本研究旨在建立一完整高分子奈米溶液分散穩定性鑑定技術系統與多功能性塗膜之物化性及其應用之分析。由利用高分子溶液經導入奈米粒子形成高分子複合奈米溶液或亦高分子溶液經由發泡技術形成高分子微泡溶液以達到多功能性塗膜之應用，以配方之設計與材料加工參數的相關性取得最佳穩定性奈米溶液配比，並使用奈米分散穩定性鑑定儀LUMiSizer之S.T.E.P原理分析多功能性奈米溶液在其不同組成物濃度下之分散性及穩定性之影響效應和其儲存壽命，與粒子、微泡含量及處理加工時間對溶液分散穩定性之影響，而由穿透率對其相對時間之關係圖，可得知粒子及微泡在多功能性奈米塗料中的物理性質，進而求得粒子及微泡在奈米分散液之粒徑分佈，經由SEM、DLS、Zeta potential結果交叉認證建立其完整系列評估之鑑定技術。並評估多功能奈米塗膜之性能與其應用之成效。本研究大致分為三部分以探討S.T.E.P在多功能性奈米溶液之分析應用，及其功能性之效能。

本研究第一部分之內容聚焦於藉由奈米分散穩定性鑑定儀LUMiSizer之S.T.E.P原理評估高分子複合奈米溶液之分散穩定性及儲存壽命，進而取得其最佳化配方以利塗膜之應用。實驗中使用UV光硬化樹脂之液相高分子基材製備複合奈米溶液，並導入功能性奈米粒子以達到功能性塗膜之功用，而探討其組成物參數對奈米粒子在於高分子溶液中分散穩定性的影響，其結果經由交叉印證以建立S.T.E.P分析方法之可靠度。由實驗結果得知，分散劑/增黏劑之比例為影響分散穩定性之關鍵，分散劑添加之比例提高其奈米分散液穩定性提升，反之，增黏劑之比例提高其奈米分散液穩定性下降，粒徑分佈結果顯示，平均粒徑愈小其奈米粒子在高分子基材中不易團聚為分散穩定性愈佳，介面電位絕對值愈大，儲存壽命愈長，其實驗結果與DLS、SEM之結果相互印證為建立S.T.E.P之準確性。

本研究第二部分之內容聚焦於探討水溶性高分子聚氨酯微泡溶液在醫療封裝材之研究及其應用，並利用奈米分散穩定性鑑定儀LUMiSizer之S.T.E.P原理評估其微泡穩定性及建立發泡密度對於微泡穩定性之影響。實驗中以水溶性高分子聚氨酯溶液經由發泡機制製備不同發泡密度之微泡溶液並塗佈於醫療包裝基材為熱封膠之應用，進一步探討其塗膜後之抗沾黏、柔軟度、耐候試驗之特性並其與LLDPE膜熱封後包裝材之剝離強度和透氣度之效能。由實驗結果得知，水溶性高分子聚氨酯微泡溶液之發泡密度愈高其微泡穩定性愈高，微泡分佈愈廣而尺寸愈小。而塗膜後之抗沾黏可達到<1 g/cm2，附著性為5B，抗刮性為HB，高柔軟度，黃化指數小於5之特性，熱封包裝材之剝離強度和透氣度隨著水溶性高分子聚氨酯微泡溶液之發泡密度提高而增加，其結論為實並與SEM之結果交叉驗證。

本研究第三部分之內容聚焦於製備UV光硬化奈米複合導電膜並利用奈米分散穩定性鑑定儀LUMiSizer之S.T.E.P原理探討其導電奈米粒子在其塗佈溶液之分散穩定性及粒徑分佈。實驗中以原位聚合法製備聚吡咯導電粒子並分散於UV光硬化樹脂之液相高分子基材，再者導入碳黑及碳管奈米粒子以協同作用提高其導電度，進一步探討不同導電奈米粒子複合作用對其分散穩定性、導電度、熱穩定度及耐候穩定性之特性，其實驗結果與DLS、SEM之結果相互印證為建立S.T.E.P對於複合粒子效應之準確性。由實驗結果得知，單一聚吡咯導電溶液為分散穩定性最佳，而三相複合導電溶液因產生團聚為分散穩定性最差，其相符為介面電位測定之結果，而由LUMiSizer測定之粒徑分佈與其DLS、SEM測定之結果相同，因碳黑及碳管粒子的協同作用，使其三相複合導電膜之導電率可達到1×10-3 S/cm，其熱穩定性為最佳，附著性為5B，抗刮性為4H-5H。三相複合導電溶液經超音波處理，其導電率可達至0.45 S/cm，平均粒徑愈小。

