研究生: |
蕭福田 Fu-Tien Hsiao |
---|---|
論文名稱: |
迷你乳化聚合反應及其在疏水性材料之應用 Miniemulsion Polymerization and The Resultant Hydrophobic Polymeric Materials |
指導教授: |
陳崇賢
Chorng-Shyan Chern |
口試委員: |
邱文英
Wen-Yen Chiu 林析右 Shi-Yow Lin 許榮木 Jung-Mu Hsu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2006 |
畢業學年度: | 94 |
語文別: | 中文 |
論文頁數: | 104 |
中文關鍵詞: | 接觸角 、撥水性 、迷你乳化 |
外文關鍵詞: | Contact Angle, Hydrophobicity, Miniemulsion Polymerization |
相關次數: | 點閱:179 下載:6 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究以SDS作為界面活性劑,Na2S2O8為起始劑,MMA (或STY )為單體進行迷你乳化聚合反應,藉由改變共同界面活性劑SMA濃度,來探討SMA在聚合反應結束後,對乳漿高分子表面之接觸角變化,以暸解迷你乳化聚合反應是否可應用在生產疏水性材料。
以不同SMA /單體比例製備之乳漿粒子經甲醇清洗、塗佈成膜之高分子表面,隨著SMA含量的增加,接觸角隨之變大。其中當SMA /單體比例達1 / 2時,高分子表面已能充份展現SMA之高疏水特性。但SMA濃度再增加時,高分子表面之接觸角則趨一定值。若改以較疏水之單體STY進行迷你乳化聚合反應時,在高SMA含量所呈現之接觸角卻較MMA / SMA Copolymer小。聚合反應機構與塗佈成膜時親疏水分子鏈段排列之差異性,致使STY / SMA Copolymer反倒無法呈現較高之接觸角,高分子表面之疏水性不如預期。將乳漿產品分別以甲醇、超純水與未經任何清洗程序處理。未清洗之乳漿粒子,在高SMA 含量之高分子表面雖已具有疏水性,但接觸角受SDS分佈之影響,其error bar較大,而以甲醇清洗之乳漿粒子,其高分子更能呈現固有的高分子表面特性,發揮SMA 所具有的高疏水能力。
Miniemulsion polymerizations with different concentrations of cosurfactant (stearyl methacrylate, SMA) were used to synthesize a series of SMA / monomer ( MMA or STY ) copolymers. Sodium dodecyl sulfate (SDS) was used as the surfactant, sodium persulfate (Na2S2O8) as the initiator, and MMA (or STY) as the monomer. The copolymers were then coated and dried on microscope slide glasses and contact angles of water on these polymeric films measured by sessile drop technique. The contact angle increases with increasing the SMA content of emulsion polymers. When SMA / monomer ratio is equal to 1 / 2, the polymer surface showed a high hydrophobic property. When the SMA / monomer ratio is above 1 / 1, the contact angle then leveled off. On the other hand, if using a more hydrophobic monomer STY to synthesize STY /SMA copolymers, the contact angle is smaller than that of MMA / SMA copolymer at higher SMA contents. The difference of the reaction mechanism and mobility of polymer chains affected the contact angles. Finally, the contact angles of polymers that was washed by methanol, ultrapure water and no treatment were determined. Polymer surfaces in the absence of treatment exhibited more hydrophobic properties only at higher SMA contents. On the other hand, polymer surfaces treated by methanol presented intrinsic hydrophobicity of SMA and exhibited excellent water resistance.
1.梁偉琪,碩士論文,國台灣科技大學化工所(2002)。
2.W. D. Harkins, J. Am. Chem. Soc., 69, 1428. (1947)
3.W. V. Smith, R. W. Ewart, J. Chem. Phys., 16, 529. (1948)
4.F. K. Hansen, J. Ugelstad, J. Polym. Sci., Polym. Chem. Ed., 16, 1953. (1978)
5.W. J. Priest, J. Phys. Chem., 56, 1077. (1952)
6.B. Jacobi, Angew. Chem., 64, 539. (1952)
7.R. M. Fitch, L. B. Shih, Prog. Colloid Polym. Sci., 56, 1. (1975)
8.R. M. Fitch, R. C. Watson, J. Colloid Interface Sci., 68, 14. (1979)
9.P. J. Feeney, D. H. Napper and R. G. Gilbert, Macromolecules, 17, 2520. (1984)
10.J. Ugelstad, M. S. El-Aasser and J. W. Vanderhoff, Polym. Lett., 11, 503. (1973)
11.J. Ugelstad, F. K. Hansen and S. Lange, Die Makromol. Chem., 175, 507. (1974)
12.A. W. Adamson, In Physical Chemistry of Surfaces, Fifth Ed, Wiley, New York. (1990)
13.S. Ross, I. D. Morrison, In Colloidal Systems and Interfaces, Wiley, New York. (1988)
14.D. H. Everett, In Basic Principles of Colloid Science, Royal Society of Chemistry, Cambridge. (1988)
15.J. Ugelstad, P. C. Mork, K. H. Kaggerud, T. Ellingsen and A. Berge, Adv. Colloids Interface Sci., 13, 101. (1980)
16.B. J. Chamberlain, D. H. Napper and R. G. Gilbert, J. Chem. Soc., Faraday Trans. I, 78, 591. (1982)
17.Y. T. Choi, M. S. El-Aasser, E. D. Sudol and J. W. Vanderhoff, J. Polym. Sci., Polym. Chem. Ed., 23, 2973. (1985)
18.A. Marmur, Colloids and Surfaces A, 116, 55. (1996)
