本論文主要以熱注射法與高溫熱裂解法合成I-III-VI族的材料，希望往後能運用在
太陽能元件上。藉由紫外光/可見光吸收光譜圖、光激發螢光圖譜及載子生命量測系統
分析其材料的光學性質，並搭配穿透式電子顯微鏡影像、掃描式電子顯微鏡影像及X光
繞射圖譜了解晶體的結構。

第一部分：
首先，藉由合併有向性堆積與配體兩種概念去控有效制晶體的形狀，並進一步
合成一維及三維結構的CuInSe2晶體。本實驗主要是利用三辛基氧化磷、三辛基化磷
和脂肪胺當成表面配體及反應溶劑形成穩定成長的環境，並在不同條件下合成不一
樣的結構。實驗中發現三辛基氧化磷與三辛基化磷會減緩成核的速度；脂肪胺則會
有效的活化前驅物而導至加速成核的速度，因此透過這兩種成核速度不同的機制控
制成核成長的速度而獲得規則的CuInSe2奈米晶體。接著改變不同時驗的參數，如反
應溫度、反應時間和配體(如：一級胺、二級胺與三級胺)去控制晶體晶相和尺寸藉
此獲得理想的晶體。

第二部分：
藉由控制能隙大小來改變量子點放光波長。在CuInS2系統中，能隙受到量子侷限
效應影響，隨著粒徑變化而改變，並且隨著時間變化，放光波長逐漸紅位移，符合量子
效應的現象，並且藉由適度增加醋酸銦的比例可提高量子產率。將製備完的CuInS2量
子點以硬脂酸鋅前驅物做陽離子交換，達到合金結構，量子產率皆有增加的趨勢，可能
與表面缺陷的修補有很大的關係。透過XPS去確認被鋅所取代的陽離子，且進一步去
證實放光波長藍位移的原因。

In this paper, the I-III-VI group material are prepared by hot-injection and thermal
decomposition, and then hope to use the solar cell in the furture. To comprehend optical and
crystal structure properties through UV-vis absorbance spectra, photoluminescence spectra,
carrier lifetime analysis system, transmission electron microscopy, scanning electron
microscopy and X-ray diffraction spectra.

First part：
This paper reports a synthetic route to CuInSe2 (CISe) ternary 3D and 1D nanostructure
with a controlled shape by combining a oriented attachment and ligand protection strategy. A
mixture of trioctylphosphine oxide (TOPO), trioctylphosphine (TOP) and aliphatic amine used
as both a capping agent and a reaction solvent was found to be vary suitable for the preparation
of three-dimensional flower-like, branched multipod nanostructures, and one-dimensional
nanowires, under various growth conditions. TOPO/TOP were found to retard the nucleation
process, and amine could be used as an activation agent by coordinating it with precursors to
assist with fast nucleation. By taking advantage of these two mechanisms (retarding and
activating reaction), the rate of the nucleation process could be regulated and CISe nanoflowers
could be obtained. Comparison of various experiments show that several experimental
parameters, such as reaction temperature, time, and several capping ligands (primary,
secondary, and tertiary amines) play important roles in the control of the motphology and size
of CISe nanostructures.

Second part：
This paper reports techniques of changing the peak wavelength by control the energy gap
of quantum dots. In CuInS2 system, tuning of the energy gap with changes in the quantum dots
size by quantum confinement effects, and the peak wavelength is red shift with time, it is
consistent with quantum confinement effects, and then increase moderately in the fraction of
indium acetate that can increase the quantum yields. In the CuInS2, the zinc stearate precursor
is added to achieve cation exchange and complete the alloy structure. Quantum yield is on the
increase , the surface defect states may be relevant. XPS spertra can check the cation replaced
by zinc stearate, and promise peak wavelength blue shift occurs in the system.

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