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研究生: 許仲志
Chung-Chih Hsu
論文名稱: 各類共沸蒸餾系統之程序設計與控制
Design and Control of Various Azeotropic Distillation Systems
指導教授: 錢義隆
I-Lung Chien
口試委員: 周宜雄
Yi-Shyong Chou
汪上曉
Shang-Hsiao Wong
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 233
相關次數: 點閱:515下載:8
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誌謝 I 摘要 II 目錄 IV 圖表目錄 VII 1 緒論 1 1.1 引言 1 1.2 各類共沸蒸餾之製程目的 5 1.3 共沸物之定義及種類 6 1.4 各類共沸蒸餾製程形式 8 1.5 文獻回顧 10 1.5 1 多重穩態解與參數敏感性 10 1.5 2 動態表現與控制 12 1.6 組織章節 14 2 熱力學模式 15 2.1 引言 15 2.2 模式建立與參數 15 2.3 蒸餘曲線(RCM) 28 2.4 質量平衡線 41 3 穩態模擬與最適化設計 43 3.1 前言 43 3.2二氧陸圜-水之設計與最適化搜尋 44 3.2.1引言 44 3.2.2壓敏蒸餾法之穩態設計 44 3.2.3壓敏蒸餾法最適化設計與經濟評估 52 3.2.4壓敏蒸餾法之不純物分離 56 3.2.5壓敏蒸餾法之年度總預算 62 3.2.6非均勻相共沸蒸餾法之穩態設計 66 3.2.6.1使用乙酸乙酯作為共沸劑之最適化穩態設計 71 3.2.6.2使用苯作為共沸劑之最適化穩態設計 82 3.2.7非均勻相共沸蒸餾法之不純物分離 95 3.2.8兩系統之經濟評估與比較 103 3.3甲基丙烯酸甲酯回收之設計與最適化搜尋 107 3.3.1引言 107 3.3.2穩態設計 107 3.3.3最適化設計與經濟評估 118 3.3.4兩塔設計之最適化設計與經濟評估 118 3.3.5單塔設計之最適化設計與經濟評估 131 3.4丙二醇甲醚去水之設計與最適化搜尋 144 3.4.1引言 144 3.4.2丙二醇甲醚去水系統之穩態設計 146 3.4.3最適化設計與經濟評估 150 4 動態模擬 174 4.1前言 174 4.2甲基丙烯酸甲酯-甲醇-水分離製成之控制架構 175 4.2.1控制策略 175 4.2.2干擾排除 179 4.3丙二醇甲醚去水分離製成之控制架構 188 4.3.1控制策略 188 4.3.2干擾排除 192 5 結論 203 附錄A計算TAC使用之公式 205 參考文獻 209

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