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研究生： 莊靖恆
Ching-Heng Chuang
論文名稱： 分支聚乙烯混摻共軛高分子之表面型態與電子性質之分析暨合成自修復彈性無規共聚物
Morphology and Electronic Properties of Semiconducting Polymer and Branched Polyethylene Blends and the synthesis of Self-Healing and elastic random copolymer
指導教授： 邱昱誠
Yu-Cheng Chiu
口試委員: 童世煌
Shih-Huang Tung
江偉宏
Wei-Hung Chiang
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2019
畢業學年度： 108
語文別： 英文
論文頁數： 88
中文關鍵詞： 共軛高分子 、溶劑添加劑 、有機場效電晶體 、自修復彈性體 、熱交聯 、氫鍵
外文關鍵詞： conjugated polymer, solvent additive, organic field-effect transistors, self-healing elastomer, thermal annealing crosslinking, hydrogen bonding
相關次數： 點閱：232  下載：0 
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    • Abstract i 中文摘要 iv Contents vi Table Captions vii Figure Captions viii Chapter 1. Morphology and Electronic Properties of Semiconducting Polymer and Branched Polyethylene Blends 14 1.1. Introduction 14 1.2. Experimental Sections 18 1.2.1. Materials 18 1.2.2. Device Fabrication 18 1.2.3. Characterization 19 1.3. Result and Discussion 21 1.3.1. UV-Vis spectroscopy to get insight on the aggregation behavior and optical properties 22 1.3.2. Atomic Force Microscopy (AFM) to characterize the morphology….. 24 1.3.3. X-ray diffraction (XRD) to investigate the solid-state packing…………. 27 1.3.4. Electronic properties of P(DPPTVT) / BPE 28 1.3.5. P(DPPTVT)/BPE in highly dilute solution. .31 1.4. Conclusion 35 Chapter 2. The Synthesis of Self-Healing and Elastic Random Copolymer 50 2.1. Introduction 50 2.2. Experimental Sections 53 2.2.1. Materials and design 53 2.2.2. Characterization 54 2.2.3. Synthesis of PBA-co-PNMA diblock copolymers 55 2.2.4. Self-Healing test 57 2.2.5. Hysteresis test 57 2.3. Results and Discussion 58 2.3.1. Characterization of the copolymer 58 2.3.2. Mechanical properties 60 2.3.3. Self-Healing properties 62 2.3.4. Hysteresis and self-recovery 63 2.3.5. Mechanical properties copolymer in the thin film form 65 2.4. Conclusions 67 References 78

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