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| 研究生： |
翁仲毅 Chung-Yi Weng |
|---|---|
| 論文名稱： |
設計具有空間電荷與高幾何梯度之非對稱異質薄膜實現超高效鹽差能源發電 Engineered Asymmetric Heterogeneous Membranes with Space Charges and High Geometric Gradients for Ultrahigh-Performance Salinity Gradient Power Generation |
| 指導教授： |
葉禮賢
Li-Hsien Yeh |
| 口試委員: |
黃俊仁
Chun-Jen Huang 黃俊仁 Chun-Jen Huang 蔡德豪 De-Hao Tsai 邱昱誠 Yu-Cheng Chiu |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2021 |
| 畢業學年度： | 109 |
| 語文別： | 中文 |
| 論文頁數： | 105 |
| 中文關鍵詞： | 奈米流體學 、水凝膠 、離子傳輸 、滲透能源轉換 、離子電流整流 、氧化鋁奈米通道薄膜 |
| 外文關鍵詞： | Nanofluidics, Hydrogel, Ion transport, Osmotic energy conversion, Ion current rectification, Alumina nanochannel membrane |
| 相關次數： | 點閱：360 下載：2 |
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鹽差能源(或稱滲透能源)，係指在具離子選擇性的奈米孔/奈米通道薄膜的幫助下，藉由逆向電滲析將儲存於鹽差中的能量轉換成電能，由於其能源取得非常環保，且蘊含於海洋/河口或鹽湖/河口的交界處，使得這類能源受到許多人的關注。在早期的研究中，鹽差能源的收集多採用具表面電荷的奈米通道膜，然而這類奈米通道膜皆因離子選擇性不足和質傳速率(或薄膜電導)低下之因素，其能源輸出仍低於可商用化之基準(5 W/m2)。直到最近，才有研究指出若使用具空間電荷的奈米通道薄膜，有效地解決上述兩個主要問題。受此啟發，我們設計了由(2-甲基丙烯醯基氧乙基)三甲基氯化銨(TMAEMA)水凝膠及高度有序分枝型氧化鋁奈米通道膜(BANM)組成的新型非對稱異質膜。前者可賦予異質膜帶有局部空間電荷，而後者可以增加異質膜的幾何梯度。實驗結果顯示TMAEMA@BANM異質膜具有高陰離子選擇性與類二極體之離子整流行為，此結果同時也能被我們模擬預測之數值趨勢所佐證。因此我們進一步將此離子二極體薄膜(TMAEMA@BANM)應用於鹽差能源轉換。令人驚訝的是，TMAEMA@BANM異質膜於仿造海水和河水的鹽差 (500 mM/10 mM NaCl之濃度差) 下，可獲取前所未有高的8.08 W/m2滲透能源獲取功率。更出奇的是，此獲取功率還可於仿造鹽湖和河水的鹽差 (5000 mM/10 mM NaCl之濃度差) 下，進一步提升到約46.9 W/m2的超高功率。很顯然地，上述兩個能源轉換輸出功率都超越了所有過去先進離子選擇膜系統所得到的結果。本論文之研究成果闡明了具空間電荷、高幾何梯度和二極體離子傳輸特性的離子選擇膜設計對於次世代超高效滲透發電裝置之開發至關重要。
Salinity gradient power (or known as osmotic power), where energy stored in a salinity gradient can be converted into electricity by reverse electrodialysis with the assistance of ion-selective nanopore/nanochannel membranes has drawn much attention because this type of energy resource is eco-friendly and abundant at sea/river or salt-lake/river interfaces. In the early-stage researches, nanochannel membranes with surface charges were mostly used to collect salinity gradient power; however, most of energy outputs achieved were still below the commercial benchmark (5 W/m2) because of the insufficient ion selectivity and low mass transportation rate (or membrane conductance). Until recently, it has been shown that nanochannel membranes with space charges are capable of resolving the above-mentioned two main problems. Inspired by this, we engineer the novel asymmetric heterogeneous membranes, consisting of 2-trimethylammonium ethyl methacrylate chloride (TMAEMA) hydrogel and highly ordered branched alumina nanochannel membrane (BANM). The former can render the composite membrane locally space-charged and the latter can increase the geometric gradient of the membrane. Experimental results obtained reveal that the TMAEMA@BANM heterogeneous membrane is of high anion selectivity and shows the diode-like ion transport behavior, which is supported by our modeling prediction. We then apply the ionic diode membrane, TMAEMA@BANM, in salinity gradient power conversion. Amazingly, we show that the TMAEMA@BANM can achieve an unprecedented power of 8.08 W/m2 by mixing artificial seawater and river water (500 mM/10 mM NaCl gradient). More surprisingly, the power produced can be further upgraded to an ultrahigh value of about 46.9 W/m2 by mixing salt lake water and river water (5000 mM/10 mM NaCl gradient). Both the values of the generated salinity gradient powers apparently outperform the previously reported values from all the state-of-the-art ion-selective membranes. These findings reported indicate that the design of ion-selective membranes with space charges, high geometry gradient and ionic diode transport property is of crucial importance towards the next-generation ultrahigh performance osmotic power generators.
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