本實驗使用一套可變體積-附視窗暨影像處理系統的高壓相平衡分析裝置，以合成法量取由丁二烯萃取溶劑DMF或NMP與1-丁烯、異丁烯、順丁烯-2、反丁烯-2、正丁烷、異丁烷或甲基乙炔等所組合而成十四組雙成分系統的汽液相平衡實驗數據，量測溫度介於298.15 K ~ 348.15 K之間，平衡壓力則介於1 bar ~ 20 bar之間。實驗所量取的雙成份系統之汽液相平衡數據均分別使用 NRTL-HOC及 UNIQUAC-HOC 模式關聯，同時也求取最適化的二元參數值。

In the present study, a visual and volume-variable high-pressure phase equilibrium analyzer (PEA) was used to measure the phase equilibrium data for the binary mixtures containing an extractive solvent, N,N-dimethylformamide (DMF) or N-methylpyrrolidone (NMP) with 1-butene、iso-butene、cis-butene-2、trans-butene-2、n-butane、iso-butane、methyl acetylene at temperatures from 298.15 K to 348.15 K and pressures from 1 bar to 20 bar. All the phase equilibrium data correlated with the NRTL-HOC and the UNIQUAC-HOC models, respectively, and simultaneously determine the optimal values of the binary parameters.

Abrams, D. S. and J. M. Prausnitz, Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems, AIChE J., 21, 116-128 (1975).
Asatani, H. and W. Hayduk, Solubilities of Gaseous Butadiene and Butene-2 in Possible Extractive Distillation Solvents, Can. J. Chem. Eng, 61, 227-2328 (1983).
Chemistry WebBook, the National Institute of Standards and Technology (NIST) , http://webbook.nist.gov/chemistry/, USA.
Chiu, H. Y., R. F. Jung, M. J. Lee, and H. M. Lin, Vapor–Liquid Phase Equilibrium Behavior of Mixtures Containing Supercritical Carbon Dioxide near Critical Region, J. Supercrit. Fluids, 44, 273–278 (2008a).
Chiu, H. Y., M. J. Lee, and H. M. Lin, Vapor-Liquid Phase Boundaries of Binary Mixtures of Carbon Dioxide with Ethanol and Acetone, Chem. Eng. Data, 53, 2393–2402 (2008b).
Deiters, U. K. and G. M. Schneider, High Pressure Phase Equilibria: Experimental Methods , Fluid Phase Equilib., 29, 145-160 (1986).
Gerrard, W., Significance of the Solubility of Hydrocarbon Gases in Liquids in Relation to the Intermolecular Structure of Liquids and the Essential Pattern of Data for All Gases, J. Appl. Chem. Biotechnol., 23, 1-17 (1973).
Hayden, J. G. and J. P. O'Connell, A Generalized Method for Predicting Second Virial Coefficients, Ind. Eng. Chem. Process Des. Dev., 14, 209-216 (1975).
Ihmels, E. C., K. Fischer, and J. Gmehling, Thermodynamic Properties of the Butenes Part I. Experimental Densities, Vapor Pressures, and Critical Points, Fluid Phase Equilib., 228-229, 155 (2005).
Iwai, Y., M. R. Margerum, and B. C.-Y. Lu, A New Three-Parameter Cubic Equation of State for Polar Fluids and Fluid Mixtures, Fluid Phase Equilib., 42, 21-41 (1988).
Jan, D. S. and Tsai, F. N., A New Four Parameter Cubic Equation of State for Mixtures Vapor-Liquid Equilibrium Calculation, Can. J. Chem. Eng., 70, 320-329 (1992).
Konrad, R., I. Swaid, and G. M. Schneider, High-Pressure Phase Studies on Fluid Mixtures of Low-Volatile Organic Substances with Supercritical Carbon Dioxide, Fluid Phase Equilib., 10, 307-314 (1983).
Matzik, I. and G. M. Schneider, Fluid Phase Equilibria of Binary Mixtures of SF6 with Octane, Nonane, Hendecane, and Decahydronaphthalene, Cis at Temperatures between 280 K and 440 K and at Pressures up to 140 MPa in Comparison to Mixtures of Hydrocarbons with CO2, CF4, and CHF3, Ber. Bunsenges. Phys. Chem., 89, 551-555 (1985).

Oliveira, J. Vladimir de and A. M. Cohen Uller, Solubility of 1,3-Butadiene and Methyl Propene in N-methyl-2-pyrrolidone, Fluid Phase Equilib., 46, 267-280 (1989).
Patel, N. C. and A. S. Teja, A New Cubic Equation of State for Fluids and Fluid Mixtures , Chem. Eng. Sci., 37, 463-473 (1982).
Peng, D. Y. and D. B. Robinson, A New Two-Constant Equation of State , Ind. Eng. Chem. Fundam., 15, 59-64 (1976).
Prausnitz, J. M., T. F. Anderson, E. A. Grens, C. A. Eckert, R. Hsieh, and J.P. O'Connell, Computer Calculations for Multicomponent Vapor-Liquid and Liquid-Liquid Equilibria, Prentice-Hall, New York, NY ( 1980).
Renon, H. and J. M. Prausnitz, Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures, AIChE J., 14, 135-144 (1968).
Soave, G., Equilibrium Constants from a Modified Redlich-Kwong Equation of State, Chem. Eng. Sci., 27, 1197-1203 (1972).
Wilding, W. V., L. C. Wilson, and G. M. Wilson, Vapor-Liquid Equilibrium Measurements on Five Binary Mixtures, Fluid Phase Equilib., 36, 67-90 (1987).
Ye, W., R. Shen, W. Liu, and J. Chen, Densities and Volumetric Properties of N-methyl-2-pyrrolidone with Aromatic Hydrocarbon at Different Temperatures, J. Chem. Thermodyn., 39, 115-122 (2007).
Zhang, G. and W. Hayduk, The Solubility of Isobutane and Isobutylene in Associated Solvents, Can. J. Chem. Eng, 6, 713-718 (1984).
Zuniga-Moreno, A. and L. A. Galicia-Luna, Compressed Liquid Densities and Excess Volumes for the Binary System CO2 + N,N-Dimethylformamide (DMF) from (313 to 363) K and Pressures up to 25 MPa, J. Chem. Eng. Data, 50, 1224-1233 (2005).
林河木、李明哲，「超臨界流體系統平衡溶解度之量測及關聯」，化工技術，第六卷，第十期，第120-138 頁 (1996)。
郭東雄，「轉化型煉油廠中石油供應鏈規劃與排程之整合策略」，博士論文，國立成功大學化學工程所 (2008)。
郭東雄，「萃取蒸餾及催化技術原理和應用製程研究」，經濟部暨所屬機關因公出國人員報告書，第5-10頁 (2012)。
陳維德，李明禮，「C10003660_1_三輕更新投資計畫GTC BTX出國報告書」，第7-10頁 (2011)。
劉致中，「石化產業年鑑」，工研院產經中心出版，第2篇，第2章，第9-12頁 (2010)。