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研究生: 廖士瑋
Shih-wei Liao
論文名稱: 以花生殼灰吸附水溶液中鉛離子的研究
Adsorption of Lead Ion from Aqueous Solution using Peanut Hull Ash
指導教授: 林俊一
Chun-I Lin
口試委員: 施信民
none
李振綱
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 85
中文關鍵詞: 花生殼灰
外文關鍵詞: peanut hull ash, lead
相關次數: 點閱:178下載:3
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  • 本實驗中,將花生殼置於方形高溫爐中,在500℃煅燒30分鐘,製成花生殼灰。利用感應耦合電漿質原子發射光譜儀、掃描式電子顯微鏡、表面積測定儀、密度測定儀、粒徑分佈儀、水份天平及pH計對花生殼灰進行組成分析及物理性質之觀察或測定。
    接著,以花生殼灰當吸附劑,對含鉛離子水溶液進行吸附,實驗結果發現,以去除速率及平衡去除量來看,花生殼灰都是良好的吸附劑。另外,我們發現,降低花生殼灰劑量或提高鉛起始濃度有利於鉛離子的去除。在高花生殼灰劑量, 3.0 g/L下,pH值、震盪速率及吸附溫度不會影響吸附量。但是在低花生殼灰劑量, 0.2 g/L時,提高pH值或吸附溫度則會提升吸附量。
    另外,Langmuir吸附等溫式比Freundlich吸附等溫式更適合描述Pb2+/PHA的吸附。利用平衡吸附的數據算出了下面的熱力學參數: Kc、G、H、和S。
    擬二階速率式可合適的迴歸本實驗中的動力學數據,最後迴歸出一條鉛離子去除量和吸附時間的關係式。


    In this experiment, peanut hull was ashed at 500℃ for 30 minutes. The content and the physical properties of peanut hull ash (PHA) was analyzed using an inductively coupled plasma atomic emission spectrometry, a scanning electron microscope (SEM), a surface area analyzer, a density meter, amoisture determination balance and a pH meter.
    PHA thus produced was found to be effective in removing lead(II) ion from aqueous solution. Experimental results indicated both the rate of removal and the removal at equilibrium were increase with decrease PHA dosage or increase initial lead concentration. pH, stroke speed and adsorption temperature, however were found to have no effect on the rate of removal and removal at equilibrium for the high PHA dosage, 3.0 g/L . High value of pH or adsorption temperature, however, might increase the removal for the low PHA dosage, 0.2 g/L. The data obtained at equilibrium were better represented by the Langmuir isotherm than the Freundlich one. Thermodynamic parameters for the adsorption process. That is Kc, G, H and S have also been calculated.
    The overall process was found to be suitably interpreted by pseudo-second-order rate equation. An empirical relationship between the removal of Pb2+ and adsorption time was also determined.

    目錄 中文摘要 Ⅰ 英文摘要 Ⅱ 誌 謝 Ⅲ 目 錄 Ⅳ 圖表索引 Ⅵ 第一章 緒論 1 第二章 文獻回顧 3 2.1 廢水 3 2.2 花生殼的性質 4 2.3 以花生殼及其衍生物吸附水溶液中鉛離子 5 2.4 吸附原理 6 2.4.1 吸附動力學 7 2.4.2 吸附等溫式 11 2.4.3 吸附速率式 13 第三章 實驗部份 18 3.1 氣體、藥品及吸附劑 18 3.2 一般實驗設備 19 3.3 花生殼灰組成及物性測定儀器 20 3.4 實驗步驟 22 3.4.1 花生殼灰的製備 23 3.4.2 分析花生殼灰的組成及物性的量測 23 3.4.2.1 感應耦合電漿質原子發射光譜儀 23 3.4.2.2 掃瞄式電子顯微鏡 24 3.4.2.3 表面積測定儀 25 3.4.2.4 密度測定儀 26 3.4.2.5 粒徑分佈儀 27 3.4.2.6 水份天平 28 3.4.2.7 pH計 28 3.4.3 鉛離子溶液的調配 29 3.4.3.1 鉛離子溶液的調配步驟 29 3.4.3.2 鉛離子溶液的pH測定 29 3.4.4 吸附實驗 30 3.4.5 水溶液中鉛離子濃度的量測 31 3.4.5.1 鉛標準液的配置步驟 32 3.4.5.2 鉛離子濃度的測定步驟 32 第四章 結果與討論 35 4.1 花生殼灰的組成和物性測量 35 4.1.1 花生殼灰中的金屬成份分析 35 4.1.2 花生殼灰的大小與形狀 35 4.1.3 花生殼灰的比表面積、比孔隙體積、及平均孔徑 36 4.1.4 花生殼灰的密度測量 36 4.1.5 花生殼灰之粒徑 36 4.1.6 花生殼灰的含水量 36 4.1.7 花生殼灰的pH值 36 4.2 吸附動力學 40 4.3 吸附熱力學 58 4.3.1 吸附等溫式 58 4.3.2 熱力學參數 60 4.4 吸附速率式 65 第五章 結論 72 參考文獻 73 附錄一 實驗數據 76 附錄二 作者簡介 84

