研究生: |
黃俊強 Chun-Chiang Huang |
---|---|
論文名稱: |
有機無機奈米核殼粒子之合成與其光催化之特性 Synthesis and characterization of organic/inorganic core–shell nanoparticles acted as visible light photocatalyst |
指導教授: |
蔡協致
Hsieh-Chih Tsai |
口試委員: |
朱一民
I-Ming Chu 王孟菊 Meng-Jiy Wang 王丞浩 Chen-Hao Wang 朱智謙 Chih-Chien Chu |
學位類別: |
博士 Doctor |
系所名稱: |
應用科技學院 - 應用科技研究所 Graduate Institute of Applied Science and Technology |
論文出版年: | 2014 |
畢業學年度: | 102 |
語文別: | 中文 |
論文頁數: | 112 |
中文關鍵詞: | 有機染料 、核/殼 、卟啉 、二氧化鈦 、奈米金 |
外文關鍵詞: | Organic dye, Core/shell, Porphyrin, Titania, Nanogold |
相關次數: | 點閱:449 下載:0 |
分享至: |
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建立奈米核/殼粒子的技術是一個倍受重視的研究領域,尤其在醫藥及生技上的潛力更是無限,而近幾年發展中,兩種形態材料的結合所製造而成之「複合型奈米核/殼材料」逐漸受到重視而嶄露頭角,複合型奈米核/殼材料之研究不單是一般奈米材料的結合技術,而更是實現單一顆奈米核/殼材料同時據有「多功能性」於一身之夢想的延伸,其本研究旨在建立一套有機染料與無機材料多功能複合型奈米核/殼材料之技術,並希望藉由此複合型奈米核/殼材料結合技術,能廣泛運用在各領域,研究係以溶膠–凝膠法使二氧化鈦水解縮合選擇性均勻披覆在有機染料表面,實驗利用透析法將Dye自組裝排列製備成奈米層級的染劑且穩定分散於水中,研究顯示Dye適合在酸和中性環境下反應,NH3環境下Dye無法自組裝形成有形狀之奈米粒子,如需添加使用界面活性劑則需要選用不帶電性的界面活性劑,Dye – TiO2成功利用NH3進行合成反應,即提升了TiO2光催化反應範圍,成功達成TiO2激發態波長延伸至可見光區域,研究中也嘗試將此技術衍生至金屬材料奈米金,在Dye–Au複合材料方面,CTAB雖然對奈米金有著強烈吸引,但CTAB卻無法使用在Dye溶液下,需要改用不帶電高分子mPEG-b-P(MEA-co-VIm)使奈米金在Dye表面均勻披覆,而形成Dye–Au核/殼複合材料,這技術是具有相當性的價值,是因為Dye和二氧化鈦以及奈米金,是完全相反條件下卻成功完成核/殼結構之複合材料。
In this study two kind of Core-shell nanoparticles were fabricated. The core materials is based on 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphine (PF6). Dispersed PF6 nanoparticles were formed in water during dialysis through self-assembly of the PF6 molecules. Therefore, we are trying to coating titanim and gold particle on the suface. The resulting TiO2-modified and gold-modifed particles were characterized using several characteristic methods. In TiO2/PF6 core shell particle, a 10–20 nm thick TiO2 layer on the surface of the PF6 nanoparticles. In Au/PF6 core shell particle, the gold particle was from on the surrounding of PF6. The chemical composition of these core-shell structures was also confirmed. In addition, TiO2/PF6 core shell particle can be utilized as visible photocatalyst. The absorption spectrum of the PF6-TiO2 core-shell nanoparticle was extended to 300–500 nm, which greatly enhanced the photocatalytic efficiency in the visible light spectrum compared to that of bare TiO2.
參考文獻
[1] L. R. Hoffman, D. A. D’Argenio, M. J. MacCoss, Z. Y. Zhang, R. A. Jones; S. I. Miller, Nature 2005, 436, 1171–1175.
