本研究分別探討分別以碳酸二甲酯(Dimethyl carbonate，DMC)和碳酸二乙酯(Diethyl carbonate，DEC)為反應物製造碳酸二苯酯(diphenyl carbonate，DPC)之程序設計與控制。本研究結合反應蒸餾與分支進料之設計，將此兩種製程整合至單一座反應蒸餾塔中，並採用當量設計以降低設備以及能耗成本。根據穩態模擬之結果顯示，以碳酸二甲酯為反應物之組態相較於Cheng et al. (2013)之研究，可節省59.54% 冷凝器能耗、71.07% 再沸器能耗。而相較於Chen et al. (2015)之研究結果，本研究以碳酸二乙酯之組態設計，可節省75.66% 冷凝器能耗、83.97% 再沸器能耗，以及79.57% 的年總成本。
於動態控制之架構上，採基本庫存環路設計，品質控制環路方面，則採用溫度控制環路以控制產品規格。以靈敏度分析找出溫度靈敏板，再以相對增益矩陣(Relative gain array，RGA)分析控制變數與操作變數之配對，找出適當的控制架構，最後再以±10%產能擾動與5%、10%組成擾動測試控制策略的可行性。此外，根據動態模擬結果，顯示出CS4於碳酸二甲酯之控制架構中有最佳之動態響應，另一方面，碳酸二乙酯之控制架構中，則是CS3為最佳之控制策略。

This research proposes an innovative process to produce diphenyl carbonate (DPC) by applying reactive distillation (RD) technique with the feed-splitting arrangement. This study presented the transesterification reaction of dimethyl carbonate (DMC) and phenyl acetate (PA) as reactants to generate DPC. And the other way generate DPC by using diethyl carbonate (DEC) and PA as reactants. In this thesis, the DPC synthesis via DMC as reactant is called DMC configuration. Similarly, DPC production via DEC as reactant is called DEC configuration.
This research illustrates new configurations to achieve 99.5 % DPC and 99.5% by-product for industrial usage by using one RD column with the feed-splitting arrangement. The optimal RD with feed-splitting configuration is determined by the minimum total annual cost (TAC). The steady state simulation results show that the DMC configuration compares with the study of Cheng et al. (2013) could reduce energy consumption by 59.54% for condenser duty, and 71.07% for reboiler duty, resulting in a 57.99% lower TAC. Besides, DEC configuration compares with the research of Chen et al. (2015) could reduce energy consumption by 75.66% for condenser duty, and 83.97% for reboiler duty, resulting in a 79.57% lower TAC.
In process dynamics, the DMC and DEC proposed designs are used to demonstrate. The inventory control loops are studied to maintain stoichiometric balance. In addition, the dynamic results presented DPC production of both configurations can maintain the specification by temperature controller during ±10% throughput and 5%, 10% composition disturbance. The dynamic performance shows that the best control structure is CS4 in DMC configuration and CS3 in DEC configuration.

Chinese
1)詹政訓 (Jan, Cheng-Hsun)，「分支進料對丙酸丁酯反應蒸餾系統的影響」，國立台灣大學化學工程研究所，碩士論文，2006
2)鄭凱 (Cheng, Kai)，「醋酸苯酯與碳酸二甲酯合成碳酸二苯酯之熱結合反應蒸餾系統的設計」，國立清華大學化學工程研究所，碩士論文，2012
3)姚志通 (Yao, Chih-Tung)，「乙酸甲酯、碳酸二甲酯、乙酸苯酯、碳酸二苯酯雙成份混合物之相平衡與蒸汽壓沸點之研究」，私立義守大學生物技術與化學工程研究所，碩士論文，2012
4)林士熙 (Lin, Shih-Shi)，「合成碳酸二苯酯的高溫高壓反應動力行為研究」國立台灣科技大學化學工程研究所，碩士論文，2014
5)賀校芸 (Ho, Hsiao-Yun)，「恆溫下含產製碳酸二苯酯主要成分之混合物的汽液相平衡研究」，國立台灣科技大學化學工程研究所，碩士論文，2014
6)陳登陽 (Chen, Deng-Yang)，「以碳酸二乙酯製造碳酸二苯酯之反應蒸餾節能程序研究」，國立台灣科技大學化學工程研究所，碩士論文，2016

English
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