電解質通過促進離子來回移動在鋰金屬電池系統中發揮重要作用。因此，在組裝電池時選擇
合適的電解液是提高循環性能的重要步驟之一。然而，目前對平面二維銅的研究中，對鍍層剝離
的鋰厚度的重點研究並沒有很好地關注定量證明形成的 SEI 的均勻性，而這是獲得良好性能的
重要因素。在這項工作中，厚度為 130 nm 的 Ag 塗層凹槽通過磁控濺射沉積在商業銅箔上的
3D 結構陣列圖案上，作為評估 Li//Cu 半電池配置中液體電解質的新平台。該設計提供了兩個
關鍵點，即所謂的 (1) Hill 和 (2) Valley 區域，以表示不同電解質的均鍍能力 (TP) 的均
勻性，這與電化學性能相關。在電鍍過程中，通過橫截面圖像可以清楚地捕捉到薄而緻密的 Li
和 SEI 層，並且在剝離後幾乎沒有發現 Li 以及在應用 FEC ( 3 59 %) 和 TMSP ( 49 60 %) 後
TP 值增加的跡象作為添加劑，這與單獨使用 LiPF 6 的 TP 值 6 6 84 %) 形成對比。
該結果顯示了丘陵和山谷如何很好地證明添加劑如何對實現均勻層產生顯著影響，這成為
與單獨使用 LiPF 6 (91.89%) 相比實現更高平均庫侖效率（ FEC 為 95.39% TMSP 為 94.87%
的根本原因。此外，使用含 FEC 的電解質分別獲得了山丘和山谷的最低電阻值（ 18.76 Ω 和
10.92 Ω）和平均表面粗糙度 Ra 24.8 和 22.4 nm ），表明由於沒有光刻膠，山谷區域具有更
好的性能，因此光滑的 SEI 可以在鍍銀的凹槽表面形成。通過應用包含山丘和山谷區域的 Ag 塗
層凹槽的設計，深入了解如何構建平台以符合在鋰金屬電池應用中篩選液體電解質的良好選擇
的努力。

Electrolytes provide an important role in Li metal battery system by promoting the movement of ion back and forth. Therefore, selecting a prompt electrolyte in assembling a cell is one of important step to enhance the cycling performance. However, the focus study on Li thickness on plating-stripping in current research on planar 2D Cu have not well concern on quantitatively demonstrating the uniformity of formed SEI, which is an important factor to achieve good performance. In this work, Ag coated groove of thickness 130 nm was deposited by magnetron sputtering on a 3D structure array pattern laying on a commercial Cu foil to act as a new platform to evaluate liquid electrolytes in Li//Cu half-cell configuration. This design provides two key points, so called (1) Hill and (2) Valley area in order to express the uniformity in term of throwing power (TP) with various electrolytes, which correlated with the electrochemical performance. During plating, a thin and dense Li and SEI layer are obviously captured through cross sectional image and almost no Li left found after stripping along with the indication of increasing on TP value after applying FEC (-3.59%) and TMSP (-49.60%) as an additive, which in contrast to TP value of LiPF6 alone (-66.84%).
This result shows how hill and valley demonstrated well how additives can give significant effect on achieving a uniform layer which become underlying reason of higher average coulombic efficiency achieved (95.39% for FEC and 94.87% for TMSP) compared to LiPF6 alone (91.89%). Moreover, lowest value of resistance (18.76 Ω and 10.92 Ω) and average surface roughness Ra (24.8 and 22.4 nm) on hill and valley respectively are obtained with FEC-contained electrolyte indicating the valley area has better properties due to photoresist absence, thus a smooth SEI can be formed on Ag coated groove surface. By applying the design of Ag coated groove containing hill and valley area, gives significant insight how a platform can be built to comply the effort in screening the good options for liquid electrolytes in Li-metal battery application.

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