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研究生: 葉玉琳
YU-LIN YA
論文名稱: 探討不同濃度PS/PMMA相分離高分子共聚物經環己烷處理所產生的表面結構轉印至NOA65光學膠上所形成凹凸紋理結構的光學差異性
transfer-printed using phase-separated PS/PMMA surface structures treated with cyclohexane
指導教授: 李俊毅
Jiunn-Yih Lee
口試委員: 邱士軒
Shih-Hsuan Chiu
陳志堅
Jyh-Chien Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 中文
論文頁數: 87
中文關鍵詞: 相分離NOA65轉印
外文關鍵詞: phase-separate, NOA65, transfer-printed
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在本文中,我們探討經間接轉印不同濃度PS/PMMA高分子相分離共聚物薄層至光學軟膠片NOA65上凹凸表面紋理結構分佈的物性及光學特性。本實驗是利用PS/PMMA兩不相容的高分子聚合物的相分離狀態,利用旋轉塗佈在玻璃表面且經環己烷處理後所產生的凹凸紋理結構,再以PDMS作為間接轉印橋梁,轉印到紫外光光學膠表面NOA65。PS/PMMA膜(membrane)為相分離的三層次薄層(subthin layer)結構,其頂層為PS-rich層、PS/PMMA共混物層和底層PMMA-rich層,通過有選擇性的溶劑(環己烷)溶解PS相,即可在薄膜表層上形成凹凸結構。所產生不同紋理的凹凸結構經間接轉印至NOA65上,會產生不連續凹凸紋理、平滑表面內裝飾很多凹處到呈現較明顯凹凸結構。NOA65光學軟膠本身不僅具有高軟度可捲曲和延展性較好的彈力特性外,然而本實驗觀察中,也發現PS/PMMA為40wt%,其凹凸紋理較均勻分佈於表面結構,其轉印到NOA65光學膠表面上,得到好的疏水性效果及灰塵不易沾黏等特性的自潔效應(正所謂蓮花效應),及具有高穿透度、低反射與最小霧度值(霧度值常作為清晰度表示),這些特性都可以應用在許多理想光學元件、螢幕,或玻璃展示櫃等。


In this paper, we studied the physical and optical properties of the mosaic textured surface of NOA65 photopolymer transfer-printed indirectly using thin layers of phase-separated PS/PMMA copolymer. The immiscible, phase-separated PS/PMMA co-polymer was spin-coated onto a glass surface and treated with cyclohexane to form the mosaic texture, then the texture was used to transfer print onto UV-curable NOA65 photopolymer with PDMS used as an indirect transfer bridge. The PS/PMMA membrane had three phase-separated sub-thin layer structures: the top PS-rich layer, the interlayer PS/PMMA blend, and the underlying PMMA-rich layer. Using a selective solvent (cyclohexane), the PS phase of the membrane surface was dissolved to form the mosaic structure. By transfer printing the mosaic structures of different textures indirectly onto the NOA65, three varieties of surface structure were formed: Non-continuous mosaic textures, smooth surfaces with many interior indentations, and more obvious mosaic structures. The NOA65 photopolymer not only has favorable elasticity, rendering it rollable and malleable, but our experimental observations also revealed that as there are samples with 60% PS and samples with 40% PMMA, transfer-printing onto the more evenly distributed mosaic texture on the NOA65 surface enabled it to have self-cleaning effects, such as hydrophobicity and not easily attracting dust (the so-called lotus effect) as well as possessing high optical transmittance, and low reflectance with minimal HAZE value (HAZE value often is expressed as clarity). These features can be applied to many common optical components such as screens, or glass display cabinets etc.

