簡易檢索 / 詳目顯示

研究生: 趙育德
Yu-teh Chao
論文名稱: 鋅金屬披覆於PC/ABS塑膠合金之特性研究
The research of the zinc coated in the PC/ABS revertex alloy
指導教授: 蘇舜恭
Shuenn-Kung Su
口試委員: 邱士軒
Shih-Hsuan Chiu
楊銘乾
Ming-Chien Yang
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 64
中文關鍵詞: 覆膜PC/ABS
外文關鍵詞: The melt shoots, PC/ABS
相關次數: 點閱:165下載:4
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本實驗以(PC/ABS)為基材,以線徑2.0mm的鋅線為金屬披覆材,分三階段進行。第一階段旨在找出適合鋅金屬熔射製程起弧穩定最佳參數,第二階段找出噴塗製程的最佳參數,第三階段著重在前處理製程的差異性與熔射製程的影響。第一階段以(電壓值及線材送線速度與電流穩定度做比較)為製程參數。找出最佳起弧參數值後,第二階段以(噴塗距離及噴槍移動速度對未噴砂的基材)做比較找出最佳噴塗參數。第三階段加入前處理製程,噴金剛砂(不噴砂、60號砂、120號砂)做表面粗化、表面潔淨(不水洗、超音波震盪一分鐘、超音波震盪六分鐘)、去除水氣(不烘乾、烘乾溫度設60度烘乾時間一小時)。找出最佳前處理製程參數後,進行塗佈製程。之後測試基本性質(厚度、導電值、增加重量),之後做機械性質測試(衝擊、抗拉、附著力測試),並做顯微觀察 (SEM)。第一階段實驗結果發現,噴塗距離最好為二十公分,噴塗時氣壓需再0.6MPA以上,噴塗最佳電壓值為28伏特,噴槍移動最佳速度一秒十公分,送線速度為一秒10.3公分。 第二階段實驗結果發現,無烘乾下附著力,120號砂﹥60號砂﹥無噴砂,六分鐘﹥洗一分鐘 ﹥無清洗,有烘乾下附著力,60號砂﹥120號砂﹥無噴砂,六分鐘﹥洗一分鐘 ﹥無清洗,烘乾完後對附著力有顯著的影響,機械性值可增加60%的衝擊力。


    This experiment takes (PC/ABS) as a parent metal, the material take the line diameter 2.0mm zinc line as the metal, divides three stages to carry on. The first stage is for the purpose of discovering suits the zinc metal melt to shoot the system regulation to get up the arc stable best parameter, the second stage discovers the spray coating system regulation the best parameter, the third stage emphatically processes the system regulation in front the difference and the melt shoots the system regulation the influence. The first stage (delivers link speed and electric current stability take voltage value and line material makes comparison) as the system regulation parameter. After discovers is best the arc parameter value, the second stage (is away from and spray gun traveling speed by spray coating to sand blasting parent metal) has not made the comparison to discover the best spray coating parameter. Front the third stage joins processes the system regulation, spurts the emery (not to sand-blast, 60 granulated substance, 120 granulated substance) makes the superficial coarsening, the surface purely (laundering, supersonic wave does not shake minute, supersonic wave shakes six minutes), the elimination moisture (does not dry, drying temperature supposes a 60 degree drying time for hour).After discovers best front processes the system regulation parameter, carries on spreads the cloth system regulation. Afterwards tests the basic nature (thickness, electric conduction value, increases weight), afterwards makes the mechanical property test (impact, anti-pulls, adhesion test), and makes the microexamination (SEM).The first stage experiment result discovered, the spray coating is away from well is 20 centimeters, when the spray coating the barometric pressure must above 0.6MPA, the spray coating best voltage value be again 28 volts, the spray gun moves optimum velocity second ten centimeters, delivers the link speed is second 10.3 centimeters. The second stage experiment result discovered that, it does not have the adhesion under drying, 120 granulated substance>60 number granulated substance>without sand-blasting, six minutes>wash a minute >without cleaning, it has x the adhesion the adhesion, 60granulated substance>120 number granulated substance>without sand blasting, six minutes>wash with one minute>without cleaning, after dries has the remarkable influence to the adhesion, mechanicalness value may increase 60% impulse.

