本文探討次微米級核殼型橡膠(CSR)、奈米級無機二氧化矽顆粒(SNP)和熱還原氧化石墨烯(TRGO)三種特用添加劑對苯乙烯(St)/乙烯基酯(VER)/特用添加劑三成份系統其聚合固化之微觀型態結構、抗體積收縮及機械性質之影響。
奈米級無機二氧化矽顆粒其表面經由帶C=C雙鍵的矽烷MPS改質而得，次微米級核殼型橡膠(CSR)其核心為聚丙烯酸正丁酯(PBA)，而外殼主要為聚甲基丙烯酸甲酯(PMMA)，並且用15 mole %帶有環氧基團之甲基丙烯酸環丙氧酯(GMA)改質外殼。氧化石墨則藉由帶有C=C雙鍵之3-(甲基丙烯醯氧)丙基三甲氧基矽烷(γ-MPS)改質親水性氧化石墨獲得官能基化氧化石墨。
上述三種特用添加劑對St/VER/特用添加劑三成份系統在反應前之相容性，固化樣品之SEM及TEM微觀結構、體積收縮及機械性質，將於文中探討之其聚合物之實驗結果。

The effects of the submicron-scale core–shell rubber (CSR), nano-scale silane-grafted silica nanoparticles (SNP) and thermally reduced graphene oxide as special additives on volume shrinkage characteristics and mechanical properties of the styrene (St)/vinyl ester resin(VER)/special additive ternary systems cured at 120 ℃ and post cured at 150 ℃have been investigated.
The SNP with a diameter of 15 nm was synthesized by size-controllable hydrolysis of elemental silicon, followed by the surface treatment of 3-methacryloxypropyltrimethoxysilane (γ-MPS) to obtain the MPS-silica. The CSRs were synthesized by two-stage soapless emulsion polymerizations, where the soft core was made from rubbery poly(n-butyl acrylate), and the hard shell was made from 85 mole% of methyl methacrylate, 15mol% glycidyl methacrylate, and 1mole% of ethylene glycol dimethacrylate as the crosslinking agent.
The experimental results are explained by an integrated approach of measurements of the static phase characteristics of a St/VER/special additive system, the cured sample morphology with SEM, TEM, and mechanical properties.

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