我們合成出四種新型的側氟烷基-活性雙氟單體：螺旋-9- {2,7-雙[4-氟-3-三氟甲基苯基]芴}-2’-鑽石烷 (M1), 螺旋-9-{2,7-雙[4-氟-3-三氟甲基苯基]芴}-9’-芴 (M2), 2,7-雙[4-氟-3-三氟甲基苯基]-9,9-二苯基芴 (M3), 與螺旋-9-{2,7-雙[4-氟-3-三氟甲基苯基]芴}-9’- 10氧-蒽 (M4)。
這些新型單體利用苯環上的氟原子分別與數種不同的雙酚進行親核性取代反應，縮合為聚合物。在GPC的分析中，高分子的數目平均分子量(Mn)最高為1.28 105g/mol。其Td5%均在470oC以上。Tg均在241~355oC之間。聚合物的接觸角介於70~100o之間。這些高分子會溶於NMP, THF, CHCl3, DMAc, 與Toluene之中。
所有聚苯基醚聚合物都利用1H-NMR、13C-NMR來確定結構，並利用DSC、TGA、PL、contact angle、DEA來分析其物性。

Four novel 2-perfluoroalkyl-activated bisfluoro monomers, Spiro-9- {2,7-bis[4-fluoro-3-trifluoromethylphenyl]fluorene}-2’-adamantane (M1), Spiro-9-{2,7-bis[4-fluoro-3-trifluoromethylphenyl]fluorene}-9’-fluorene (M2),2,7-Bis[4-fluoro-3-trifluoromethylphenyl]-9,9-diphenylfluorene (M3), and Spiro-9-{2,7-bis[4-fluoro-3-trifluoromethylphenyl]fluorene}-9’- xanthene (M4) have been synthesized and characterized.
These monomers were converted to novel poly(aryl ether)s by nucleophilic displacement of the fluorine atom on the benzene ring with several bisphenols. The products of the poly(aryl ether)s exhibit number average molecular weights (Mn) up to 1.28 105g/mol in GPC. The decomposition temperatures (Td) for 5% weight loss all occurred above 470oC in nitrogen. The glass transition temperature (Tg) of these polymers recorded between 241 and 355oC by DSC. These polymers showed a contact angle (θ) between 70~100o. All the polymers are soluble in a wide range of organic solvents, e.q., NMP, THF, CHCl3, DMAc, and Toluene.
These poly(aryl ether)s were characterized by 1H-NMR, 13C-NMR, DSC, TGA, PL, contact angle, and DEA measurements.

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