本研究探討一系列生物分解性界面活性劑之合成、性質及應用。以糊精之衍生物構造中glucose unit為親水基，oxirane-containing為疏水基合成glycoside polyethers，為具生物分解性之界面活性劑。本研究合成之界面活性劑有九種，由糊精，環氧氯丙烷及聚乙二醇烷基醚化合物為原料反應而得。其構造中含非離子性親水基Ethylene Oxide系列者為六種，不同疏水基之系列者為三種。本研究合成之界面活性劑與一般常用之界面活性劑ABS比較，合成物有甚佳之生物分解性，其原因為所使用之原料Dextrin為澱粉之加水分解物，化學構造為glucose unit，極易受到排水或河流水中之微生物分解，合成物均具有pH緩衝能力。而構造中帶有EO基之系列，緩衝能力較佳。酸鹼較強之條件下。合成物具有耐酸鹼性。由於合成物具有極佳之降低表面張力、低起泡性、濕潤性、耐酸鹼性及分散性等重要性質。在布的精練、漂白等前處理過程中，合成物之使用，可增加鹼劑、漂白劑對布的滲透作用，增進精練漂白效果。結果顯示合成物可作為棉織物之前處理藥劑。
合成物使用於棉纖維織物之直接染料染色，依染料助劑之不同，產生緩染或促染效果。光譜法之結果顯示，在染浴中助劑與染料形成複合體，複合體之形成減少染料之凝集，因而減少染料對纖維之親和力，染色過程呈現緩染效果。若複合體之形成，降低未凝集之染料，減少染料之吸光度，增加對纖維之親和力，染色過程呈現促染效果。

A series of biodegradable surfactants has been prepared by the reaction of the propylene glycol polyglucosides with a hydrophobic oxirane-containing material of the glycidyl ether. These surfactants have been obtained by the reactions of dextrin, epichlorohydrin and polyoxyethylene alkyl ether in this study. They are containing six compounds of nonionic polyoxyethylene chain and three compounds of various length of hydrophobic alkyl chain in structure. These surfactants are found to exhibit considerably more highly biodegradable than traditional surfactant (ABS) does, because they would be the natural foods of bacteria present in sewage or raw river water. These surfactants exhibit acid-alkali resistance and surface activities including surface tension, low-foaming and wetting power. These surfactants also have good ability to improve the whiteness and the wetting power of cotton fabrics in a hydrogen peroxide bleaching system.
The results of the influence of a series of biodegradable dextrin derivative surfactants on the direct dyes-cotton dyeing system have been found that the presence of these surfactants in direct dyeing solution can retard or increase the rate of cotton dyeing depending on the formation of the disaggregated or more aggregated direct dyes in dye-surfactant systems, the degree of aggregation of direct dyes influencing the rate of cotton dyeing.

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