[2] T. F. Mah; B. Pitts, B. Pellock; G. C. Walker; P. S. Stewart; G. A. O’Toole, Nature 2003, 426 , 306–310.
[3] K. Kakinoki, K. Yamane, R. Teraoka, M. Otsuka, Y. Matsuda, J. Pharmaceutic Science 2004, 93, 582-589.
[4] T.Y. Peng, A. Hasegawa, J. R. Qiu, K. Hirao, Chem. Mater. 2003, 15, 2011-2016.
[5] Y. S. Chen, J. C. Crittenden, S. Hackney, L. Sutter, D. W. Hand, Environ. Sci. Technol. 2005, 39, 1201-1208.
[6] M.A. Khan, H.T. Jung, O.B. Yang, J. Phys. Chem. B 2006, 110, 6626-6630.
[7] G. K. Mor, O. K. Varghese, M. Paulose, K. Shankar, C. A. Grimes, Sol. Energy Mater. Sol. Cells 2006, 90, 2011–2075.
[8] D. Wang, F. Zhou, Y. Liu, W. Liu, Mater. Lett. 2008, 62, 1819-1822.
[9] G. Natu, Y. Wu, J. Phys. Chem. C 2010, 114, 6802–7.
[10] J. J. Ebelmen, Ann. 1846, 57, 331.
[11] C. J. Brinker, and G. W. Scherer, Academic press, Boston, 1990.
[12] H. Schroeder, Phys. Thin Films 1969, 5, 87.
[13] G. P. Kalaignan, D. J. Seo, S. B. Park, Materials Chemistry and Physics 2004, 85, 286.
[14] R. K. Nagarale, V. K. Shahi, R. Rangarajan, J. Membrane Science 2005, 37, 248.
[15] J. P. Chen, W. S. Lin, Enzyme Microb. Technol. 2003, 32, 801.
[16] D. Y. Wang, K. Li, H. L. W. Chan, Sens Actuators A Phys 2004, 1, 114.
[17] A. M. Siouffi, J. Chromatography A 2003, 801, 1000.
[18] M. Sato, E. B. Slamovich, T. J. Webster, Biomater. Sci. 2005, 26, 1349.
[19] 陳慧英、黃定加、朱秦億,「溶膠凝膠法在製備上之應用」,化工技術第七卷第十一期,1999年11月號。
[20] A. Morifawa, Y. Iyoku, and Y. I. Kakimoto, J. Mater. Chem. 1985, 2, 679.
[21] R. O. R. Coast, and W.L. Vasconcelos, J. Non Cryst Solids 2002, 304, 84.
[22] M. Ochi, R. Takahashi, J. Polym Sci B Polym Phys 2001, 39, 1071.
[23] B. Himmel, T. Gerber, H. Burger, J. Non Cryst Solids 1987, 91, 122.
[24] Effect of long and short Pb-free soldering profiles of IPC/JEDEC J-STD-020 on plastic SMD packages, Microelectronics Reliability 2004, 44, 1293.
[25] J. D. Mackenzie, J. Non Cryst Solids 1982, 48, 1.
[26] 陳東煌,「複合奈米粒子的製備與應用」,化工技術,2003,120,180-193.
[27] V. V. Hardikar and E. Matijevic, J. Colloid Interface Sci 2000, 221, 133-136.
[28] F. Caruso, Chem. Eur. j 2000, 6, 413-419.
[29] E. Matijevic, J Eur Ceram Soc 1998, 18, 1357-1364.
[30] P. Davies, G. A. Schurr, P. Meenan, R. D. Nelson, H. E. Bergna, C. S. Brevett and R. H. Goldbaum, Adv. Mater. 1998, 10, 1264-1270.
[31] 陳嘉祈和呂世源,「奈米核殼粒子與奈米中空球之製備與應用」,化工技術2003,120,194-203。
[32] F. Caruso, Adv. Mater. 2001, 13, 11-22.
[33] E. Matijevic, Chem. Mater. 1993, 5, 412-426.
[34] X. C. Guo and P. Dong, Langmuir 1999, 15, 5535-5540.