    目錄 中文摘要…………………………………………………………………Ⅰ 英文摘要…………………………………………………………………III 誌謝………………………………………………………………………V 目錄………………………………………………………………………VI 圖表索引…………………………………………………………………X 第一章緒論 1.1 前言………………………………………………………………1 1.2 文獻回顧…………………………………………………………3 1.3 研究目的…………………………………………………………5 第二章參考文獻 2.1 熱噴塗技術簡介……………………………………………7 2.2 電弧噴塗………………………………………………………9 2.3 可熔射材料…………………………………………………11 2.4 表面預處理………………………………………………12 2.4.1 粗化處理……………………………………………12 2.4.2 水洗………………………………………………15 2.4.3 乾燥………………………………………………16 2.5 熱噴塗塗層的結構特點…………………………………………17 第三章實驗 3.1 實驗架構………………………………………………………20 3.2 實驗儀器與裝置…………………………………………………21 3.2.1 實驗及測試用材料…………………………………………21 3.2.2 實驗設備…………………………………………………23 3.3 實驗方法………………………………………………………24 3.3.1電弧噴塗系統………………………………………………24 3.3.2 設備參數……………………………………………………25 3.3.2.1 工作電壓………………………………………………26 3.3.2.2 送線速度………………………………………………27 3.3.2.3 最佳氣壓………………………………………………28 3.3.3 噴塗參數……………………………………………………29 3.3.3.1 噴塗距離………………………………………………30 3.3.3.1 噴槍移動速度…………………………………………31 3.3.3.1 噴塗角度………………………………………………32 3.3.4 前處理參數…………………………………………………33 3.3.4.1 噴砂…………………………………………………34 3.3.4.2 水洗…………………………………………………34 3.3.4.3 烘乾………………………………………………35 第四章結果與討論 4.1設備參數………………………………………………………38 4.1.1不同送線速度對電壓大小的電流穩定度之影響…………38 4.1.1.1 送線速度10.3cm/s對電壓大小的電流穩定度……39 4.2 噴塗參數………………………………………………………43 4.2.1不同噴槍距離對噴槍移動速度的附著力之影響………43 4.2.1.2噴槍移動速度10cm/s………………………………44 4.3 基本性質檢測……………………………………………………45 4.3.1 平均重量………………………………………………46 4.3.2 平均厚度………………………………………………46 4.3.3 平均粗糙度………………………………………………47 4.3.4 平均電阻值…………………………………………………48 4.4 機械性質檢測……………………………………………………49 4.4.1 附著力………………………………………………………49 4.4.2 衝擊力………………………………………………………51 4.4.3抗拉強度……………………… ……………………………53 4.5 表面狀態………………………………………… …………………54 第五章 結論………………………………………………………………56 第六章 未來方向與展望…………………………………………………58 參考文獻…………………………………………………………………59

    1. R. G. T. Geesink, K. de Groot, and C. P. A. T. Klein, "Chemical Implant
    Fixation Using Hydroxy-apatite Coatings", Clin. Orthop., 225 (1987)
    pp.147~170.

    2. A. Ravaglioli, and A. Krajewski, "Bioceramics: Materials, Properties,
    Applications", Chapman & Hall Press, London, (1992) pp.44-45.

    3. M. Jarcho, "Calcium Phosphate Ceramics as Hard Tissue Prosthetics",
    Clin. Orthop., 157 (1981) pp.259-278.

    4. L. L. Hench, "Biocermics: From Concept to Clinic", J. AM. Ceram.
    Soc., 74 (1991) pp.1487-1510.

    5. J. D. Bobyn, R. M. Pilliar, H. U. Cameron, and G. C. Weatherly, "The
    Optimum Pore Size for the Fixation of Porous-Surfaced Matel
    Implants by the Ingrowth of Bone", Clin. Orthop., 150 (1980)
    pp.263-270.

    6. S. D. Cook, K. A. Walsh, and R. J. Haddad, "Interface Mechanics and
    Bone Growth into Porous Co-Cr-Mo Alloy Implants", Clin. Orthop.,
    193 (1985) pp.271-280.

