本文探討以不飽和聚酯樹脂(UP)與苯乙烯(ST)為共單體，利用無乳化劑之乳化聚合法合成出反應性微膠顆粒(reactive microgels，RM)，用來當作不飽和聚酯之抗體積收縮劑(low-profile additive，LPA)。吾人並探討反應性微膠顆粒(RM)其顆粒大小、及其顆粒表面及內部的C=C雙鍵數，對ST/UP/RM三成份系在低溫300C聚合固化後之SEM微觀型態結構之影響。
本文中，吾人亦探討核心為PBA(聚丙烯酸正丁酯)，外殼為PMMA之奈米級壓克力核殼型橡膠增韌劑(CSR)，其顆粒大小及外殼化學組成對苯乙烯(ST)/不飽和聚酯(UP)/(CSR)其三成份系1100C聚合固化後成品之機械性質的影響。

Reactive microgels(RM)-based low-additive profiles(LPA), which were made from unsaturated polyester (UP) and styrene (ST), were synthesized by soapless emulsion polymerizations. The effects of particle size and the number of C=C bonds on the surface and the interior of RM on the sample morphology cured at 300C as observed by scanning electron microscopy (SEM) have been investigated.
In this work, the effects of particles size and the shell chemical composition of the nano-scale acrylic type of core-shell rubbers (CSR), as toughneners for UP resins, on the mechanical properties of the ST/UP/CSR ternary systems after the cure at 1100c have also been explored.

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