[35] A. P. Philipse, M. P. B. Vanbruggen and C. Pathmamanoharan, Langmuir 1994, 10, 92-99.
[36] Z. Y. Zhong, Y. Mastai, Y. Koltypin, Y. M. Zhao and A. Gedanken, Chem. Mater. 1999, 11, 2350-2359.
[37] D. Gerion, F. Pinaud, S. C. Williams, W. J. Parak, D. Zanchet, S. Weiss and A. P. Alivisatos, J. Phys. Chem. B 2001, 105, 8861-8871.
[38] F. Caruso, R. A. Caruso and H. Mohwald, Science 1998, 282, 1111-1114.
[39] F. Caruso, X. Y. Shi, R. A. Caruso and A. Susha, Adv. Mater. 2001, 13, 740-744.
[40] K. S. Mayya, D. I. Gittins and F. Caruso, Chem. Mater. 2001, 13, 3833-3836.
[41] L. M. LizMarzan, M. Giersig and P. Mulvaney, Langmuir 1996, 12, 4329-4335.
[42] S. J. Oldenburg, R. D. Averitt, S. L. Westcott and N. J. Halas, Chem Phys Lett 1998, 288, 243-247.
[43] J. B. Jackson and N. J. Halas, Russ. J. Phys. Chem. B 2001, 105, 2743-2746.
[44] C. X. Song, D. B. Wang, G. H. Gu, Y. S. Lin, J. Y. Yang, L. Chen, X. Fu and Z. S. Hu, J. Colloid Interface Sci 2004, 272, 340-344.
[45] K. Kamata, Y. Lu and Y. N. Xia, J. Am. Chem. Soc. 2003, 125, 2384-2385.
[46] W. L. Zhang, B. Kohler, E. Oswald, L. Beutin, H. Karch, S. Morabito, A. Caprioli, S. Suerbaum and H. Schmidt, J. Clin. Microbiol. 2002, 40, 4486-4492.
[47] R. Schmidt, H. Schmidt, P. Kapeller, C. Enzinger, S. Ropele, R. Saurugg and F. Fazekas, J. Clin. Microbiol. 2002, 203, 253-257.
[48] R. C. Advincula, J. Dispersion Sci. Technol. 2003, 24, 343-361.
[49] Frank Caruso, Adv. Mater. 2001,13, 11-21.
[50] R. Partch, S.G Gangolli, E Matijević, W Cal, S Arajs, J. Colloid Interface Sci. 1991, 144, 27-35.
[51] S.M. Marinakos, L.C. Brousseau , A. Jones, D.L. Feldheim, Chem. Mater. 1998, 10, 1214-1219.
[52] S.M. Marinakos, J.P. Novak, L.C. Brousseau, A.B. House, E.M. Edeki, J. Am. Chem. Soc. 1999, 121, 8518-8522.
[53] L. Quaroni, G. Chumanov, J. Am. Chem. Soc. 1999, 121, 10642.
[54] H.Y. Chang, S.Y. Cheng, C.I. Sheu, Y.H. Wang, Nanotechenology 2003, 14, 603-608.
[55] A.S. Susha, F. Caruso, A.L. Rogach, G.B. Sukhorukov, A. Kornowski, H. Mohwald, M. Giersig, A. Eychmuller, H. Weller, Colloids Surf A Physicochem Eng Asp 2000, 163, 39-44.
[56] M. Ohmori, E. Matijevic, J. Colloid Interface Sci. 1992, 150, 594-598.
[57] Werner Stober, J. Colloid Interface Sci. 1968, 26, 62-69.
[58] Andrew J. Ruys, Mater. Sci. Eng., A 1999, 265, 202-207.
[59] Z.Y. Chen, Mater. Sci. Eng., B 1999, B67, 95-98.
[60] Isabel P.S., Dmitry S. K., Arif A. M., Michael G., Nicholas A. K., Luis M. L.Marzan, Langmuir 2000, 16, 2731-2735.
