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研究生： 王予均
Yu-Chun Wang
論文名稱： 開發具生物相容性、高彈性與壓電性之3D列印光固化樹脂
Development of Biocompatible, Flexible and Piezoelectric Photo-Resin for 3D Printing
指導教授： 何明樺
Ming-Hua Ho
口試委員: 陳崇賢
Chorng-Shyan Chern
高震宇
Chen-Yu Kao
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 190
中文關鍵詞： 3D列印光固化樹脂 、生物相容性樹脂 、壓電性樹脂 、高彈性樹脂
外文關鍵詞： digital light processing (DLP), photopolymer, 3-dimensional printing, flexibility
相關次數： 點閱：223  下載：0 
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    • 摘要 I Abstract II 致謝 IV 目錄 V 圖目錄 XI 表目錄 XX 方程式目錄 XXII 專有名詞縮寫 XXIII 第一章 緒論 1 第二章 文獻回顧 3 2.1 積層製造技術介紹 3 2.1.1 積層製造於生醫領域應用優勢 3 2.1.2 積層製造技術分類 4 2.2 光聚合固化技術介紹 7 2.2.1 光固化系統成型機制 7 2.2.2 光固化聚合技術應用機台介紹 8 2.3 光固化樹脂的主要成分 10 2.3.1 寡聚體 11 2.3.2 反應型稀釋劑單體 14 2.3.3 光起始劑 16 2.3.4 功能性添加劑 18 2.4 調控光固化樹脂機械性質之參數 19 2.4.1 玻璃轉移溫度對機械性質之影響 20 2.4.2 分子鏈中交聯密度對材料機械性質之影響 22 2.4.3 微結構軟/硬端比例對機械性質之影響 23 2.5 壓電性光固化複合材料介紹 24 2.5.1 PVDF壓電特性介紹 25 3 第三章 實驗材料與方法 27 3.1 實驗藥品 27 3.2 實驗儀器 29 3.3 實驗步驟 31 3.3.1 光反應型寡聚體的改質 32 3.3.2 光固化樹脂配方系統 32 3.4 光固化材料鑑定與性質檢測 33 3.4.1 黏度測試 33 3.4.2 拉伸試驗 33 3.4.3 靜態降解重量損失測試 35 3.4.4 傅立葉轉換紅外線光譜儀(FTIR)分析 36 3.4.5 多功能固體密度測量儀 37 3.4.6 耐磨耗試驗分析 38 3.4.7 耐候試驗測試 39 3.5 結構孔洞化與壓縮變形量檢測 40 3.5.1 壓縮測試 40 3.5.2 孔洞結構列印參數調整 41 3.6 含石墨烯之光固化型薄膜分散性與壓電性質分析 42 3.6.1 高功率X光繞射儀(XRD)分析 42 3.6.2 壓電訊號反覆敲擊試驗 42 3.6.3 百格測試接面附著度 42 3.7 體外細胞測試 44 3.7.1 光固化材料試片製作 44 3.7.2 生物相容性檢測方式與操作 44 3.7.3 細胞來源 46 3.7.4 細胞培養 47 3.7.5 細胞冷凍保存 48 3.7.6 細胞解凍及培養 48 3.7.7 細胞計數 49 3.7.8 粒線體活性測試 51 4 第四章 結果與討論 54 4.1 光固化樹脂流變性質分析 54 4.1.1 反應型稀釋劑對樹脂流變性之影響 54 4.1.2 溫度對不同寡聚體的流變性之影響 57 4.2 樹脂的配方設計與機械性質調控 59 4.2.1 聚合物結構對機械性質影響 59 4.2.2 聚合物分子量對機械性質影響 63 4.2.3 稀釋單體玻璃轉移溫度對機械性質影響 65 4.2.4 循環拉伸試驗測定回復性 76 4.2.5 機械漸進性質的光固化樹脂系統調控 78 4.2.6 固化時間對機械性質影響 81 4.2.7 光固化樹脂表面硬度 84 4.3 材料的體積收縮率與列印精準度分析 86 4.3.1 稀釋單體結構和體積收縮率的相關性 86 4.3.2 無機粒子添加劑對體積收縮率的影響 90 4.4 材料的孔洞輕量化與變形量分析 95 4.4.1 聚合物機械性質與壓縮應變關係 95 4.4.2 材料孔隙率對與壓縮性質影響 97 4.5 傅立葉轉換紅外光譜儀轉化率分析 100 4.5.1 稀釋單體對轉化率的影響 101 4.5.2 寡聚體分子結構對轉化率之影響 105 4.6 光固化樹脂材料親疏水性分析 110 4.6.1 反應型稀釋劑化學結構對親疏水性影響 110 4.6.2 寡聚體化學結構對親疏水性影響 113 4.7 聚合物的降解性質 115 4.7.1 寡聚體不同化學結構的降解性質 116 4.7.2 不同單體稀釋劑的降解性質 118 4.7.3 光固化樹脂老化機械性質測試 120 4.7.4 光固化樹脂耐磨性質測試 124 4.8 含石墨烯之柔性3D列印複合材料 127 4.8.1 石墨烯於樹脂中流變性質比較 127 4.8.2 含石墨烯之光固化型薄膜之XRD結晶型態分析 128 4.8.3 界面整合百格測試 131 4.8.4 壓電層於不同衝量下的電訊號質比較 133 4.9 材料生物性質檢測 135 4.9.1 寡聚體化學結構對生物相容性的影響 136 4.9.2 反應型單體對生物相容性之影響 137 4.9.3 壓電性光固化樹脂生物相容性檢測 140 4.10 光固化樹脂商業化應用 142 第五章 結論 143 參考文獻 145

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