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研究生: 邱晨華
CHEN-HUA CHIU
論文名稱: EPDM架橋系統對物性影響效應之研究
The Effect of Crosslinking System on Physical Properties of EPDM
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 楊銘乾
Ming-Chien Yang
陳志堅
Jyh-Chien Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2014
畢業學年度: 102
語文別: 中文
論文頁數: 78
中文關鍵詞: 三元乙丙橡膠複合架橋混練硫化
外文關鍵詞: EPDM rubber, composite-crosslinking, blend, vulcanization
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本研究主要在探討EPDM常用的架橋系統,以及硫磺/過氧化物並用的複合架橋系統,先以孟山都硫變儀(monsanto rheometer)來決定熱壓溫度,以及探討各架橋系統對於架橋速度的影響, 熱壓成型後試片,測試其機械特性及永久壓縮變形率,以老化試驗探討隨著硫化劑的比例不同對於耐老化程度的影響,以DMA進行分子鏈運動分析。
結果顯示硫磺(Sulfur)與過氧化物(DCP)以3:7比例並用的複合架橋體系,其硫化速度快且加工安全性好,機械性質與硫磺架橋體系統相當,且耐老化程度與永久壓縮變形率與過氧化物架橋系統相當,具有最好的綜合性能。


This study is focused on the common crosslinking system for EPDM rubber and a composite crosslinking system of sulfur / peroxide for EPDM rubber, A Monsanto rheometer was employed to determine the processing time and the optimum process temperature, and explore the crosslinking rate, and test the mechanical properties and compression set, Aging tests was used for investigating different proportions of crosslinking agent for heat aging resistance properties, The dynamic mechanical analysis (DMA) was used for investigating chain motion.
The experimental results show that the crosslinking system with sulfur and DCP in a weight ratio of 3:7,Yielded the faster crosslinking rate and the processing is safety, The mechanical properties is close to those with sulfur crosslinking system, the degree of resistance to aging and compression set were close to those of peroxide crosslinking system, had perfectly total properties .

摘要 I Abstract II 誌謝 III 目錄 IV 圖目錄 VII 表目錄 VIII 第一章 緒論 1 1.1前言 1 1.2研究動機與目的 1 1.3三元乙丙橡膠概述 3 1.3.1生產方法 3 1.3.2結構 6 1.3.3性能 8 1.3.4應用 10 1.3.5 混摻 12 1.4橡膠硫化概述 14 1.4.1硫化歷程 14 1.4.2交聯鍵類型 15 1.4.3硫化曲線圖 16 第二章 文獻回顧 19 2.1橡膠硫化歷史 21 2.2.1橡膠硫化體系 22 第三章 實驗部分 30 3.1實驗架構 30 3.2使用材料 31 3.3試驗方法與步驟 34 3.3.1 EPDM硫化膠製備 34 3.3.2機械特性分析 34 3.3.3硫化試驗 37 3.3.4 熱動態機械分析(Dynamic Mechanical Analysis,DMA) 38 3.3.5熱重量損失分析- Thermal Gravity Analysis (TGA) 39 第四章 結果與討論 46 4.1拉伸強度及伸長率試驗(Stress and Strain) 46 4.1.2老化後物性分析 47 4.2 硬度試驗(Hardness) 54 4.3硫化反應 62 4.4壓縮永久變形試驗(Compression Set) 69 4.5熱動態機械分析(Dynamic Mechanical Analysis,DMA) 72 4.6熱重量損失分析- Thermal Gravity Analysis (TGA) 74 第五章 結論 75 參考文獻 76

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