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研究生: 蕭輔箴
Fu-Zhen Hsiao
論文名稱: 團狀模塑料之機械性質研究
Study on the Mechanical Properties of Bulk Molding Compounds Materials
指導教授: 鍾俊輝
Chunhui Chung
口試委員: 郭俞麟
Yu-Lin Kuo
陳建光
Jem-Kun Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 77
中文關鍵詞: 玻璃纖維BMC團狀模塑料
外文關鍵詞: glass fiber, BMC, Bulk molding compound
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本研究目的為混合團狀模塑(BMC,Bulk molding compound)材料置於模具後以熱壓成型技術製作出BMC拉伸試片,搭配材料拉伸試驗機與蕭氏硬度計來取得實驗數據,再將實驗數據以田口方法找出BMC材料最佳實驗參數並探討添加物在不同水準比例情況下與機械性質之間關係。實驗以田口L9直交表選用苯乙烯單體、石墨粉末、玻璃纖維以及低輪廓添加劑;對BMC材料成形中最有影響力的四個因子進行分析,分析結果顯示,石墨之添加量與硬度關係最為密切,在拉伸強度方面則為玻璃纖維之添加量,經由預測及驗證分析後,BMC最佳化配方為低輪廓添加劑4 wt%、玻璃纖維15wt%、石墨30 wt%、苯乙烯單體4 wt%,按照此添加比例製做出的BMC試片具有最佳之成型性以及最佳之機械性質。

關鍵字:玻璃纖維、BMC、團狀模塑料


The purpose of this study is a mixed BMC material and placed in a mold using thermoforming technology to produce BMC tensile test piece, with tensile testing machine and Shore Durometer hardness to obtain experimental data. Analysis of optimum parameters of BMC material and then the experimental data using the Taguchi method and explore the relationship between the mechanical properties of the additive levels in different proportions situation. Experiment with Taguchi L9 orthogonal array selection styrene monomer, graphite powder, glass fiber and low profile additives; for BMC material forming the most influential of the four factors were analyzed and the results showed that the amount of graphite and between hardness most closely in terms of the relationship between the tensile strength is the amount of glass fibers.After the best analysis predicted and verified, BMC optimized formulation for the low-profile additive 4 wt%, glass fiber 15wt%, graphite 30 wt%, styrene monomer 4 wt%, as previously this formulation manufactured BMC specimens with the most best of formability and the best of the mechanical properties.

Keyword: glass fiber, BMC, Bulk molding compound

摘要 I ABSTRACT II 致謝 III 目錄 IV 表索引 VIII 圖索引 IX 第1章 緒論 1 1.1 研究背景 1 1.2 研究目的與方法 2 1.3 論文架構 3 第2章 文獻回顧 5 2.1 複合材料[1] 5 2.2 BMC材料[2] 6 2.3 團狀模造成型(BULK MOLDING) 7 2.4 纖維強化複合材料之機械性質 8 第3章 實驗方法與設備 10 3.1 實驗材料 12 3.2 實驗設備 19 3.2.1 試片模具 19 3.2.2 熱壓機 21 3.3 BMC材料混和與試片備製 21 3.4 田口法實驗規劃 23 3.4.1 S/N比 24 3.4.2 變異數分析 26 3.5 實驗量測 27 3.5.1 拉伸試驗 27 3.5.1.1 彈性模數 28 3.5.1.2 降伏強度(yield strength) 29 3.5.1.3 抗拉強度(tensile strength) 29 3.5.1.4 斷裂伸長(elongation at break) 30 3.5.1.5 延性 30 3.5.1.6 材料拉伸試驗機 31 3.5.2 硬度量測 32 3.5.2.1 蕭氏硬度[26] 33 3.5.2.2 蕭氏硬度試驗機 34 3.5.3 掃描式電子顯微鏡(SEM) 35 3.6 實驗數據分析 35 第4章 實驗結果與討論 37 4.1 田口實驗 37 4.2 田口試片硬度實驗結果 38 4.2.1 硬度變異數分析 41 4.2.2 田口實驗硬度確認與分析 43 4.3 田口試片最大拉伸強度結果 45 4.3.1 拉伸變異數分析 48 4.3.2 田口實驗拉伸確認與分析 50 4.3.3 試片最佳參數之拉伸結果 52 4.4 田口實驗結果討論 54 4.4.1 石墨控制因子分析 54 4.4.2 玻璃纖維控制因子 56 4.5 微觀組織分析 57 4.5.1 斷面觀察 58 4.5.2 截面觀察 59 第5章 結論 62 5.1 結論 62 5.2 未來展望 63 參考文獻 65 附錄 A 拉伸曲線圖 68

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