[61] Thearith Ung, Luis M. Liz-Marzan, Paul Mulvaney, Langmuir 1998, 14, 3740-3748.
[62] X. Shi, T. Cassagneau, F. Caruso, Langmuir 2002, 18, 904-910.
[63] K. S. Mayya, D. I. Gittins, F. Caruso, Chem. Mater. 2001, 13, 3833-3836.
[64] L.M. Liz-Marzan, M. Giersig, P. Mulvaney, Langmuir 1996, 12, 4329-4335.
[65] O. Masahiro, M. Egon, J. Colloid Interface Sci. 1993, 160, 288-292.
[66] H.Y. Chang, S.Y. Cheng, C.I. Sheu, Y.H. Wang, Nanotechenology 2003, 14, 603-608.
[67] H. Y. Chuang, D. H. Chen, J. Nanopart. Res. 2008, 10, 233-241.
[68] V. C. Fuertes, C. F. A Negre, M. B. Oviedo, F. P. Bonafe, F. Y. Oliva, C. G. Sanchez, J Phys Condens Matter 2013, 115304.
[69] C. Feldmann, Adv. Mater. 2001, 13, 1301-1303.
[70] S. Gunes, T. Neugebauer, N. S. Sariciftci, J. Roither, M. Kovalenko, G. Pillwein, W. Heiss, Adv. Funct. Mater. 2006, 16, 1095-1099.
[71] Ito S., Zakeeruddin S. M., Humphry-Baker R., Liska P., Charvet R., Comte P., Nazeeruddin M. K., Pechy P., Takata M., Miura H., Uchida S., Gratzel M. Adv. Mater. 2006, 18, 1202-1025.
[72] Chuang H. Y., Chen D. H., J. Nanopart. Res. 2008, 10, 233-241.
[73] O. Carp, C. L. Huisman, A. Reller, Prog. Solid State Chem. 2004, 32, 33-177.
[74] A. Fujishima, T. N. Rao, D. A. Tryk, J. Photochem. Photobiol., C 2000, 1, 1-21.
[75] J.M. Herrmann, Catal. Today 1999, 53, 115-129.
[76] A. Mills, S. L. Hunte, J. Photochem. Photobiol., A 1997, 108, 1–35.
[77] Li Q., Mahendra S., Lyon D.Y., Brunet L., Liga M.V., Li D., Alvarez P.J.J., Water Res. 2008, 42, 4591-4602.
[78] Fujishima A., Honda K., Nature 1972, 238, 37–38.
[79] A. Giwa, P. O. Nkeonye, K. A. Bello, E. G. Kolawole, J. Environ Prot 2012, 3, 1063-1069.
[80] Murray C.A., Goslan E.H., Parsons S.A., J. Environ. Eng. Sci. 2007, 6, 311–317.
[81] Salthammer T., Fuhrmann F., Environ. Sci. Technol. 2007, 41, 6573–6578.
[82] Matsunaga T., Tomoda R., Nakajima T., Wake H., FEMS Microbiol. Lett. 1985, 29, 211–214.
[83] Wei C., Lin W.Y., Zainal Z., Williams N.E., Zhu K., Kruzic A.P.,Smith R.L., Rajeshwar K., Environ. Sci. Technol. 1994, 28, 934–938.
[84] Watts R.J., Kong S., Orr M.P., Miller G.C., Henry B.E., Water Res. 1995, 29, 95–100.
[85] Zan L., Fa W., Peng T.P., Gong Z.K., J. Photochem. Photobiol. B. Biol. 2007, 86, 165–169.
[86] Hajkova P., Spatenka P., Horsky J., Horska I., Kolouch A., Polym. 2007, 4, 397–401.
[87] Cho M., Chung H., Choi W., Yoon J., Appl. Environ. Microbiol. 2005, 71, 270–275.
[88] Kikuchi Y., Sunada K., Iyoda T., Hashimoto K., Fujishima A., J. Photochem. Photobiol. A. 1997, 106, 51–56.
[89] Gelover S., Gomez L.A., Reyes K., Leal M.T., Water Res. 2006, 40, 3274–3280.
