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研究生: 游雅婷
Ya-ting Yu
論文名稱: Epoxy/PU摻合程序硬化行為影響效應之研究
The influence of blend process on curing Behavior of Epoxy/PU Resin system
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 邱士軒
none
李俊毅
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2012
畢業學年度: 100
語文別: 中文
論文頁數: 83
中文關鍵詞: 異方性導電膜咪唑微膠囊
外文關鍵詞: Anisotropic conductive film (ACF), Imidazole, M
相關次數: 點閱:264下載:0
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  • 針對異方性導電膜(Anisotropic Conductive Film,ACF)未來應用之需求,期望開發出能快速硬化,儲存壽命長之配料系統,並能符合應用之性能。
    本研究使用不同加工方式及不同條件前處理,來製備類(仿)微膠囊,使用咪唑化合物做為環氧樹脂之硬化劑,epoxy resin聚合結構是利用FT-IR進行官能基分析及鑑定;使用DSC分析類(仿)微膠囊之潛在硬化行為,利用TGA、TMA及peeling test進行熱性質與接著性之分析,經由類(仿)微膠囊包覆,能夠有效延遲環氧樹脂與硬化劑反應時間,可經由選擇殼層材質,製備不同反應速率之潛在型硬化劑。


    In this study, we aim to develop rapid hardening and long shelf life anisotropic conductive film (ACF) for the application in future. The experimental employed different manufacture processing and conditions to fabricate microcapsules. The imidazole was used as hardener for epoxy. Then the microcapsules were evaluated by FTIR, DSC, TGA, TMA, peeling test to characterize the physical-chemical properties. Through microencapsulation, the epoxy/hardener reaction time increase and the latent hardener in varied reaction time could be synthesized from different microencapsulate shell material.

    目錄 中文摘要 ................................................................... I Abstract .................................................................. II 謝誌 ..................................................................... III 目錄 ...................................................................... IV 圖目錄 ................................................................... VII 表目錄 .................................................................... IX 第一章 緒論 ............................................................... 1 1.1 研究背景 .............................................................. 1 1.2 前言 .................................................................. 2 1.3 異方性導電膜(ACF)之介紹 ............................................. 3 1.4 時事回顧 ............................................................. 12 第二章 文獻回顧 .......................................................... 15 2.1 Polyurethane ......................................................... 15 2.1.1 聚氨酯之介紹 ....................................................... 15 2.1.2 聚氨酯之概論 ....................................................... 16 2.2 環氧樹脂之介紹 ....................................................... 19 2.2.1 環氧樹脂興起 ....................................................... 19 2.2.2 環氧樹脂之定義 ..................................................... 20 2.2.3 環氧樹脂之種類 ..................................................... 23 2.3 環氧樹脂與聚氨酯 ..................................................... 26 2.3.1 氧樹脂與聚氨酯之改質 ............................................... 26 2.3.2 互穿型高分子網狀結構體( Interpenetrating Polymer Networks,IPN ) ..................................................................... 27 2.4 微膠囊 ............................................................... 27 2.4.1 微膠囊介紹及結構 ................................................... 27 2.4.2 微膠囊包覆技術 ..................................................... 29 2.4.3 常見的微膠囊包覆方式 ............................................... 32 2.3.4 延續 ............................................................... 35 第三章 實驗 .............................................................. 36 3.1 實驗流程 ............................................................. 36 3.2 實驗藥品 ............................................................. 36 3.3 實驗步驟 ............................................................. 37 3.4 儀器原理及操作條件 ................................................... 38 3.4.1 傅立葉轉換紅外線光譜儀(Fourier Transform Infrared Spectrometer,FT-IR) ............................................ 38 3.4.2 熱重損失分析儀(Thermal Gravimetric Analyzer, TGA) ..................................................................... 38 3.4.3 熱示差掃描量熱儀(Differential Scanning Calorimeter,DSC) ......... 39 3.4.4 剝離強度測試(peeling strength) ................................... 39 3.4.5 熱機械分析儀(Thermo Mechanical Analyzer,TMA) .................... 40 第四章 結果與討論 ........................................................ 41 4.1 原物料之分析鑑定 ..................................................... 41 4.2 Epoxy resin與imidazole之反應結構分析鑑定 ............................. 41 4.3 PU之軟化點認 ......................................................... 42 4.4 不同加工程序對反應速率之分析鑑定 ..................................... 42 4.5 不同處理方式及不同硬化劑含量對反應速率之分析鑑定 ..................... 44 4.6 固化物之熱性質及物性分析 ............................................. 46 第五章 結論 .............................................................. 62 參考文獻 .................................................................. 63 附錄 ...................................................................... 68 作者簡介 .................................................................. 71

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