本研究主要使用擁有兩個末端位置羰基之雙馬來醯亞胺(N’-bismaleimide-4,4-diphenylmethane, BMI) 與擁有一個CH2兩個NH基之巴比妥酸(Barbituric acid, BTA)進行聚合反應，以及可抑制自由基反應之對苯二酚(Hydroquinone, HQ)進行麥克加成反應與自由基聚合反應之反應動力學探討。另外，使用擁有一個末端位置羰基之甲基丙烯酸四氟丙酯(2,2,3,3-Tetrafluoropropyl methacrylate, TFPMA)與巴比妥酸(BTA)參與反應，並使用可促進分子量交聯之三羥甲基丙烷三丙烯酸酯(Trimethylolpropane triacrylate, TMPTA)進行聚合特性研究。
並使用微分式掃描熱量分析儀(DSC)獲得反應放熱量，將所得數據處理與計算後選用最適合之反應模型，再利用Arrhenius equation計算出活化能(Ea)與頻率因子(A)；最後利用熱重/熱示差分析儀(TGA)以及凝膠滲透層析儀(GPC)進行材料耐熱性質的探討及分析。

This work studied the polymerization reaction of the two terminal -C=C- groups of N,N-bismaleimide-4,4-diphenylmethane (BMI) with one CH2 group and two NH groups of Barbituric acid (BTA).And use of inhibitor free radical polymerization of hydroquinone (HQ) were studied kinetics of free radical polymerization and Michael addition reaction . In addition , use one terminal -C=C- groups of 2,2,3,3-Tetrafluoropropyl methacrylate(TFPMA) with Barbituric acid (BTA) involved in the reaction and use Trimethylolpropane triacrylate(TMPTA)to promote molecular cross-linking with characteristics of polymerization of research materials.
DSC was used to obtain the reaction kinetics data, then data were used to choose the best-fit kinetics model and determine triplet kinetics parameters.And then use TGA and GPC to discuss and analyze material properties of the heat-resistant.

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