[90] Lyon D.Y., Adams L.K., Falkner J.C., Alvarez P.J.J., Environ. Sci. Technol. 2006, 40, 4360–4366.
[91] Chong M., Jin B., Chow C., Saint C., Water Res. 2010, 44, 2997–3027.
[92] Chen J, Liu M, Zhang L, Zhang J, Jin L, Water Res. 2003, 37, 3815-3820.
[93] Zhang Z, Yuan Y, Fang Y, Liang L, Ding H, Jin L, Talanta 2007, 73, 523-528.
[94] M. Gratzel, Nature 2001, 414, 338–344.
[95] P. Xie, F. Guo, Curr. Org. Chem 2007, 11, 1272–1286.
[96] Z. Chen, F. Li, C. Huang, Curr. Org. Chem. 2007, 11, 1241–1258.
[97] N. Robertson, Angew. Chem. Int. Ed. 2008, 47, 1012–1014.
[98] A. B. F. Martinson, T. W. Hamann, M. J. Pellin, J. T. Hupp, Chem. Eur. J. 2008, 14, 4458–4467.
[99] A. Hagfeldt, M. Gratzel, Chem. Rev. 1995, 95, 49–68.
[100] U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissortel, J. Salbeck, H. Spreitzer, M. Gratzel, Nature 1998, 395, 583–585.
[101] M. K. Nazeeruddin, S. M. Zakeeruddin, J.J. Lagref, P. Liska, P. Comte, C. Barolo, G. Viscardi, K. Schenk, M. Gratzel, Coord.Chem. Rev. 2004, 248, 1317–1328.
[102] A. S. Polo, M. K. Itokazu, N. Y. M. Iha, Coord. Chem. Rev. 2004, 248, 1343–1361.
[103] M. Gratzel, Inorg. Chem. 2005, 44, 6841–6851.
[104] S. Nakade, T. Kanzaki, W. Kubo, T. Kitamura, Y. Wada, S.Yanagida, J. Phys. Chem. B 2005, 109, 3480–3487.
[105] B. O Regan, M. Gratzel, Nature 1991, 353, 737–740.
[106] Joo J., Kwon S.G., Yu T., Cho M., Lee J., Yoon J., Hyeon T., J. Phys. Chem. B 2005, 109, 15297-15302.
[107] Vinodgopal K., Wynkoop D.E., Kamat P.V., Sci. Technol. 1996, 30, 1660-1666.
[108] Ni M., Leung M.K.H., Leung D.Y.C., Sumathy K., Energy Rev. 2007, 11, 401-425.
[109] Litter M.I., Catal. B: Environ. 1999, 23, 89-114.
[110] Fujishima A., Zhang X., Tryk D., A. Surf. Sci. Rep. 2008, 63, 515-582.
[111] Li H., Li J., Huo Y., J. Phys. Chem. B 2006, 110, 1559-1565.
[112] Ishibai Y., Sato J., Nishikawa T., Miyagishi S., Appl.Catal. B: Environ. 2008, 79, 117-121.
[113] Shaban Y.A., Khan S.U.M., Int. J. Hydrogen Energy 2008, 33, 1118-1126.
[114] Furube A., Asahi T., Masuhara H., Yamashita H., Anpo M., Chem. Phys.Lett. 2001, 336, 424-430.
[115] Irie H., Watanabe Y., Hashimoto K., J. Phys. Chem. B 2003, 107, 5483-5486.
[116] Ihara T., Miyoshi M., Iriyama Y., Matsumoto O., Sugihara S., Appl. Catal., B 2003, 42, 403-409.
[117] Milgrom L.R., OUP, Oxford, 1997; The porphyrins, ed. D. Dolphin, Academic Press, New York, 1978.
[118] J. T. Groves, R. C. Haushalter, M. Nakamura, T. E. Nemo, B. J. Evans, J. Am. Chem. Soc. 1981, 103, 2884-2886.
[119] K.M. Kadish, K.M. Smith, R. Guilard, The Porphyrin Handbook, Academic Press, San Diego 2000.
