本實驗使用一套可變體積-附視窗暨影像處理系統的高壓相平衡分析裝置，以合成法量取乙基乙炔+ DMF、乙基乙炔+ NMP、1,3-丁二烯+ DMF及1,3-丁二烯+ NMP等四組雙成分系統與1,3-丁二烯+ [NMP/water = 2.09/1（莫耳比)]一組三成分系統的汽液相平衡實驗數據，量測溫度介於298.15 K ~ 348.15 K之間，平衡壓力則介於1 bar ~ 10 bar之間。實驗所量取的雙成分及三成分系統之汽液相平衡數據均分別使用NRTL-HOC及UNIQUAC-HOC模式關聯，同時也求取最適化的二元參數值。

With a synthetic method, a high-pressure phase equilibrium analyzer (PEA) with a visual-variable volume cell was used to measure the vapor-liquid phase equilibrium data for ethyl acetylene + DMF, ethyl acetylene + NMP, 1,3-butadiene + DMF, 1,3-butadiene + NMP, and 1,3-butadiene + [NMP/water = 2.09/1 (in molar ratio)] at temperatures from 298.15 K to 348.15 K and pressures from 1 bar to 10 bar. All the phase equilibrium data of binary and ternary systems were correlated with the NRTL-HOC and the UNIQUAC-HOC models, respectively, and simultaneously determined the optimal values of the binary parameters.

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