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研究生: 蕭詳樺
Hsiang-Hua Hsiao
論文名稱: 共押出複合薄膜之光學與聲學研究
A study on Acoustic Properties and Optical Properties of Co-extruded Composite Film
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 游進陽
none
邱智瑋
Chih-Wei Chiu
呂政錡
none
江宗穎
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 106
中文關鍵詞: 揚聲器振膜背光模組擴散膜霧度三軸共押出聚對苯二甲酸乙二酯-14-環己烷二甲醇酯乙烯醋酸乙烯酯剛性楊氏係數
外文關鍵詞: speakers, diaphragm, backlight, the proliferation of film, haze, triaxial co-extruser, polyethylene terephthalate 1, 4-cyclohexanedimethanol acetate, ethylene vinyl acetate, rigidity, Young's modulus
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本研究是利用聚對苯二甲酸乙二醇酯-1,4-環己烷二甲醇酯(Poly (ethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate)及乙烯醋酸乙烯酯(Ethylene-vinyl acetate)加入發泡母粒製備成複合型發泡薄膜,以研究複合薄膜結構及發泡對於光學性質及聲學性質之影響。
實驗上先針對所使用之原物料通過熱性質及流變行為分析如熱重損失(TGA)、示差掃描量熱(DSC)、熔流指數(MFI)及迴轉式流變儀(MCR)等分析,參考分析後之數據,以作為後續加工參數之依據及限制。樣品製備方面則以三軸共押出機使用共押出之方式,參考原物料材料分析之性質,歸納出適合之加工參數。製備之樣品則以內層為添加發泡母粒之乙烯醋酸乙烯酯(EVA)作為彈性層,剛性較高之聚對苯二甲酸乙二醇酯-1,4-環己烷二甲醇酯則作為外層。
所製備之樣品厚度為90~100μm,符合微型揚聲器所使用振膜之規格,經由拉伸實驗分析力學性能,可以得知其在後續可承受的使用範圍以及材料剛性。藉著光學及聲學儀器分析,探討薄膜材料、複合薄膜結構比例及發泡對於光學及聲學之影響性。


The study is the use of poly (ethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate and ethylene-vinyl acetate that added a chemical foaming agent to prepare the foaming co-extruded composite film then to research the influences of composite film foaming structure for optical and acoustic properties.
The first experiment for the raw materials used in the analysis such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), melt flow index (MFI) and rheometer (MCR) analyzed by thermal properties and rheological behavior , the reference data analysis, as a basis for processing parameters and limitations. Sample preparation using a triaxial co-extrusion machine with reference of the raw materials materials analysis summarized for the processing parameters. Sample preparation for the addition of the foaming masterbatch inner places of ethylene vinyl acetate (EVA) as an elastic layer, a high rigidity of polyethylene terephthalate is cyclohexane-1,4-dimethylene terephthalate as outer layer.
The thickness of the the prepared samples are 90 ~ 100μm conformed to the specifications of the diaphragm micro-speaker. By analyzing the mechanical properties of tensile test, you can learn its rigidity and affordable range in use. By optical and acoustic instrumental analysis, to explore film materials, composite film and foam structure of the proportion of the optical and acoustic impact resistance.

Keywords: speakers, diaphragm, backlight, the proliferation of film, haze, triaxial co-extruser, polyethylene terephthalate 1,4-cyclohexanedimethanol acetate, ethylene vinyl acetate, rigidity, Young's modulus

摘要I AbstractIII 目錄IV 圖目錄VII 表目錄XI 第1章 緒論1 1.1研究背景與發展趨勢1 1.2研究動機與目的2 第2章 文獻回顧3 2.1聚對苯二甲酸乙二醇酯-1,4-環己烷二甲醇酯(Poly (ethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate),PETG)3 2.2乙烯醋酸乙烯酯(Ethylene-vinyl acetate)5 2.3薄膜製造工藝7 2.3.1押出吹塑成型法7 2.3.2押出流延成型法9 2.3.3多層薄膜技術10 2.4液晶顯示器(Liquid-Crystal Display,LCD)13 2.4.1 LCD背光模組14 2.5光擴散膜18 2.5.1光擴散膜之分類18 2.5.2光擴散劑材料20 2.6聲音原理與揚聲器21 2.6.1聲音21 2.6.2揚聲器21 2.6聚合物發泡材料30 2.6.1發泡體的分類30 2.6.2發泡的原理31 2.6.3發泡之過程32 2.6.2發泡劑的種類和方式36 參考文獻39 第3章 實驗材料、儀器與方法45 3.1實驗材料45 3.2實驗儀器47 3.3實驗方法48 3.3.1實驗架構45 3.3.2薄膜製備48 3.3.3儀器試驗54 第4章 結果與討論62 4.1原物料鑑定62 4.1.1熱性質62 4.1.2流變行為67 4.2加工溫度與參數綜合探討71 4.2.1加工溫度設定71 4.2.2加工參數設定72 4.3薄膜分析73 4.3.1力學性質分析73 4.3.2光學性質分析84 4.3.3音頻效應探討96 4.3.4斷面型態與特徵103 第5章 結論106

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