    參考文獻

    Abou-Mesalam, M.M., “ Sorption Kinetics of Copper, Zinc, Cadmium and Nickel Ions on Synthesized Silico-Antimonate Ion Exchanger ”, Colloids Surf. A, 225, 85-94 (2003).
    Aharoni, C. and F. C. Tompkins, “ Kinetics of Adsorption and Desorption and Elovich Equation ”, in Elex, D.D., H. Pines, P.B. Weisz, (Eds.), Advances in Catalysis and Related Subjects, Vol. 21, Academic Press, New York, New York (1970).
    Ayala, J., F. Blanco, P. García, P. Rodriguez and J. Sancho,“ Asturian Fly Ash as a Heavy Metals Removal Material ”, Fuel, 77, 1147-1154 (1998).
    Bhattacharya, A. K. and C. Venkobachar, “ Removal of Cadmium (II) by Low Cost Adsorbents ”, J. Environ. Eng., 110, 110-122 (1984).
    Brown, P., I. A. Jefcoat, D. Parrish, S. Gill and E. Graham,“ Evaluation of the Adsorptive Capacity of Peanut Hull Pellects for Heavy Metals in Solution ”, Adv. Environ. Res., 4, 19-29 (2000).
    Choy, K. K. H., D. C. K. Ko, C. W. Cheung, J. F. Porter and G. McKay, “ Film and Intraparticle Mass Transfer during the Adsorption of Metal Ions onto Bone Char ”, J. Colloid Interface Sci., 271, 284-295 (2004).
    Daifullah, A. A. M., B. S. Girgis and H. M. H. Gad, “ Utilization of Agro-Residues (Rice Husk) in Small Waste Water Treatment Plants ”, Mater. Lett., 57, 1723-1731 (2003).
    Dimitroval, S. V. and D. R. Mehandgiev, “ Lead Removal from Aqueous Solutions by Granulated Blast-Furnace Slag ”, Wat. Res., 32, 3289-3292 (1998).
    Eligwewe, C. A., N. B. Okolue, C.O. Nwambu and C.I.A. Nwoko, “ Adsorption Thermodynamics and Kinetics of Mercury(Ⅱ), Cadmium(Ⅱ) and Lead(Ⅱ) on Lignite ”, Chem. Eng. Technol., 22, 45-49 (1999).
    Guo, Y., J. Qi, S. Yang, K. Yu, Z. Wang and H. Xu., “ Adsorption of Cr(Ⅵ) on Micro- and Mesoporous Rice Husk-Based Active Carbon ”, Mater. Chem. Phys., 78, 132-137 (2002).
    Gupta, V. K., A. Rastogi, M. K. Dwivedi and D. Mohan, “ Process Development for the Removal of Zinc and Cadmium from Wastewater using Slag – A Blast Furnace Waste Material ”, Sep. Sci. Technol., 32, 2883-2912 (1997).
    Gupta, V. K. and I. Ali, “ Utilisation of Bagasse Fly Ash ( a Sugar Industry Waste) for the Removal of Copper and Zinc from Wastewater ”, Sep. Purif. Technol., 18, 131-140 (2000).
    Gürses, A., Ç. Dogar, M. Yalçın, M. Açıkyıldız, R. Bayrak and S. Karaca,“ The Adsoption Kinetics of the Cationic Dye, Methylene Blue, onto Clay ”, J. Hazard. Mater., B131, 217-228 (2006).
    Ho, Y. S. and G. Mckay, “ The Sorption of Lead(II) Ions on Peat ”, Wat. Res., 33, 578-584 (1999).
    Ho, Y. S., J. C. Y. Ng and G. Mckay, “ Removal of Lead(II) form Effluents by Sorption on Peat Using Second-Order Kinetics ”, Sep. Sci. Technol., 36,241-261 (2001).
    Huang, C. P. and E. A. Rhoads, “ Adsorption of Zn (II) onto Hydrous Aluminosilicates ”, J. Colloid Interface Sci., 131, 289-306 (1989).
