本文目的為探討三種特用添加劑，分別為(1)奈米級及次微米級核殼型橡膠(Core-Shell Rubber, CSR)(2)矽烷接枝之蒙特納石黏土(Montimrillonite clay, MMT)(3)官能基化之脫層石墨烯奈米層板(functionalized exfoliated grapheme nanoplatelet)，其對苯乙烯(St)/不飽和聚酯(UP)樹脂或乙烯基酯樹脂(VER)系統之聚合固化反應動力、玻璃轉移溫度及X光散射特性之影響。
　　本研究也利用小角度X光散射儀(Small-angle X-ray scattering, SAXS)測定UP及VER之稀薄苯乙烯溶液之散射強度，根據Guinier Law計算不同濃度下之環動半徑(Radius of Gyration, Rg)，可用於瞭解UP或VER分子擴散至MMT層間的長廊空間之難易程度。並利用廣角度X光散射儀(Wide-angle X-ray scattering, WAXS)測定St/UP(或VER)/矽烷接枝蒙特納石黏土(MPS-MMT)三成份系統之固化試片，瞭解MPS-MMT層間距離之變化及在基材中的分散程度。
　　另外，分別使用差式掃描卡計(DSC)及傅立業轉換紅外線光譜儀(FTIR)測量St/UP(或VER)/添加劑之三成份系統在聚合固化過程中的反應動力。最後使用動態機械分析儀(DMA)測量固化後樣品之玻璃轉移溫度。

The effects of three additives, including (1) nano-scale and submicron-scale core-shell rubber additive, (2) silane-grafted montmorillonite and (3) functionalized exfoliated grapheme nanoplatelet, on the cure kinetics, glass transition temperature and X-ray scattering characteristics for the Styrene(St)/Unsaturated polyester (or Vinyl ester resin)/additives ternary systems after the cure have been investigated.
The scattering intensity of vinyl ester resin (VER) and unsaturated polyester (UP) with different structure in dilute styrene solution was measured by the method of small angle X-ray scattering (SAXS), and the radius of gyration of VER and the UP molecule can then be calculated by using the Guinier law. And measured the cured specimens for St/UP (or VER)/silane-grafted MMT ternary system by using wide angle X-ray scattering (WAXS), investigate the change of d-spacing and the degree of dispersion of the substrate of silane-grafted MMT .
The reaction kinetics for the St/UP (or VER)/additive ternary system during the cure was measured by differential scanning calorimetry (DSC) and fourier transform infrared spectroscopy (FTIR). Finally, based on the Takayanagi mechanical models, the glass transition temperature in each region of the cured samples for St/UP/additive ternary system has been measured by dynamic mechanical analysis (DMA).

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