中文摘要 I ABSTRACT II 目 錄 IV 圖 目 錄 VIII 表 目 錄 XI 第一章 緒論 1 1.1前言 1 1.2 超疏水表面起源和製備 4 1.3光學基本定理 4 1.3.1光的本質 4 1.3.2光波 5 1.3.3 折射與反射 7 1.2.3.1 反射定律 7 1.3.3.2 折射定律 8 1.3.4 全反射(Total Internal Reflection)現象 9 1.3.5 光散射 10 1.3.6 光繞射 11 1.3.7 反射與漫反射 12 第二章 相關原理與文獻回顧 13 2.1 抗反射光學效應 13 2.1.1 破壞性干涉 13 2.2 表面接觸角介紹 14 2.2.1 蓮花效應 14 2.2.2 液滴濕潤表面現 15 2.2.3 表面接觸角量測 17 2.2.4 遲滯角 18 2.2.5 滾動角 19 2.2.6 超疏水條件 20 2.3 超疏水材料 21 2.3.1 超疏水原理和機制 21 2.3.2超疏水表面粗糙度原理 21 2.3.3 製備超疏水表面方式 25 第三章 研究動機與架構 30 3.1研究動機 30 3.2 實驗架構 31 第四章 實驗方法 32 4.1實驗材料與設備 32 4.1.1 實驗材料 32 4.1.2 實驗設備 36 4.2 實驗步驟及製作流程 38 4.2.1 基本試片製作說明 38 4.2.2 實驗方法(一) 41 4.2.3實驗方法(二) 43 4.3掃描電子顯微鏡(SEM)量測 45 4.3.1 SEM原理 45 4.4原子力顯微鏡(AFM)量測吸附力 46 4.4.1 AFM原 46 3.4.2原子力顯微鏡探針 47 4.4.3 AFM量測(力-距離)曲線 49 4.5接觸角計量測水滴接觸角 50 4.5.1接觸角計 50 4.5.2接觸角定義 51 4.6 紫外線光譜儀(UV/VIS/NIR spectrometers) 52 4.7 霧度、穿透率量測 52 第五章 結果與討論 54 5.1 在SEM下觀察,未浸泡及浸泡在環己烷溶液下的差異 54 5.2不同PS/PMMA濃度下,表面凹凸紋理薄膜厚度 57 5.3 AFM下觀察薄膜凹凸紋理結構 59 5.4 AFM下觀察薄膜凹凸紋理結構 62 5.5 光學量測 63 5.6 霧度量測 66 第六章 結果 67 第七章 未來展望 68 第八章 參考文獻 69

[1] 中華民國科學技術年鑑(九十二年版) 國科會自然處,"奈米"
[2] W. Barthlott,C. Neinhuis,"Purity of the sacred lotus,or escape from contamination in biological surfaces",1997,Planta,202,1-8
[3] T.Wagner, C. Neinhuis,W. Barthlott,"Wettability and Contaminability of Insect Wings as a Function of Their Surface Sculptures",1996,ActaZool, 77(3),213-255
[4] R. Blossey,"Self-cleaning surfaces — virtual realities",2003, Nat. Mater.,2(5),301-306
[5] W. Barthlott, C. Neinhuis,"Purity of the sacred lotus, or escape from contamination in biological surfaces",1997,Planta, 1-8, 202
[6] W. Barthlott, C. Neinhuis,"Purity of the sacred lotus, or escape from contamination in biological surfaces",1997,Planta,1-841, 202
[7] 內尾舜二著,"實用塑膠透鏡",1999,台灣復文興業
[8] 李冠卿,"近代光學",1988,聯經出版社,台北
[9] 岸川利郎著,杜光宗編譯,"光學入門",2000,建宏出版社,基隆
[10] 蔡俊欽,"導光板光學設計及製程之最佳化研究",2004,國立高雄應用科技大學碩士論文
[11] 郭惠隆,"LCD 用光學薄膜",2002,化工技術第3 期
[12] 張詠,"超疏水高分子薄膜應用於奈米草矽基材及奈米碳管基材其抗反射性與耐候性之探討與研究",2009,國立台灣科技大學材料科學與工程研,碩士學位論文
[13] Dinguo Chen,"Anti-reflection (AR) coating made by sol-gel processes: A review",2000,Solar Energy Material, Vol.68, 313-336
[14] L. Jiang, Y. Zhao, J. Zhai,"A lotus-leaf-like superhydrophobic surface: A porous microsphere/nanofiber composite film prepared by electrohydrodynamics",2004, Angewandte Chemie - International Edition,43(33),4338-4341
[15] Y.T. Cheng, D.E. Rodak , C.A. Wong, C. A. Hayden,"Effects of micro-and nano-structures on the self-cleaning behaviour of lotus leaves",2006,Nanotechnology, 17(5), 1359-1362.
[16] 徐世昌,"花自清潔功能與奈米科技之應用",2006,科學發展,354,60-63
[17] Y.T. Cheng, D.E. Rodak , C.A. Wong, C. A. Hayden,"Effects of micro-and nano-structures on the self-cleaning behaviour of lotus leaves",2006,Nanotechnology,17(5), 1359-1362.
