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研究生： 何旻致
Min-Chih Ho
論文名稱： 應用連續式熱裂解反應系統處理酯化製程廢棄物之研究
Study on Treatment of Residues of Esterification Process via Continuous Pyrolysis System
指導教授： 曾堯宣
Yao-Hsuan Tseng
口試委員: 顧洋
Young Ku
蔡伸隆
Shen-Long Tsai
李豪業
Hao-Yeh Lee
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2023
畢業學年度： 111
語文別： 中文
論文頁數： 90
中文關鍵詞： 固體廢棄物 、酯化製程 、熱裂解 、旋窯反應器
外文關鍵詞： solid waste, esterification process, pyrolysis, rotary kiln reactor
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    • 摘要 I ABSTRACT II 圖目錄 IX 表目錄 XI 第一章 緒論 1 1.1 前言 1 1.2 研究動機 3 第二章 文獻回顧 4 2.1 熱化學轉化技術的種類 4 2.1.1 燃燒化學反應技術 4 2.1.2 氣化化學反應技術 4 2.1.3 熱裂解反應技術 5 2.1.4 熱化學資源化技術比較 6 2.2 熱裂解技術於不同溫度特性比較 8 2.2.1 慢速裂解 9 2.2.2 快速裂解 9 2.2.3 閃速裂解 10 2.3 高分子熱裂解機制 11 2.3.1 生物質熱裂解機制 12 2.3.2 聚丙烯酸酯與丙烯酸鈉裂解機制 13 2.3.3 裂解產物生成機制 13 2.4 熱裂解化學反應器簡介 15 2.4.1 固定床反應器 15 2.4.2 流體化床反應器 16 2.4.3 燒蝕反應器 17 2.4.4 微波反應器 18 2.4.5 電漿反應器 19 2.4.6 真空熱裂解反應器 20 2.4.7 旋轉錐反應器 21 2.4.8 螺桿反應器 22 2.4.9 迴轉窯反應器 23 2.4.10 熱裂解反應器比較 24 2.5 熱裂解產物後處理技術 26 2.5.1 粒狀汙染物捕集原理 26 2.5.2 粒狀汙染物控制設備 27 2.5.3 酸鹼氣體污染防治設備 31 第三章 研究方法 34 3.1 實驗規劃 34 3.2 實驗藥品 36 3.3 實驗設備與分析儀器 36 3.3.1 實驗設備 36 3.3.2 分析儀器 37 3.4 熱裂解系統 39 3.4.1 批次熱裂解反應器 39 3.4.2 連續式熱裂解反應器 41 第四章 結果與討論 43 4.1 原料特性分析及熱裂解可行性評估 43 4.2 批次熱裂解系統 45 4.2.1 裂解溫度於批次系統中對產物之影響 45 4.2.2 反應時間於批次系統中對產物之影響 50 4.2.3 載氣流量於批次系統中對於產物之影響 52 4.3 連續式熱裂解系統 53 4.3.1 連續式反應器設計 53 4.3.2 裂解溫度於連續系統中生成產物之影響 57 4.3.3 顆粒屬性於連續系統中裂解效能之影響 60 4.3.4 滯留時間於連續系統中裂解程度之影響 61 4.3.5 連續式反應器最佳連續操作參數 62 4.3.6 丙烯酸濃縮固廢裂解後固體產物分析 63 4.4 連續式熱裂解系統操作成本及經濟效益評估 66 第五章 結論與未來展望 68 5.1 結論 68 5.2 未來展望 71 第六章 參考文獻 73

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