溫試紙模擬材料表面在不同電漿參數下的受溫情況，藉由以上的觀察與測試數據交叉比對證明使用噴射式大氣電漿於鞋材表面處理的實質成果與效益。
除此之外，在實驗結果中呈現出，除了電漿源輸出功率，電漿掃描距離，掃描速度與掃描次數之外，直流式噴射電漿電源輸出頻率的改變更會直接影響高分子材料在表面處理上的表現結果，說明了可變的電漿源輸出頻率對於高分子材料處理的重要性。
期望藉由本研究做為產業推廣的起始點，將諸多傳統產業與高分子聚合物應用相關產業製程中大量的有機溶劑使用量減低或取代，以藉此提升產業製程工業安全性與友善我們的生活環境做努力。

關鍵詞：高分子聚合物鞋材、噴射式大氣電漿、變頻電漿電源、表面極性、親水性

Abstract
Atmospheric pressure plasma jet (APPJ) has been widely used in various industries in recent years. This research focuses on the application of Atmospheric plasma jet to the surface treatment of various related materials in the footwear industry. Due to the characteristics and qualities of Atmospheric plasma jet Surface modification and cleaning to achieve all kinds of the polymer shoes material, also can improve surface energy and hydrophilicity, activate the surface of the material and increase the hydrophilic functional group to achieve purpose for the bonding between polymer materials with water-based adhesives.
In this study, atmospheric pressure plasma jet by different frequencies and scanning circles, The surface properties of the materials are analyzed by the contact angle measuring instrument, field emission scanning electron microscope (FE-SEM) is used to observe surface morphology change on the material, and the instrument analyzes the species content produced under different plasma parameters by optical emission spectroscopy (OES), Simulates the temperature condition of the material surface under different plasma parameters with the temperature sensitive test paper. Otherwise, in these results, in addition to the plasma source output power, plasma scanning distance, scanning speed and scanning times, the change of the output frequency of the DC plasma power supply will directly affect the performance of the polymer material in surface treatment. As a result, the importance of variable plasma source output frequency for polymer material processing is illustrated. Thru the cross-comparison of the above observation and test data proves the use of atmospheric plasma jet is the substantial results and benefits of surface treatment of shoe materials and industry.
It is hoped that, By this research will be used as a starting point for industrial promotion, and the use lot of organic solvents in the industrial processes related to many traditional industries and high polymer applications will be reduced or replaced, thereby enhancing the safety of industrial process industries and friendly to living environment of ours.

Keywords: Polymer shoe material, Atmospheric pressure plasma jet, Frequency conversion plasma power supply, Surface energy, Hydrophilic

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