[120] S. Takagi, H. Inoue, in: V. Ramamurthy, K.S. Schanze, Multimetallic and Macromolecular Inorganic Photochemistry, vol. 6, Marcel Dekker,New York, 1999, 215.
[121] K.M. Smith, Porphyrins, Metalloporphyrins, Elsevier, Amsterdam, 1975.
[122] H. Inoue, S. Funyu, Y. Shimada, S. Takagi, Pure Appl. Chem. 2005, 77, 1019-1033.
[123] M. Wark, in: K.M. Kadish, K.M. Smith, R. Guilard (Eds.), The Porphyrin Handbook, vol. 17, Academic Press, New York, 2003.
[124] V.R.L. Constantino, C.A.S. Barbosa, M.A. Bizeto, P.M. Dias, An. Acad. Bras. Cienc. 2000, 72, 45-49.
[125] F. Bedioui, Coord. Chem. Rev. 1995, 144, 39-68.
[126] J.K. Thomas, Chem. Rev. 1993, 93, 301-320.
[127] M. Ogawa, K. Kuroda, Chem. Rev. 1995, 95, 399-438.
[128] K. Takagi, T. Shichi, J. Photochem. Photobiol. C: Photochem. Rev. 2000, 1, 113-130.
[129] J.K. Thomas, Acc. Chem. Res. 1988, 21, 275-280.
[130] K. Takagi, T. Shichi, in: V. Ramamurthy, K.S. Schanze, Solid State and Surface Photochemistry, vol. 5, Marcel Dekker, New York, 2000, 31.
[131] M. Ogawa, in: S.M. Auerbach, K.A. Carrado, P.K. Dutta, Handbook of Layered Materials, Marcel Dekker, 2004.
[132] 郭清奎,「金屬奈米粒子的製造」,物理雙月期刊,614,2001。
[133] M. Moskovits, Rev. Mod. Phys. 1985, 57, 783-826.
[134] Bradley J. S., The Chemistry of Transition Metal Colloids. In Clusters and Colloids; Schmid, G., Ed.; VCH Publishers: New York, NY (USA), 1994, 459.
[135] Reetz M. T., Helbig W., J. Am. Chem. Soc. 1994, 116, 7401-7402.
[136] Reetz M. T., Winter M., Breinbauer R.; Thomas T.A., Vogel W., Chem. Eur. J. 2001, 7, 1084-1094.
[137] Brust M., Walker M., Bethell D., Schiffrin D. J., Whyman R., J. Chem. Soc. Chem. Commun. 1994, 7, 801-802.
[138] Ntes V. F., Krishnan K. M., Alivisatos A. P., Science 2001, 291, 2115-2117.
[139] Guo L., Huang Q., Li X.Y., Yan S., Phys. Chem. Chem. Phys. 2001, 3, 1661-1665.
[140] Park S.J., Kim S., Lee S., Khim Z. G., Char K., Hyeon, T., J. Am. Chem. Soc. 2000, 122, 8581-8582.
[141] Yu Y.Y., Chang S.S., Lee C.L., Wang C. R., Chris., J. Phys. Chem. B 1997, 101, 6661-6664.
[142] Kortenaar M. V. Ten., Kolar Z. I., Tichelaar F. D., J. Phys. Chem. B 1999, 103, 2054-2060.
[143] Okitsu K., Bandow, H., Maeda Y., Chem. Mater. 1996, 8, 315-317.
[144] Okitsu K., Mizukoshi Y., Bandow H., Yamamoto T. A., Nagata Y., Maeda Y., J. Phys. Chem. B 1997, 101, 5470-5472.
[145] Mizukoshi Y., Okitsu K., Maeda Y., Yamamoto, T. A., Oshima R., Nagata Y., J. Phys. Chem. B 1997, 101, 7033-7037.
[146] Bohen C., Huffman D., Absorption and Scatteing of Light by Small Particles, Wiley, New York, 1983.