19.T. S. Meiron, A. Marmur and I. S. Saguy, Journal of Colloid and Interface Science, 274, 637. (2004)
20.Mathilde Callies, David Qur, Journal of Materials Chemistry, 15, 55. (2005)
21.A. H. Hogt, D. E. Gregonis, J. D. Andrade and J. D. Andrade, Journal of Colloid and Interface Science, 106, 289. (1985)
22.黃寶瑤,碩士論文,國立台灣科技大學化工所 (1993)。
23.C. Allain, D. Ausserre, and F. Rondelez, Journal of Colloid and Interface Science, 107, 5. (1985)
24.D. Y. Kwok, A. W. Neumann, Advances in Colloid and Interface Science, 81, 167. (1999)
25.R. N. Wenzel, Ind. Eng. Chem., 28, 988. (1936)
26.J. Bachmann, A. Ellies and K. H. Hartge, Journal of Hydrology, 231, 66. (2000)
27.N. A. Patankar, Langmuir, 19, 1249. (2003)
28.A. Marmur, Langmuir, 19, 8343. (2003)
29.R. E. Johnson, R. H. Dettre, in: E. Matijevic (Ed.), In Surface and Colloid Science, Wiley-Interscience, New York. (1969)
30.A. Marmur, Advances in Colloid and Interface Science, 50, 121. (1994)
31.E. Chibowski, Advances in Colloid and Interface Science, 103, 149. (2003)
32.T. Yasuda, T. Okuno, Langmuir, 10, 2435. (1994)
33.Didem ner, Thomas J. McCarthy, Langmuir, 16, 7777. (2000)
34.J. E. Mark, In Polymer Data Handbook, New York:Oxford University Press. (1999)
35.D. F. S. Petri, J. Braz. Chem. Soc., 13, 695. (2002)
36.H. Y. Erbil, Langmuir, 10, 2006. (1994)
37.翁暢健,碩士論文,中原大學化學系 (2002)。
38.R. Arshady, Biomaterials, 14, 5. (1993)
39.B. Baradie, M. S. Shoichet, Macromolecules, 36, 2343. (2003)
40.B. A. Bezuglyi, O.A. Tarasov, and A. A. Fedorets, Colloid Journal, 63, 668. (2001)
41.C. J. Budziak, A. W. Neumann, Colloids and Surfaces, 43, 279. (1990)
42.Xina Xie, Norman R. Morrow, Colloids and Surfaces A, 138, 97. (1998)
43.N. Milman, J. K. Yoon and A. J. Hickey, Colloids and Surfaces B, 1, 315. (1993)
44.G. T. Smedley, D. E. Coles, Journal of Colloid and Science, 286, 310. (2005)
45.A. Siebold, M. Nardin and J. Schultz, Colloids and Surfaces A, 161, 81. (2000)
46.R. E. Ayala, E. Z. Casassa and G. D. Parfitt, Powder Technology, 51, 3. (1987)
47.W. Zhang, B. Hallstrm, Desalination, 79, 1. (1990)
48.A. Marmur, Colloids and Surfaces A, 136, 209. (1998)
49.J. Drelich, J. D. Miller and R. J. Good, Journal of Colloid and Interface Science, 179, 37. (1996)
50.H. S. Van Damme, A. H. Hogt and J. Feijen, Journal of Colloid and Interface Science, 114, 167. (1986)
51.W. Zhang, M. Wahlgren and B. Sivik, Desalination, 72, 263. (1989)
52.J. D. Andrade, In Surfaces and Interfacial Aspects of Biomedical Polymers, New York, Vol. 1. (1985)
53.G. L. Mack, J. Phys. Chem., 40, 159. (1936)
54.A. B. Ponter and A. P. Boyes, Can. J. Chem., 50, 2419. (1972)
55.C. Neinhuis, W. Barthlott, Annals of Botany, 79, 667. (1997)
56.Motohiro Okouchi, Yoshinao Yamaji and Kiyoshi Yamauchi, Macromolecules, 39, 1156. (2006)
57.劉育成,碩士論文,國立台灣科技大學化工所 (1998)。
58.張宏德,碩士論文,國立台灣科技大學化工所 (1999)。
59.Chern C.S., Polymerization of Monomer Emulsions, Encyclopedia of Surface and Colloid Science 1.1. ( 2005 )
60.S. Guruvenket, M. Komath, S. P. Vijayalakshmi, A. M. Raichur and G. M. Rao, Journal of Applied Polymer Science, 90, 1618. (2003)
61.K. Gotoh, Y. Nakata, M. Tagawa and M. Tagawa, Colloids and Surfaces A, 224, 165. (2003)
62.R. G. Craig, G. C. Berry and F. A. Peyton, J. Phys. Chem., 64, 541. (1960)
63.H. F. Webster, J. P. Wightman, Langmuir, 7, 3099. (1991)
64.D. Briggs, H. Chan, M. J. Hearn, D. I. McBriar and H. S. Munro, Langmuir, 6, 420. (1990)
65.J. Brandrup, E. H. Immergut, In Polymer Handbook, 3rd Edition, New York, Wiley. (1989)
66.蔡信行,聚合物化學(上),文京圖書有限公司 (1978)。
67.G. Karanikolopoulos, C. Batis, M. Pitsikalis and N. Hadjichristidis, Journal of Polymer Science: Part A, 42, 3761. (2004)
68.G. Stergiou, P. Dousikos and M. Pitsikalis, European Polymer Journal, 38, 1963. (2002)
69.J. Brandrup, E. H. Immergut and E. A. Grulke, In Polymer Handbook, 4th Edition, New York, Wiley. (1999)