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研究生： 馬愛途
Ni'matut - Tamimah
論文名稱： Metal Nanoparticle Synthesis/Deposition under Femtosecond Laser Irradiation in Water
Metal Nanoparticle Synthesis/Deposition under Femtosecond Laser Irradiation in Water
指導教授： 今榮東洋子
Toyoko Imae
口試委員: 氏原真樹
Masaki Ujihara
鄧熙聖
Hsisheng Teng　
學位類別： 碩士
Master
系所名稱： 應用科技學院 - 應用科技研究所
Graduate Institute of Applied Science and Technology
論文出版年： 2016
畢業學年度： 104
語文別： 英文
論文頁數： 96
中文關鍵詞： FemtosecondLaser 、MetalNanoparticle 、GoldNanoparticle 、SilverNanoparticle 、PlatinumNanoparticle 、Synthesis 、Deposition.
外文關鍵詞： Femtosecond Laser, Metal Nanoparticle, Gold Nanoparticle, Silver Nanoparticle, Platinum Nanoparticle, Synthesis, Deposition.
相關次數： 點閱：170  下載：0 
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    • This study is to suggest the synthesis and deposition of metal nanoparticles under femtosecond laser irradiation and clarify several factors that govern the properties of nanoparticles synthesized by femtosecond laser irradiation in liquid environment. In the experiments, metal nanoparticles were formed by irradiating laser to the metal precursor without any reducing agent. Precursor solutions of three different metals i.e. gold, silver, and platinum were prepared by dissolving sodium tetrachloroaurate(III) dihydrate, (NaAuCl4•2H2O, 99%), Silver Nitrate (AgNO3, 99.9%), and sodium hexachloroplatinate(IV) hexahydrate (Na2PtCl6•6H2O, 98%) in water. Ultraviolet visible, dynamic light scattering, optical microscopy, transmission electron microscopy (TEM) and atomic force microscopy were used to analyze the morphology of the metal nanoparticles formed and deposited. Fomvar-coated TEM grids were used as a substrate for depositing metal nanoparticle. Irradiation effect from femtosecond laser in water was generated spherical metal nanoparticles for each metal nanoparticle in dilute concentration of the precursor. Hence, the Mie theory of surface plasmon band position dependence with average size of the particle formed is no longer valid because the particle size is very small. The deposition was promising approach for this purpose because the deposited amount of the nanoparticles on substrate is enough even for low bulk concentration. This is very simple technique and environmentally friendly because it does not use any chemicals except for a metal precursor. This method was an easy, low-energy consuming, and suitable for deposited “film of” metal nanoparticles.

    Master’s Thesis Recommendation Form Qualification Form by Master’s Degree Examination Committee Abstract Acknowledgements Table of Contents List of Figures List of Tables List of Abbreviations Chapter I: General Introduction 1.1 Metal Nanoparticles (NPs) and Their Properties 1.1.1 Physical Properties 1.1.2 Chemical Properties 1.2 Synthesis Method of Metal NPs 1.2.1 Bottom-up Methods 1.2.2 Top-down Methods 1.3 Laser Irradiation in Aqueous Solution 1.3.1 The Interaction of Electromagnetic Radiation with Medium 1.3.2 Formation of Metal NPs by Laser Irradiation in Aqueous Solution 1.4 Objectives of this study Chapter II: Materials and Instruments 2.1 Materials 2.2 Instruments Chapter III: Exploration of Synthesis of Gold NPs by Reduction method 3.1 Introduction 3.2 Experimental Section 3.2.1 Chemical Synthesis 3.2.2 Characterization 3.3 Results and Discussion 3.3.1 Existent SPR of NPs 3.3.2 An Effect of Temperature on Gold NPs Formation 3.3.3 An Effect of Reductant Concentration on Size of Gold NPs 3.3.4 Light Effect on the Optical Properties of Gold NPs 3.3.5 Size Calibrations from Extinction SPR Chapter IV: Metal Nanoparticle Synthesis/Deposition under Femtosecond Laser Irradiation in Water 4.1 Introduction 4.2 Experimental Section 4.2.1 Synthesis of Metal NPs 4.2.2 Deposition of Metal NPs 4.3 Results and Discussion 4.3.1 An Effect of Concentration Precursor Solutions on the Metal NPs Synthesis 4.3.1.1 Synthesis of Gold NPs 4.3.1.2 Synthesis of Silver NPs 4.3.1.3 Synthesis of Platinum NPs 4.3.2 Deposition of Metal NPs under Femtosecond Laser Irradiation 4.3.2.1 Carbon-coated Copper TEM Grids Substrate 4.3.2.2 Formvar-coated Stainless Steel TEM Grids Substrate Chapter V: Conclusion Appendix A: Femtosecond Laser Appendix B: Formvar-coated TEM Grids References

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