在本文中，疏水2,2,6,6-四甲基-1-哌啶氧自由基（TEMPO）-氧化纖維素奈米纖維凝膠通過醯胺化方式製備而成，再加入ZnO nws ，ZnO nps ，carbon dots ，使其凝膠具有電容性，進而合成出具有電容性的疏水2,2,6,6-四甲基-1-哌啶氧自由基（TEMPO）-氧化纖維素奈米纖維薄膜。通過傅立葉轉換紅外光譜、紫外線可見光透射率、接觸角和在水中的穩定性來確認膜的改性、光學性質、疏水性和電容的效果。膜的透射率從87％降低至41％，加入ZnO nws ，ZnO nps ，carbon dots 後透射率從85%降低至10%以下，然而電容度卻有所提升，加入ZnO NW 的輸水膜擁有最低的電阻優勢，而加入ZnO接觸角也有所上升，表明疏水性增加且膜在水中變得非常穩定。因此，這些結果表明成功地合成耐水和疏水且具電容度的纖維素膜。

In the thesis, the hydrophobic film which has the best conductivity was synthesize.
The hydrophobic 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO)-oxidized cellulose nanofiber gel was prepared by amidation reaction. Then different ratio of ZnO nanowires, ZnO nanoparticles and Carbon dots were added to find the best conductive film which has hydrophobic property.
The modification, optical property, hydrophobicity and conductivity property of the films were confirmed with Fourier transform infrared absorption, ultraviolet-visible transmittance, contact angle, stability in water and electrochemical impedance spectroscopic measurements. After adding ZnO nanowire, ZnO Nanoparticle and carbon dots, the transmittance decreased from 85% to less than 10%. However, lifetime of an electron in films which embedded ZnO and carbon dots increased. The film with ZnO nanowires had the longer lifetime of an electron. It means the film embed ZnO nanowire has larger charge transfer and better conductivity. The contact angle of films increased after adding the ZnO, indicating the increase of the hydrophobicity. Then, the films were very stable in water. Thus, these results indicate that water resistant, hydrophobic and conductive cellulose film was successfully synthesized by adding ZnO.

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