研究生: |
江昆達 Kwun-Da Juang |
---|---|
論文名稱: |
奈米級及次微米級核殼型橡膠添加劑及蒙特納石黏土對苯乙烯/乙烯基酯/特用添加劑三成份系之聚合固化反應動力及玻璃轉移溫度之影響研究 Effects of nano-scale and submicron-scale core-shell rubber additives, and montmorillonite clay on the cure kinetics and glass transition temperatures for styrene/ vinyl ester /additive ternary systems |
指導教授: |
黃延吉
Yan-Jyi Huang |
口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 330 |
中文關鍵詞: | 核殼橡膠 、未飽和聚酯 |
外文關鍵詞: | reactive microgel, core-shell rubber |
相關次數: | 點閱:259 下載:2 |
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本文之目的,乃探討三種特用添加劑,分別為:(1) 反應性微膠顆粒(2)奈米級與次微米級核殼型橡膠(core-shell rubber)添加劑及(3)矽烷改質蒙特納石黏土(montmorillonite clay,MMT),其對苯乙烯/不飽和樹脂/特用添加劑三成份系統之聚合固化動力及玻璃轉移溫度影響。吾人利用微分掃描熱分析儀(DSC)及傅立葉轉換紅外光譜儀(FTIR)測量ST/UP/additive三成份系在聚合固化過程中之反應動力。最後依據Takayanagi機械模式,ST/UP/additive三成份系聚合固化後的樣品,其在各相區之玻璃轉移溫度,吾人亦以動態機械測定儀(DMA)測量之。
The effects of reactive microgel (RM) and nano-scale and sub-micron scale core shell rubbers (CSR) as low-profile additives (LPA), and silane treated montmorillonite clay (MMT) on the cure kinetics and glass transition temperatures for styrene/unsaturated polyester/additive ternary systems have been investigated. The reaction kinetics for the ST/UP/additive ternary system during the cure was measured by differential scanning calorimetry (DSC) and Fourier transform infrared spectrometry (FTIR). Finally, based on the Takayanagi mechanical models, the glass transition temperature in each region of the cured samples for ST/UP/additive ternary systems has been measured by the dynamic mechanical analysis (DMA).
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