本論文係針對有機/無機混成材製備及其對織物機能化加工應用進行研究；研究共分成三大部分，第一部分首先製備氟碳共聚合物及其混成材，經以各種儀器分析發現氟碳聚合物確實能與SiO2產生氫鍵結合而製成混成材，由於無機相SiO2之加入，而使混成材之孔洞及表面積亦隨之增加，同時以TGA檢測四種成品之熱穩定性依序為氟碳共聚合物/ SiO2混成材 >氟碳聚合物/ SiO2混成材 >氟碳共聚合物 >氟碳聚合物。第二部分將上述四種氟碳共聚合物或其混成材在不同加工流程及方式下對棉織物行潑水、潑油加工，探討其對加工織物性質之影響，經研究結果得知，以氟碳共聚合物處理之加工布具有最大之潑水、潑油接觸角，獲得最佳之潑水、潑油效果，而以氟碳共聚合物/ SiO2行同浴處理之加工織物強力最佳，但其柔軟性較差。另以合成之藥劑做加工時，其加工方式或順序對加工布之接觸角及白度影響並不是很大，但對強力卻有明顯的影響，在耐水洗堅牢度方面，在經過十次水洗後加工布之接觸角僅降低3%左右。綜合而言，先以TEOS預處理再施予氟碳聚合物處理之加工布，會具有較佳的物理性能。第三部分係藉由溶膠-凝膠法，以不同重量比之TEOS/VTES與Chitosan製成有機/無機混成材料，經FTIR及NMR分析確認有機/無機混成材內之Chitosan與SiO2間會形成氫鍵結合，並於表面形態分析發現較多VTES與TEOS添加後，由於Chitosan表面覆蓋一層均勻無機相SiO2互穿網路結構，使得Chitosan混成材隨著VTES/TEOS重量比增加而具有含量較高的矽、碳、氧原子含量及較佳的耐熱性、抗紫外線效果等，惟Chitosan-VTES/SiO2混成材隨著TEOS添加量達到2.4克時，其機械性質出現不升反降的結果。

There are three parts in this thesis. The first part is to prepare a fluorocarbon polymer and its hybrid materials. It is found that fluorocarbon copolymers can produce hydrogen bonds with SiO2 to form hybrid materials. Thermogravimetric (TGA) is used to test the thermostabilities of the four products, which are ranked as follows: fluorocarbon copolymer/SiO2 hybrid material > fluorocarbon polymer/SiO2 hybrid material > fluorocarbon copolymer > fluorocarbon polymer. In addition, it is found that, due to the inorganic SiO2 used, the number of pores and the specific surface areas of the hybrid materials both increased. In the second part, different procedures are used to study water and oil repellent effect on cotton fabrics with fluorocarbon copolymer or its hybrid materials. The experimental results indicate that fabric treated with fluorocarbon copolymer have larger contact angle for water and oil repellent finish, and the fabric treated with simultaneous bathing of fluorocarbon copolymer/ SiO2 are the strongest but have poorer softness. Furthermore, when processing with chemical compounds, the processing methods and steps have little effect on the fabric’s angle of contact and bleaching, but have more significant influence on strength. Regarding washing fastness, after ten-time water washing, the angle of contact of treated fabrics decreased by about 3% only. Overall, the fabric pre-treated with TEOS, followed by fluorocarbon polymer, has the best balance of physical properties. In the third part, the study explores the strength and thermal properties of various hybrid materials that are made of Tetraethoxysilane/Vinyltriethoxysilane (TEOS/VTES) and Chitosan in different weight ratios. It is confirmed, from Micro Fourier transform infrared (Micro FT-IR) and nuclear magnetic resonance (NMR) analysis, that hydrogen bonds emerging between Chitosan and SiO2 in hybrid materials. With the addition of more VTES and TEOS, the surface of the hybrid material features thick granules. In addition, the mechanical performance and thermostability of both types of hybrid are better than pure Chitosan. The former is enhanced with an increasing amount of TEOS until it exceeds 2.4 g and the latter is also improved with an increasing amount of TEOS.

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