由上述實驗結果得知，奈米分散穩定性鑑定儀LUMiSizer利用其S.T.E.P技術可即時及準確地得知奈米粒子在其多功能性高分子奈米溶液之分散情形，根據如此在塗佈工業應用上，可帶來產品之研究開發及品管之重大貢獻。

In this study, we aim to establish a complete dispersibility analysis system for polymeric nanosolution, and analyzing of properties and applications for multifunctional coatings as well. The synthesis of multifunctional coatings is by adding nanoparticles into polymeric solution or using foaming technique to obtain polymeric micro-foam solution. The great stable of nanosolution is obtained by optimizing materials selection and processing parameter. The multisample analytical centrifuge (LUMiSizer, L.U.M. GmbH, Berlin Germany) used in this study employs S.T.E.P technology (Space and Time resolved Extiction Profile), which allows to measure the intensity of the transmitted light as function of time and position over the entire sample length simultaneously. While the variation of the light extinction curves after centrifugal segregation provided a qualitative description, a rigorous formulation can provide detailed quantitative characterization. By this method, the dispersibility and shelf life of multifunctional nanosolution and effects of nanoparticles content and processing time on dispersiblity can be characterized easily. It also determines the particle size distribution of multifunctional coatings; the results were comparable with those obtained using dynamic light scattering, scanning electron microscope and zeta potential analysis. This study has addressed three parts respectively to discuss the applications of S.T.E.P technology on analyzing multifunctional nanosolution and evaluating the performances.

Part (i) describes the dispersibility and particle size distributions of nanocomposite coatings. The LUMiSizerR analytical centrifuge with STEP technology can determine the particle dispersion and size distribution of multisample organic/inorganic composite coatings. The stability of the coatings increases upon increasing the dispersant concentration, and decreases upon increasing the binder concentration. Dispersibility measurements reveals that the coating sample with higher dispersant concentration exhibits the best stabilizing performance without agglomeration, due to its lowest sedimentation rate, determining through shelf-life predictions with the LUMiSizerR and its highest absolute zeta potential. The dispersibility results obtain from the zeta potential and LUMiSizerR data are consistent and precise. Using DLS and SEM to determine PSDs provided results that are similar to those obtained using the LUMiSizerR. The particle sizes decrease with high dispersibility and increase with low dispersibility.

Part (ii) describes the stability and application in medical packaging of polyurethane foam coatings. The preparation of PUFs with various foam densities are through mechanical foaming and then coated PUFs of different foam densities onto TyvekR medical paper at different thicknesses. The PUF coating with higher foam density has the highest stability. SEM imagings reveal that the cell size of the PUF coats decrease and the cell density of the PUF coats increase upon increasing the foam density respectively. The PUF coat with higher foam density exhibits low tackiness (<1 g/cm2), high adhesion (5B), high scratch resistance (HB), high flexibility (passes), and high durability ( 5).The peel strength increases upon increasing the foam density of the PUF coats and decreases upon increasing the coating thickness of the PUF coats. The SEM images of peeled seal surfaces are consistent with the mechanical properties of heat seals. The air permeability of these medical pouches increases upon increasing the foam density and cell density of the PUF coats.

Part (iii) describes the in-situ synthesis and stability of conductive nanocomposite coatings by uv-induced polymerization.The UV-cured conductive nanocomposite coatings containing hybrid nanoparticles of PPy, CB and CNT are developed. Poly (pyrrole) is synthesized using chemical oxidation method and well-dispersed into polymer matrix. The stability and particle size distribution of nanocomposite coatings are investigated by LUMiSizerR, and the results were in good agreement with that of DLS and Zeta potential, which PPy coating showed the greatest stability and smallest particle size without agglomerates. The morphology measurements by SEM indicateds the aggregates of particles in the hybrid coatings resulting in the larger particle size and border particle size distribution. In the conductivity, the PPy/CB/CNT hybrid coat had highest conductivity (1×10-3 S/cm). Apart from the improvement in the electrical conductivity, the thermal stability also enhanced with addition of nanoparticles, even the PPy/CB/CNT nanocomposite coats exhibit great durability to the adhesion of the 5B level value, and scratch of 4H-5H value. Moreover, the PPy/CB/CNT nanocomposite through ultrasonication resulted in higher conductivity (0.45 S/cm) and smaller particle size (310 nm).

From previous experimental results, the LUMiSizerR with S.T.E.P technology via analytical centrifuge allows the characterization of dispersed particles to better understand the underlying dispersiblity mechanisms. The approach can also provide objective direct assessments and quantified analyses of separation phenomena in coating systems for R&D and product control.

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