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研究生: 吳慧茹
Hui-Ru Wu
論文名稱: 以花生殼灰吸附水溶液中鎳離子的研究
Adsorption of Nickel Ion from Aqueous Solution using Peanut Hull Ash
指導教授: 林俊一
Chun-I Lin
口試委員: 施信民
Shin-Min Shih
李振綱
Cheng-Kang Lee
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 97
中文關鍵詞: 花生殼灰鎳離子吸附
外文關鍵詞: peanut hull ash, nickel ion, adsorption
相關次數: 點閱:175下載:0
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本研究探討以花生殼灰來吸附水溶液中鎳離子的吸附動力學。實驗中,將花生殼置於500°C的高溫爐中鍛燒30分鐘,製成花生殼灰。接著,利用感應耦合電漿質原子發射光譜儀、掃瞄式電子顯微鏡、粒徑測定儀、密度測定儀、表面積測定儀、水份天平及pH計分別進行花生殼灰的組成分析與物理性質之測定。
水溶液中鎳離子濃度是以感應耦合電漿質原子發射光譜儀來量測。
實驗結果顯示,花生殼灰的吸附效率是可接受的。
降低花生殼灰劑量、提高起始鎳離子濃度、pH值、震盪速率或吸附溫度,可提高鎳離子的吸附速率及平衡吸附量。物理吸附是本吸附系統的控制步驟。擬二階速率式可適當的描述吸附動力學數據。最後並迴歸出一條吸附速率式。
實驗也發現,起始鎳離子濃度、pH值、震盪速率及吸附溫度對吸附的影響會被花生殼灰劑量變化的影響所遮蔽。


This study investigates the kinetics of the adsorption of nickel ion from aqueous solution by peanut hull ash (PHA).
Peanut hull ash (PHA) was prepared by calcinating peanut hull in a 500°C box furnace for 30 min. The content and the physical properties of peanut hull ash (PHA) were analyzed by using an inductively coupled plasma atomic emission spectrometry (ICP), a scanning electron microscope (SEM), a laser diffraction particle size analyzer, a density meter, a surface area analyzer, a moisture determination balance and a pH meter.
Nickel concentrations in aqueous solution was determined by an ICP.
Experimental results indicated that PHA prepared was an acceptable absorbent to remove nickel from aqueous solution.
The adsorption rate and adsorption at equilibrium were found to increase with increasing initial nickel concentration, initial pH, stroke speed or adsorption temperature or with decreasing PHA dosage. Physisorption was thought to be the rate determining step for the adsorption process. Pseudo-second-order rate equation was found to interpret the kinetic data suitably. Finally, an empirical adsorption rate equation has been determined.
Experimental results also lead us to suspect that the effects of initial nickel concentration, initial pH, stroke speed and adsorption temperature are concealed by the effect of PHA dosage.

中文摘要 I 英文摘要 II 致 謝 IV 目 錄 V 圖表索引 VIII 第一章 緒論 1 第二章 文獻回顧 3 2.1 鎳廢水的來源及影響 3 2.2 花生殼 4 2.3 以花生殼及其衍生物吸附水溶液中鎳離子 5 2.4 吸附原理 7 2.4.1 影響吸附的因素 8 2.4.2 吸附速率式 12 第三章 實驗部分 17 3.1 氣體、藥品及吸附劑 17 3.2 實驗設備 18 3.3 實驗儀器 19 3.4 實驗步驟 20 3.4.1 花生殼灰的製備 20 3.4.2 花生殼灰的組成分析及物理性質量測 21 3.4.2.1 感應耦合電漿質原子發射光譜儀 21 3.4.2.2 掃瞄式電子顯微鏡 22 3.4.2.3 雷射粒徑分佈儀 22 3.4.2.4 密度測定儀 23 3.4.2.5 表面積測定儀 25 3.4.2.6 水份天秤 25 3.4.2.7 pH計 26 3.4.3 鎳離子溶液的調配 27 3.4.3.1 鎳離子溶液的調配步驟 27 3.4.3.2 鎳離子溶液的pH測定 27 3.4.4 吸附實驗 28 3.4.5 溶液中鎳離子濃度的量測 29 3.4.5.1 鎳標準液的配置步驟 29 3.4.5.2 鎳離子濃度的測定步驟 29 第四章 實驗結果與討論 32 4.1 花生殼灰之組成與物性 32 4.1.1 花生殼灰中的成份分析 32 4.1.2 花生殼灰的大小與形狀 36 4.1.3 花生殼灰的粒徑 36 4.1.4 花生殼灰的密度 36 4.1.5 花生殼灰的比表面積、比孔隙面積及平均孔徑 36 4.1.6 花生殼灰的含水量 37 4.1.7 花生殼灰的pH值 37 4.2 吸附的實驗結果 38 4.2.1 鍛燒時間對吸附的影響 38 4.2.2 吸附效率 42 4.2.3 操作變數對吸附的影響 44 4.2.4 吸附速率式 54 4.2.5 高花生殼灰劑量下其他操作變數的影響 61 第五章 結論 66 參考文獻 67 附錄一 實驗數據 73 附綠二 作者簡介 84

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