    Johns M. M., W. E. Marshall and C. A. Toles, “ Agricultural By-products as Granular Activated Carbons for Adsorbing Dissolved Metals and Organics ”, J. Chem. Technol. Biotechnol., 71, 131-140 (1998).
    Kalavathy, M. H., T. Karthikeyan, S. Rajgopal and L. R. Miranda, “ Kinetic and Isotherm Studies of Cu(II) Adsorption onto H3PO4-activated Rubber Wood Sawdusst ”, J. Colloid Interface Sci., 292, 354-362 (2005).
    Khalid, N., S.Ahmad, A. Toheed, and J. Ahmed, “ Immobilization of Arsenic on Rice Husk ”, Adsorpt. Sci. Technol., 16, 655-666 (1998).
    Lagergren, S., “ About the Theory of So-Called Adsorption of Soluble Substances ”, kungliga Svenska Vetenskapsakademiens. Handlingar, Band 24, 1-39 (1898).
    Li, Q., J. Zhai, W. Zhang, M. Wang and J. Zhou, “ Kinetic Studies of Adsorption of Pb(II), Cr(II) and Cu(II) from Aqurous Solution by Sawdust and Modified Peanut Husk ”, J. Hazard. Mater., 141, 163-167 (2007).
    Morris, C. J. and W. J. Weber, Wat. Pollut. Res., Proceedings of 1st International Conference on Water Pollution Research, 2, Pergamon Press, New York, New York, U.S.A., pp.213-216 (1962).
    Periasamy, K. and C. Namasivayam, “ Process Development for Removal and Recovery of Cadmium from Wasterwater by a Low-Cost Adsorbent: Adsorption Rate and Equilibrium Studies ”, Ind. Eng. Res., 33, 317-320 (1994).
    Randall, J. M., E. Hautala and G. McDonald, “ Binding of Heavy Metal
    Ions by Formaldehyde-Polymerized Peanut Skins ”, J. Appl. Polym.
    Sci., 22,379-387 (1978).
    Ruthven, D. M., “ Principles of Adsorption and Adsorption Process ”,
    John Wiley & Sons, New York, New York, U.S.A.(1984).
    Ricordel, S., S. Taha, I. Cisse and G. Dorange, “ Heavy Metals Removal by Adsorption onto Peanut Husks Carbon: Characterization, Kinetic Study and Modeling ”, Sep. Purif. Technol., 24, 389-401 (2001).
    Stumm, W., “ Chemistry of the Solid-Water Interface ”, John Wiley and Sons, New York, New York, U.S.A. (1992).
    Wang, L. H. and C. I Lin, “ Adsorption of Lead(II) Ion from Aqueous Solution Using Rice Hull Ash ”, Ind. Eng. Chem. Res., 47, 4891-4897 (2008).
    World Health Organization, Guidelines for Drinking-Water Quality, 3rd Ed., World Health Organization, Geneva, Switzerland, p.54 (2006).
    Young R. N., G. McDonald, J. M. Randall, “ Effect of Light Metal Ions
    on the Sorption of Heavy Metal Ions on Natural Polymers ”, J. Appl.
    Polym. Sci., 23, 1027-1035 (1979).
    王麗華,“以稻殼灰吸附水溶液中重金屬離子的研究”,國立台灣科技大學化學工程系博士論文(2008)。
    林敬智,“下水汙染灰渣應用於銅離子去除之初步探討”,國立中興大學環境工程研究所碩士論文 (2001)。
    徐玉標,“重金屬汙染知多少?”,科學月刊,第233期 (1989)。
    蔡嘉仁,“廢棄活性白土對水溶液中重金屬之吸附特性研究”,義守大學材料科學與工程學系碩士論文 (2005)。

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