本研究合成製備兩種綠色界面活性劑，第一種以葡萄糖與丙二醇在酸催化下經縮醛反應製備丙二醇配醣體，接著將丙二醇配醣體與擁有8到12個長碳鏈之烷基環氧丙基醚反應合成一系列葡萄糖型界面活性劑；第二種是以穀胺酸(Glutamic Acid)及脂肪酸(C2-C14)合成製備一系列胺基酸型界面活性劑，將兩種合成產物利用FT-IR測定以確認其結構，再測試其基本性質，包括表面張力、導電度、螢光性質、接觸角、起泡性、COD化學需氧量、BOD生化需氧量、乳化性質檢測，並透過表面張力數據代入熱力學參數，求得吉伯士自由能(Gibbs Free Energy) ΔG = ΔH – TΔS，藉以探討界面性能及微胞凝集情形。另外將兩種綠色界面活性劑作染色之助劑，添加於薑黃、指甲花天然植物色素，進行羊毛纖維染色性應用。

This study was the first to prepare two types green surfactant, one type glucose and propylene glycol acetal under acid catalysis by reacting propylene glycol glycoside, followed by synthesis of a series of glucose derivative-type surfactant; and other type used glutamate (Glutamic acid) and fatty acids (C2-C14) to prepare a series of amino acid type synthetic surfactant, the use of two synthetic product FT-IR was measured to confirm its structure, and then test their essential properties, including surface tension,conductivity, fluorescence, contact angle, foaming properties, chemical oxygen demand , biochemical oxygen demand, and emulsification. And to the thermodynamic parameters through the surface tension data generation, and seek Gibbs free energy ΔG = ΔH – TΔS. Also by combining these two green surfactant and natural plant pigments to proceed, dyeing of wool fiber tests.

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