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研究生: Kukuh Wicaksono
Kukuh Wicaksono
論文名稱: Effect of NH2 Doping in Carbon Dots on Singlet Oxygen Generation
Effect of NH2 Doping in Carbon Dots on Singlet Oxygen Generation
指導教授: 今榮東洋子
Toyoko Imae
口試委員: 氏原真樹
Masaki Ujihara
鄭智嘉
Chih Chia Cheng
學位類別: 碩士
Master
系所名稱: 應用科技學院 - 應用科技研究所
Graduate Institute of Applied Science and Technology
論文出版年: 2018
畢業學年度: 106
語文別: 英文
論文頁數: 52
中文關鍵詞: Carbon DotsSinglet OxygenAnthracene
外文關鍵詞: Carbon Dots, Singlet Oxygen, Anthracene
相關次數: 點閱:274下載:1
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  • 比例變化的碳點通過水熱過程產生具NH2。透射電子顯微鏡圖像和X 射線衍射分
    析給出了碳點具有量子點尺寸和無定形結構的信息。
    紅外吸收光譜和X 射線光電子能譜分析證實,碳點具有石墨和脂肪族碳以及羧基
    和胺基團的官能團。紫外-可見光譜和熒光光譜表明,碳點在340nm 處有一個激發
    帶,再440nm 處有一個發射帶。由於參雜NH2 的碳點具有優異的強度和量子產率,
    量子產量隨著NH2 含量的增加而增加。另外,單線態氧產生從碳點被檢驗出來。


    Carbon dots with variation of NH2 ratio doped was produced by hydrothermal
    procedure. Transmission electron microscopic images and X-ray diffraction analyses
    gave the information that carbon dots had a quantum dot size and the amorphous
    structure. Infrared absorption spectra and X-ray photoelectron spectroscopic analyses
    confirmed that carbon dots had functional groups of graphitic and aliphatic carbon and
    carboxyl and amine groups. Ultraviolet-visible and fluorescence spectra showed that
    carbon dots had an excitation band at 340 nm and an emission band at 440 nm. Carbon
    dots had excellent intensities and quantum yields due to doped NH2. Quantum yields
    increased with increasing NH2 content. Additionally, singlet oxygen generation from
    carbon dots was examined.

    Abstract .......................................................................................................................... i 摘要 ............................................................................................................................... ii Table of Contents ........................................................................................................... iii List of Figures ................................................................................................................ v List of Tables ................................................................................................................. viii Chapter 1-General Introduction ..................................................................................... 1 1.1. Introduction ............................................................................................................ 1 1.1.1 Photodynamic therapy (PDT) ............................................................................... 1 1.1.2 Carbon dots ........................................................................................................... 4 1.1.3 Singlet Oxygen ..................................................................................................... 7 1.1.4 Anthracene ............................................................................................................ 9 1.2. Motivation and Objective of the work .................................................................... 10 Chapter 2-Experimental Section .................................................................................... 11 2.1 Material and Reagents ............................................................................................. 11 2.2 Instruments .............................................................................................................. 11 2.3 Experimental procedure ........................................................................................... 12 2.3.1 Synthesis of carbon dots ....................................................................................... 12 2.3.2 Measurement of fluorescence quantum yield ....................................................... 13 2.2.3 Detection of singlet oxygen generation ............................................................... 14 Chapter 3-Results and Discussion ................................................................................. 17 3.1 Characterization of carbon dots ............................................................................... 17 3.1.1 UV-vis absorption spectra .................................................................................... 17 3.1.2 Fluorescence spectra ............................................................................................. 18 3.1.3 Infrared absorption spectra ................................................................................... 25 3.1.4 HRTEM images .................................................................................................... 26 3.1.5 X-Ray Diffraction (XRD) analysis ....................................................................... 27 3.1.6 X-Ray Photoelectron Spectroscopy (XPS) analysis ............................................. 28 3.2 Quantum yield measurement ................................................................................... 33 3.3 Singlet oxygen generation ....................................................................................... 36 3.3.1 Timescan Measurement ........................................................................................ 36 3.3.2 Singlet Oxygen Generation .................................................................................. 38 Chapter 4-Summary and Conclusion ............................................................................. 46 List of References .......................................................................................................... 48

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