[18] K. Ma,T.S. Chung,R.J. Good,"Surface Energy of Thermotropic Liquid crystalline polyesters and polyesteramide",1998,Polym. Sci.B,36(13), 2327-2337
[19] S. Wu,"Polymer Interface and Adhesion",1982 Marcel Dekker Inc.,16
[20] A. W. Neumann, D. Renzow, H. Reumuth, I. E. Richter,"Gleichgewiethte an der Phasengrenze zwisehen FestkSrpern",1971,Forschr.Kolloide, Polymere,55,49
[21] J.F. Padday,"Wetting Spreadding and Adhesion",1978,Academic Press,17
[22] J.F. Padday,"Wetting Spreadding and Adhesion",1978,Academic Press
[23] Miwa, M Nakajima, Akira,Fujishima, Akira,Hashimoto, Kazuhito, Watanabe, Toshiya., "Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces",2000,Langmuir 16(13),5754
[24] J. Tsibouklis , T. G. Nevell,"Ultra-Low Surface Energy Polymers:The Molecular Design Requirements",2003,Adv. Master.,14,647
[25] D. P. Carlson , W. Schmiegel,"Ullmann’s Encyclopedia of Industrial Chemistry",1988,Weinheim, 393
[26] L. Jiang , D. Zhu,"Reversible Switching between Superhydrophilicity and Superhydrophobicity",2004,Angew Chem. Int. Ed.,43,357
[27] R. N. Wenzel,"Resistance of solid surfaces to wetting by water",1936,Ind. Eng. Chem.,28,998
[28] D. Queue,"On water reoellency",2005,Soft Matter ,1,55
[29] A. B. D. Cassie and S. Baxer,"Wettability of porous surfaces",1994, Trans. Faraday Soc.,40,546
[30] S. B axter, A.B.D. Cassie,"The Water Repellancy of Fabrics and a New Water Repellancy Test",1945,J. Textile Inst. 36, T67-90
[31] Rao, K.S., El‐Hami, K., Kodaki, T., Matsushige, K. , Makino, K., "A no-vel method for synthesis of silica nanoparticles",2005 Journal of Colloid and Interface Science 289, 125‐131
[32] Mine, E., Nagao, D., Kobayashi, Y. , Konno, M. "Solvent effects on particle formation in hydrolysis of tetraethyl orthosilicate",2005, Journal of Sol-Gel scienceand technology35,197-201
[33] Shirtcliffe, N.J., McHale, G., Newton, M.I. , Perry, C.C. "Intrinsically superhydrophobic organosilica sol‐gel foams",2003, Langmuir 19, 5626‐5631
[34] Yang, S.Y., Chen, S., Tian, Y., Feng, C. Chen, L. "Facile transformation of a nativep polystyrene (PS) film into a stable superhydrophobic surface visol‐gel process", 2008,Chemistry of Materials 20, 1233‐1235
[35] Takai, O., A. Hozumi, and N. Sugimoto,"Coating of transparent water-repellent thin films by plasma-enhanced CVD",1997, Journal of Non-Crystalline Solids, 218: p. 280-285
[36] Hozumi, A., et al.,"Preparation of transparent water-repellent films by radio-frequency plasma-enhanced chemical vapour deposition",1997 Journal of Materials Science, 32(16): p. 4253-4259
[37] Vaswani, S., J. Koskinen, D.W. Hess,"Surface modification of paper and cellulose by plasma-assisted deposition of fluorocarbon films",2005, Surface & Coatings Technology, 195(2-3): p. 121-129
[38] Hodak, S.K., et al.," Enhancement of the hydrophobicity of silk fabrics by SF6 plasma",2008, Applied Surface Science, 254(15): p. 4744-4749
[39] Liu, B., He, Y.N., Fan, Y. & Wang, X.G.,"Fabricating super‐hydrophobic lotus‐leaf‐like surfaces through soft‐lithographic imprinting",2006,Macromolecular Rapid Communications 27, 1859‐1864
[40] L. Jung-Pil, C. Sinho, P. Soojin,"Preparation of silica nanospheres and porous polymer membranes with controlled morphologies via nanophase separation",2012, Nanoscale Research Letters , 7-440
[41] Venkateshwarlu Gopishetty,Ihor Tokarev and Sergiy Minko, "Biocompatible stimuli-responsive hydrogel porous membranes via phase separation of a polyvinyl alcohol and Na-alginate intermolecular complex",2012, J. Mater. Chem., 22, 19482-19487
[42] 蔡元鈞,"高分子薄膜模仿壁虎纖毛微結構表面特性探討",2008,國立台灣科技大學材料科學與工程研究所,碩士學位論文
[43] Mike Bowers,"THE BOWERS GROUP",1997,research projects, synthetic polymer.
[44] .張雲閔,"高分子分散液晶-黏土奈米複材膜之製備與光電性質研究",2006,中原大學化學研究所,碩士學位論文
[45] .蔡燿全,"奈米級仿生黏著科技",2006,國立台灣大學機械工程研究所,碩士學位論文

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