本研究為使用聚乙烯吡咯烷酮（Polyvinylpyrrolidone, PVP）、硝酸銀(Silver nitrate, AgNO3)以及奈米銀棒(Silver nanorod, AgNR)結合單軸、同軸靜電紡絲來進行紡絲薄膜的製備。單軸、同軸靜電紡絲機台經由我們進行改良成適合本研究進行的配置。並使用奈米銀棒改善先前研究中電子傳導通路不連貫的問題。奈米銀棒的製備採用多元醇合成方式，並調整其製備參數如：銀種、各種原材料濃度的調整，來製造適合本研究使用的奈米銀棒；PVP/ AgNR/ AgNO3纖維膜結合硝酸銀的添加，將纖維膜經還原後得PVP/ AgNR/AgNP纖維膜，使作為電子傳導骨幹的奈米銀棒相互之間接觸電阻得以減少。並將所製備的薄膜進行SEM、TEM、TGA、四點探針、FTIR分析，最後成功製備出電阻率低於109Ω-cm的薄膜，具備靜電能力，有應用於導電的潛力。

In this study, we used polyvinylpyrrolidone (PVP), silver nitrate (AgNO3) and silver nano rod (AgNR) as raw materials to prepare fibrous mats through single/coaxial electrospinning. We also improved the single/co-axial electrospinning device in this study. AgNRs were prepared via polyol process to adjust the silver nanowires parameters. The interfacial resistance of silver nanowires was reduced by adding silver nitrate in the fibrous mats. After reduction of PVP/AgNR/AgNO3, the fibers transformed to PVP/ AgNR/AgNP. The resulting mats were analyzed using SEM, TEM, TGA and FTIR. Furthermore, the sheet resistances of the prepared fibrous mats were measured by four-point probe which have a resistance below 109Ω-cm.

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