甲酸反應蒸餾製程之不同熱整合設計研究｜國立臺灣科技大學博碩士論文系統

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研究生：	沈惠麗 Felicia - Januarlia Novita
論文名稱：	甲酸反應蒸餾製程之不同熱整合設計研究 Heat-Integrated Design of Formic Acid Production via Reactive Distillation Configuration
指導教授：	李豪業 Hao-Yeh Lee
口試委員:	李明哲 Ming-Jer Lee 王聖潔 San-Jang Wang
學位類別：	碩士 Master
系所名稱：	工程學院 - 化學工程系 Department of Chemical Engineering
論文出版年：	2013
畢業學年度：	101
語文別：	英文
論文頁數：	132
中文關鍵詞：	heat-integrated 、formic acid production 、reactive distillation 、thermally coupled 、external heat integration
外文關鍵詞：	heat-integrated, formic acid production, reactive distillation, thermally coupled, external heat integration
相關次數：	點閱：213 下載：7
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上一筆

The heat-integrated design of formic acid production via reactive distillation (RD) configuration will be investigated in this thesis. The design for this process refers to Huang’s process and it is optimized to obtain a better process design that has the minimum total energy. Later on, design which is optimized will be used as reference by the other configuration to reduce the “remixing effects” phenomena which may occur. The first approach is the thermally coupled configuration. As the results, the “remixing effects” can be reduced and minimum total energy less than the base case and optimization design can also be achieved. This research also investigates another heat-integrated method. It is external heat integration which uses the heat of top distillate vapor in one column to transfer the heat to side heater and/or to the reboiler of another column. The results for this method are better than the thermally coupled one because the total energy can be further reduced compared to thermally coupled design.

ABSTRACT	i
ACKNOWLEDGEMENT	iii
TABLE OF CONTENTS	v
LIST OF FIGURES	vii
LIST OF TABLES	xiii
Chapter 1 INTRODUCTION	1
1.1 Background	1
1.2 Literature Survey	6
1.2.1 Carbonylation Process and Hydrolysis Process	6
1.2.2 Process flowsheets in Previous Research	10
1.3 Motivation of This Work	19
1.4 Organization of This Thesis	20
Chapter 2 INFORMATION NEEDED IN THE PROCESS SIMULATION AND ANALYSIS	21
2.1 Thermodynamic Properties	21
2.1.1 Vapor Liquid Equilibrium	21
2.1.2 Residue Curve Map (RCM)	28
2.2 Kinetic Model	30
Chapter 3 BASE CASE AND OPTIMIZATION DESIGN	33
3.1 Base Case Configuration	33
3.1.1 Formic Acid 85 wt% Base Case	33
3.1.2 Formic Acid 99 wt% Base Case	42
3.2 Optimization of RD Configuration	49
3.2.1 Formic Acid 85 wt% Optimization Design	53
3.2.2 Formic Acid 99 wt% Optimization Design	59
Chapter 4 THERMALLY COUPLED CONFIGURATION AND EXTERNAL HEAT INTEGRATION	67
4.1 Thermally Coupled Configuration	67
4.1.1 Formic Acid 85 wt% Thermally Coupled Configuration	70
4.1.2 Formic Acid 99 wt% Thermally Coupled Configuration	75
4.2 External Heat Integration	82
4.2.1 Formic Acid 85 wt% External Heat Integration	85
4.2.2 Formic Acid 99 wt% External Heat Integration	93
Chapter 5 CONCLUSIONS	103
REFERENCES	105

                                

