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研究生: 任逸群
I-Chun Ren
論文名稱: 中性化水泥砂漿工程性質及檢測方法之研究
Study on Engineering Properties and Test Methods of Carbonized Mortar
指導教授: 張大鵬
Ta-Peng Chang
陳君弢
Chun-Tao Chen
口試委員: 田永銘
Yong-Ming Tien
黃然
Ran Huang
學位類別: 碩士
Master
系所名稱: 工程學院 - 營建工程系
Department of Civil and Construction Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 76
中文關鍵詞: 砂漿碳化工程性質量測法pH 值
外文關鍵詞: mortar, carbonation, engineering properties, measurement technique, pH value
相關次數: 點閱:227下載:14
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本研究探討水泥砂漿相同水灰比(w/c = 0.6)、拌合步驟、養護及環境條件之下,不同擴散型式之碳化深度與砂漿基本工程性質之關係,並比較四種不同碳化深度量測法。
研究結果顯示:(1)各項基本工程性質皆會因碳化深度的增加而增加,超音波波速約提升5.47~7.42 %、動態彈性模數約提升13.68~20.63 %、動態剪力模數約提升18.57~29.31 %、抗壓強度約提升45.96~62.50 %。(2)四種不同碳化深度量測法中,就量測便利性而言,酚酞測定法最快,其次為X光繞射法,X光顯微分析,最後為熱重量分析,其中酚酞測定法、X光繞射法、熱重量分析三者所量測碳化深度結果相近,但X光顯微分析的結果會隨著選取點位的方式而異,故碳化深度較不確定。(3) 水泥砂漿會因中性化後pH值約由12下降至8~11左右,但其pH值變化與碳化深度之間的關聯性並不顯著。


This study investigates the relation between the carbonation depths resulting from different types of diffusion and the engineering properties of the mortar prepared with the same water-cement ratio (w/c = 0.6), mixing procedure, curing and environmental conditions.
The results showed that: (1) Engineering properties of the mortar specimens were improved by the increased carbonation depth by 5.47 to 7.42% for the ultrasonic pulse wave speed, by 13.68 to 20.63 % for the dynamic elastic modulus, by 18.57 to 29.31 % for the dynamic shear modulus, and by 45.96 to 62.50% for the compressive strength. (2) In consideration of the measuring convenience among four detecting techniques for the carbonation depth, the phenolphthalein titration is the fastest, the X-ray diffraction method ranked the second, the X-Ray energy dispersive spectroscopy ranked the third, and the thermal gravimetric analysis was the slowest. Similar carbonation depths were obtained using the phenolphthalein titration, X-ray diffraction and thermal gravimetric analysis. In contrast, fluctuating carbonation depths were obtained by the X-ray energy dispersive spectroscopy because of the dispersed selections of test points. (3) Due to carbonation, the pH value of the mortar dropped from about 12 to around 8 to 11, but the correlation between the pH value and the carbonation depth is insignificant.

致謝 I 中文摘要 III 英文摘要 IV 總目錄 V 表目錄 VIII 圖目錄 IX 第一章 緒論 1 1.1 研究動機 1 1.2 研究目的 1 1.3 研究內容與流程 2 第二章 文獻回顧 4 2.1 混凝土耐久性 4 2.2 混凝土中性化 4 2.2.1 混凝土碳化之機理 5 2.2.2 混凝土碳化之影響因素 7 2.2.3 混凝土碳化之性質的改變 8 2.2.4 混凝土碳化之加速方式 8 2.2.5 混凝土碳化之量測方式 9 第三章 試驗計畫 16 3.1 試驗內容 16 3.2 試驗材料 16 3.3 試驗參數 17 3.3.1 試體編號說明 18 3.4 試驗儀器與設備 18 3.5 試驗項目與步驟 22 第四章 結果與討論 36 4.1 工程性質 36 4.1.1 超音波波速 36 4.1.2 動態彈性與剪力模數 37 4.1.3 抗壓強度 37 4.1.4工程性質之小結 38 4.2 pH值 38 4.2.1 碳化對pH值之影響 38 4.2.2 pH值小結 39 4.3 不同碳化檢測方式比較 39 4.3.1 酚酞測定法 39 4.3.2 熱重量分析 40 4.3.3 X光繞射法 40 4.3.4 X光顯微分析 41 4.3.5 不同碳化檢測方式比較小結 41 第五章 結論與建議 67 5.1 結論 67 5.2 建議 69 參考文獻 72

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