    7. 王寶琪, "電漿熔射氫氧基磷灰石披覆於鈦鋁釩合金基材生醫塗層
    之生物特性與生物反應研究", 國立成功大學材料科學及工程研究
    所博士論文 , 1994.
    8. P.-I. Branemark, B. O. Hansson, R. Adell, U. Breine, J. Lindstrom, O.
    Hallen, and A. Ohman, "Osseointegrated Implants in the Treatment of
    the Endentulous Jaw", Scand. J. Plast. Reconstruc. Surg., 11 (1977)
    Soppl. pp.16.

    9. T. Albrektsson, P.-I. Branemark, H.-A. Hansson, and J. Lindstrom,
    “Osseointegrated Titanium Implants. Requirements for Ensuring a
    Long-Lasting, Direct Bone-to-Implant Anchorage in Man", Acta
    Orthop. Scand., 52 (1981) pp.155-170.

    10. C. Johansson, J. Lausmaa, M. Ask, H.-A. Hansson, and T. Albrektsson,
    "Ultra-Structural Differences of the Interface Zone between Bone and
    Ti6Al4V or Commercially Pure Titanium", J. Biomed. Eng., 11 (1989)
    pp.3-8.

    11. J. W. McCutchen, J. P. Collier, and M. B. Mayer, "Osseointegration of
    Titanium Implants in Total Hip Arthroplasty", Clin. Orthop., 261
    (1990) pp.114-125.

    12. G. L. de Lange, C. de Putter, and F. L. J. A. de Wijs, "Histological and
    Ultra-Structural Appearance of the Hydroxyapatite-Bone Interface", J.
    Biomed. Mater. Res., 24 (1990) pp.829-845.

    13. H. A. Hoogendoom, W. Renooij, L. M. A. Akkermans, W. Visser, and
    P. Wittebol, "Long-Term Study of Large Ceramic Implants (Porous
    Hydroxyapatite) in Dog Femora", Clin. Orthop., 187 (1983)
    pp.281-288.

    14. C. A. van Blitterswijk, S. C. Hesseling, J. J. Grote, H. K. Koerten, and
    K. de Groot , "The Biocompatibility of Hydroxyapatite Ceramic: A
    Study of Retrieved Human Middle Ear Implants", J. Biomed. Mater.
    Res., 24 (1990) pp.433-453.

    15. K. de Groot, C. P. A. T. Klein, J. G. C. Wolke, and J. M. A. de
    Blieck-Hoger-vorst, "Chemistry of Calcium Phosphate Bioceramics
    "in "CRC Handbook of Bioactive Ceramics", edited by T. Yamamuro ,
    L. L. Hench, and J. Wilson, CRC Press Inc., Boca Raton, Florida, Vol.
    II (1990) pp.3-16.

    16. F. Barbon, B. Locardi, M. Verita, G. Gabbi, C. Grispibni, P. T. Leali, E.
    B. del Prever, P. Gallinaro, G. Gerulli, G. L. del Bue, G. Lualdi, E. V.
    Finzi, P. Giusti, and F. Marotti, "Biocompatibility and Osteogenetic
    Characteristics of New Biocompatible Glasses". Biomaterials, 12
    (1991) pp.565-568.

    17. T. Kitsugi, T. Yamamuro, and T. Kokubo, "Analysis of A-W
    Glass-Ceramic Surface by Micro-Beam X-Ray Diffraction", J.
    Biomed. Mater. Res., 24 (1990) pp.259-273.

    18. L. L. Hench, "Bioactive Glasses and Glass-Ceramics: A Perspective",
    in "CRC Handbook of Bioactive Ceramics", edited by Yamamuro, L.
    L. Hench, and J. Wilson, CRC Press Inc., Boca Raton, Florida, Vol. I
    (1990) pp.7-23.

    19. S. Yoshii, Y. Kakutani, T. Yamamuro, T. Nakamura, T. Kitsugi, M. Oka,
    T. Kokubo, and M. Takagi, "Strength of Bonding between A-W
    Glass-Ceramic and the Surface of Bone Cortex", J. Biomed. Mater.
    Res. 22 (1988) pp.327-338.

    20. T. Kitsugi, T. Yamamuro, H. Takeuchi, and M. Ono, "Bonding
    Behavior of Three Types of Hydroxyapatite with Different Sintering
    Temperatures Implanted in Bone", Clin. Orthop., 234 (1988)
    pp.280-290.