1) Agrawal, R.; Fidkowski, Z. T., Are Thermally Coupled Distillation Columns Always Thermodynamically More Efficient for Ternary Distillations?, Ind. Eng. Chem. Res., 1998, 37, 3444 - 3454.
2) Avila, J. R. A.; Hasebe, S., New Synthesis Procedure to Find the Optimal Distillation Sequence with Internal and External Heat Integrations, Ind. Eng. Chem. Res., 2013, 52, 4851 - 4862.
3) Bai, L.; Zhao, Y.; Hu, Y.; Zhong, B.; Peng, S., Kinetics of the Carbonylation of Methanol in a Mechanically Agitated Reactor, J. of Nat. Gas Chem., 1996, 5 (3), 229 - 236.
4) Bezenehtak, K.; Combes, G.; Dehghani, F.; Foster, N.; Tomasko, D., Vapor-Liquid Equilibrium for Binary Systems of Carbon Dioxide + Methanol, Hydrogen + Methanol, and Hydrogen + Carbon Dioxide at High Pressures, J. Chem. Eng. Data., 2002, 47, 161 - 168.
5) Caballero, J. A., Thermally Coupled Distillation, 10th International Symposium on Process Systems Engineering - PSE2009., 2009, 59 - 64.
6) Doherty, M.; Perkins, J., On the Dynamics of Distillation Process. I. The Simple Distilation of Multicomponent Non - Reacting, Homogeneous Liquid Mixtures, Chem. Eng. Sci., 1978, 33, 359 - 578.
7) Dunnebier, G.; Pantelides, C., Optimal Design of Thermally Coupled Distillation Columns, Ind. Eng. Chem. Res., 1999, 38, 162 - 176.
8) En.wikipedia.org, 2009., Formic acid - Wikipedia, the free encyclopedia. [online] Available at http://en.wikipedia.org/wiki/Formic_acid.
9) Fidkowski, Z.; Krolikowski, L., Thermally Coupled System of Distillation Columns; Optimization Procedure, AIChE J., 1986, 32 (4), 537 - 546.
10) Gadalla, M. A., Internal Heat Integrated Distillation Columns (iHIDiCs) - New Systematic Design Methodology, Chem. Eng. Res. Des., 2009, 87, 1658 - 1666.
11) Harwardt, A.; Marquardt, W., Heat-Integrated Distillation Columns : Vapor Recompression or Internal Heat Integration?, AIChE J., 2012, 58 (12), 3740 – 3750.
12) Hirata, K., Heat Integration of Distillation Column, Chemical Engineering Transactions., 2009, 18, 39 - 44 (DOI : 10.3303/CET0918004).
13) Huang, H. P.; Lee, M. J.; Lee, H. Y.; Chen, J. H., Formic Acid Manufacturing System and Method of Manufacturing Formic Acid, Patent Application Publication., 2012, US2012/0123157 A1.
14) Hung, S. B.; Chen, J. H.; Lin, Y. D.; Huang, H. P.; Lee, M. J.; Ward, J. D.; Yu, C. C., Control of Plant wide Reactive Distillation Processes: Hydrolysis, Transesterification and Two-Stage Esterification, J. of the Taiwan Ins. of Che. Eng., 2010, 41, 382 - 402.
15) Ihs.com. n.d., 2013, Chemicals Industry Solutions | IHS. [online] Available at: http:// http://www.ihs.com/products/chemical/planning/ceh/formic-acid.aspx.
16) Indu, B.; Ernst, W.; Gelbaum, L., Methanol-Formic Acid Esterification Equilibrium in Sulfuric Acid Solutions: Influence of Sodium Salts, Ind. Eng. Chem. Res., 1993, 32, 981-985.
17) Js-hengmao.com., 2012, Jiangsu Hengmao Machinery Manufacture Co,.Ltd. [online] Available at: http://www.hengmaomachinery.com/news/3526.html.
18) Lee, H. Y.; Lee, Y. C.; Chien, I. L.; Huang, H. P., Design and Control of a Heat-Integrated Reactive Distillation System for the Hydrolysis of Methyl Acetate, Ind. Eng. Chem. Res., 2010, 49, 7398 - 7411.
19) Leonard, J. D., Preparation of Formic Acid by Hydrolysis of Methyl Formate, United State Patent., 1981, 4.299.981.
20) Lin, Y. D.; Chen, J. H.; Cheng, J. K.; Huang, H. P.; Yu, C. C., Process Alternatives for Methyl Acetate Conversion using Reactive Distillation. 1. Hydrolysis, Chem. Eng. Sci., 2008, 63, 1668 - 1682.
21) Liu, Q.; Takemura, F.; Yabe, A., Solubility and Diffusivity of Carbon Monoxide in Liquid Methanol, J. Chem. Eng. Data., 1996, 41, 589 - 592.
22) Luyben, W. L., Design and Control of a Fully Heat - Integrated Pressure - Swing Azeotropic Distillation System, Ind. Eng. Chem. Res., 2008, 47, 2681 - 2695.
23) Luyben, W., Distillation Design and Control Using Aspen Simulation; John Wiley & Sons, Inc; New Jersey, 2006.
24) Luyben, W.; Yu, C., Reactive Distillation Design and Control; John Wiley & Sons, Inc; New Jersey, 2008.
25) Lynn. J. B.; Homberg, O. A.; Singleton, A. H., Formic Acid Synthesis by Lower Alkyl Formate Hydrolysis, United State Patent., 1973, 3.907.884.
26) Mahajan, D.; Slegeir, W. A.; Sapienza, R. S.; O’Hare. T. E., Low Temperature Synthesis of Methyl Formate, United State Patent., 1985, 4.613.623.
27) Mai, P.; Vu, T.; Mai, K., Analysis of Temperature Effects on Ester Hydrolysis Reactions in a Fixed-Bed Chromatographic Reactor, Ind. Eng. Chem. Res., 2004, 43, 4691.
28) Nguyen, N.; Demirel, Y., Using Thermally Coupled Reactive Distillation Columns in Biodiesel Production, Energy., 2011, 36, 4838 - 4847.
29) Noeres, C.; Kenid, E. Y.; Gorak, A., Modelling of Reactive Separation Processes: Reactive Absorption and Reactive Distillation, Chem. Eng. Process., 2003, 42, 157 - 178.
30) Polak, J.; Lu, B. C. Y., Excess Gibbs Free Energies and Excess Volumes of Methyl Formate + Methanol and Methyl Formate + Ethanol at 298.15 K, J. Chem. Thermodyn., 1972, 4, 469 - 476.
31) Smith, R., Chemical Process Design and Integration; John Wiley & Sons Ltd; Chichester, 2005.

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