本論文主要是開發新的有機染料，是以苯乙烯基菲為衍生物的染料，一個有機
染料主要的基本結構上是具有拉電子基、π-共振橋基和推電子基三部份，而本論
文的有機染料所使用的拉電子基是cyanoacrylic acid；π-共振橋基是苯乙烯基菲；
推電子基是triphenylamine，而在已有的文獻上大部分是以苯乙烯或二苯乙烯為
骨架衍生物研究居多，因此本實驗重新合成(Z)-2-cyano-3-(4-((E)-4-(diphenylami
-no)syryl)phenyl)acrylic acid(CDSPA)是文獻上已有的化合物作為對照組，且本實
驗室利用反式二苯乙烯照光經順式二苯乙烯進行六電子環化變成菲的光氧化環
化反應，藉此成功合成出一系列的苯乙烯基菲衍生物，此結構增強了分子剛性及
增加π 共軛系統，而對於苯乙烯基菲衍生物作為有機太陽電池的染料，目前是尚
未有研究及討論的，因此本論文將對以苯乙烯基菲骨架的有機染料進行探討及研
究。

This paper aims to develop new organic dyes. The dye main backbone is
styrylphenanthrene derivatives in this paper. A basic structure of the organic dye
includes three parts: an acceptor, a π-electron resonance bridge and a donor. The
acceptor of organic dye is the cyanoacrylic acid; the π-resonance bridge groups is
styrylphenanthrene; their donor is the triphenylamine in this paper. However the most
DSSCs dyes of the reported literature are based on styrene or derivatives of stilbene
backbone, we synthesized the compound(CDSPA) as the counterpart. We used
irradiated methodology to make trans-stilbene changing into cis-stilbene, which then
carried out six-electron photocyclization to afford phenanthrene. By this feature, we
have successfully synthesized a series of derivatives of styrylphenanthrenes, and their
molecular structure strengthened the rigidity and increased more conjugated π system.
Until now, no research in literatures studied styrylphenanthrene derivatives as DSSCs
dye, therefore this paper will aim to synthesize organic dye with styrylphenanthrene
main backbone and study on their photophysical properties.

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