[147] Sharma V., Park K., Srinivasarao M., Mater. Sci. Eng., R. 2009, 65, 1-38.
[148] Ghosh S.K., Assam University Journal of Science & Technology: Physical Science and Technology 2011, 7, 114.
[149] 尹邦耀,「奈米時代」,五南圖書出版,2005
[150] 蕭義鴻,「以電化學方法製備鐵奈米粒子之研究」,國立中山大學電機工程學系研究所碩士論文,2004。
[151] C. Kim, M. Choi, J. Jang, Catal. Commun. 2010, 11, 378–382.
[152] R. Marsalek, Z. Navratilova, Chem. Pap. 2011, 65, 77-84.
[153] R. Marsalek, J. Pospišil, B. Taraba, Colloids. Surf. A. Physicochem Eng Asp 2011, 383, 80-85.
[154] Burckbuchler V., Wintgens V., Lecomte S., Percot A., Leborgne C., Danos O., Kichler A., Amiel C., Biopolymers 2006, 81, 360–370.
[155] Bender M. L., Komiyama, M., Cyclodextrin Chemistry; Springer-Verlag: Berlin, Germany 1978.
[156] Valente A. J. M., Nilsson M., Soderman O., J. Colloid Interface Sci. 2005, 281, 218–224.
[157] Cabaleiro L. C., Nilsson M., Soderman O., Langmuir 2005, 21, 11637–11644.
[158] Pineiro A., Banquy X., Perez-Casas S., Tovar E., Garcıa A., Villa A., Amigo A., Mark A. E., Costas M., J. Phys. Chem. B 2007, 111, 4383–4392.
[159] Xing H., Lin S. S., Yan P., Xiao J. X., Chen Y. M., J. Phys. Chem. B 2007, 111, 8089–8095.
[160] Takayama Y., Negishi H., Nakamura S., Koura N., Idemoto Y., Yamaguchi F., J. Ceram. Soc. Jpn. 1999, 107, 119-122.
[161] K. Tanaka, Shokubai Kogaku Koza 10, Chijin Shokan, Tokyo 1967, 787.
[162] Yoldas B. E., J. Mater. Sci. 1986, 21, 1087-1092.
[163] Bowen H. K., Mater. Sci. Eng. 1986, 65, 1574-1577.
[164] Stober W., Fink A., Bohn E. J., J. Colloid Interface Sci. 1968, 26, 62-69.
[165] C. Kim, M. Choi, J. Jang, Catal. Commun. 2010, 11, 378–382.
[166] J. W. Lee, S. Kong, W. S. Kim, J. Kim, Mater. Chem. Phys. 2007, 106, 39–44.
[167] I. Shown, M. Ujihara, T. Imae., J. Nanosci. Nanotechnol. 2011, 11, 1–7.
[168] J.W. Lee, M.R. Othman, Y. Eom, T.G. Lee, W.S. Kim, J. Kim., Microporous Mesoporous Mater 2008, 116, 561–568.
[169] H. Kuwata, H. Tamaru, K. Esumi, K. Miyano, Appl. Phys. Lett. 2003, 83, 4625-4627.
[170] Yu Y. Y., Chang S. S., Lee C. L., Wang C. R. C., J. Phys. Chem. B. 1997, 101, 6661-6664.
[171] Dawson A., Kamat P. V., J. Phys. Chem. B 2001, 105, 960-966.
[172] Ship A. N., Lahav M., Gabai R., Willner I., Langmuir 2000, 16, 8789-8795.
[173] R.F. Khairutdinov, N. Serpone, J. Phys. Chem. 1995, 99, 11952–11958.
[174] S.Y. Huang, G. Schlichthorl, A.J. Nozik, M. Gratzel, A.J. Frank, J. Phys. Chem. B. 1997, 101, 2576–2582.
[175] D. Chen, D. Yang, J. Geng, J. Zhu, Z. Jiang, Appl. Surf. Sci. 2008, 255, 2879–2884.
[176] M. Tanaka et al, J. Biomed. Mat. Res. 2004, 684–695.