    21. R. E. Holmes, R. W. Bucholz, and V. Mooney, "Porous
    Hydroxyapatite as a Bone-graft Substitute in Metaphyseal Defects", J.
    Bone Joint Surg,, 68A (1986) pp.904-911.

    22. R. W. Bucholz, A. Cariton, and R. Holmes, "Interporous
    Hydroxyapatite as a Bone Graft Substitute in Tibial Plateau Fractures",
    Clin. Orthop., 240 (1989) pp.53-62.

    23. T. Kokubo, "Bioactive Glass Ceramics: Properties and Applications",
    Biomaterials, 12 (1991) pp.155-163.

    24. S. Kotani, Y. Fujita, T. Kitsugi, T. Nakamura, and T. Yamamuro,
    "Bone Bonding Mechanism of P-Tricalcium Phosphate", J. Biomed.
    Mater. Res., 25 (1991) pp.1303-1315.
    25. M. Neo, S. Kotani, Y. Fujita, T. Nakamura, and T. Yamamuro,
    "Differences in Ceramic-Bone Interface between Surface-Active
    Ceramics and Resobable Ceramics: A Study by Scanning and
    Transmission Electron Microscopy", J. Biomed. Mater. Res., 26 (1992)
    pp.255-267.

    26. G. Buare, "Biochemical Aspects Ofosseo-Integration", in "CRC
    Handbook of Bioactive Ceramics", edited by T. Yamamuro, L. L.
    Hench, and J. Wilson, CRC Press Inc., BocaRaton, Florida , Vol. I
    (1990) pp. 81-97.

    27. G. Heimke, "The Aspects and Methods of Fixation of Bone
    Replacement", in "Osseo-Integrated Implant Vol. I Basics, Materials &
    Joint Replacement", edited by Gunther Heimke, CRC Press Inc.,
    (1990) pp.1-26.

    28. I. Key, R. A. Young, and A. S. Posner, Nature, 210 (1964) pp.1050.

    29. F. C. M. Driessens, "Formation and Stability of Calcium Phosphates in
    Relation to the Phase Composition of the Mineral in Calcified Tissue" ,
    in "Bioceramic of Calcium Phosphate", edited by K. de Groot, CRC
    Press, Inc., BocaRaton, Florida, (1983) pp.1-32.

    30. H. Newesely, "High Temperature Behavior of Hydroxy- and
    Fluorapatite", J. Oral Rehab., 4 (1977) pp.97.

    31. J. Zhou, X. Zhang, J. Chen, S. Zeng, and K. de Groot, "High
    Temperature Characteristics of Synthetic Hydroxyapatite", J. Mater.
    Sci. Mater. Med., 4 (1993) pp.83-85.

    32. American Ceramic Society, "Phase Diagrams for Ceramists",
    Washington Dc, 5 (1983) pp.321-322.

    33. American Ceramic Society, "Phase Diagrams for Ceramists", 4th
    Printing, Washington DC, (1979) pp.106.

    34. L. L. Hench, and E. C. Ethridge, “Biomaterials – An Interfacial
    Approach”, Academic Press Inc., San Diego, New York, Berkeley,
    Boston, London, Sydney, Tokey, Toronto, (1980) pp.18-21.

    35. F. N. Longo, "Second National Conference on Thermal Spray", Pub.
    by American Society for Metals, USA, 1, (1984).

    36. J. H. Clare, "Metal Handbook", ninth edition, Pub. by American
    Society for Metals, USA, 1, (1984).

    37. H. S. Ingham, and A. P. Shepard, "Plasma Flame Process", METCO
    Inc., Westburg, Long Island, New York, USA, (1965) pp.11.

    38. P. Cheang and K. A. Khor, "Influence of Powder Characteristics on
    Plasma Sprayed Hydroxyapatite Coatings", J. Thermal Spray
    Technology, 5 (1996) pp.310-316.

    39. H. S. Ingham, "Flame Spray Handbook", Pub. by Metco Inc., New
    York, 35, Vol. 3, (1965) pp.17.

    40. J. Forgione, "Statistical Aspects of Failure Analysis", American
    Society for Metals, (1964) pp.360-364.

    無法下載圖示 全文公開日期 2014/07/26 (校內網路)
    全文公開日期 本全文未授權公開 (校外網路)
    全文公開日期 本全文未授權公開 (國家圖書館:臺灣博碩士論文系統)
    QR CODE