因應節能減碳的政策，電動車發展逐漸被全球各國重視，且需求量愈見增加，而鋰離子電池由於能量密度高之原因常被考慮用於電動車之儲能，磷酸鋰鐵 (LiFePO4)正極材料是常見運用於電動車之正極材料，但由於其導電度及高溫性能仍有待改善之空間，因此目前仍是研究的重點。本論文研究目的為利用常壓射頻電漿對LiFePO4正極進行表面改質，藉由親水官能基接枝於正極表面，而後形成非晶質相含碳化合物來達成提升在高溫下對磷酸鋰鐵正極材料之保護，避免Fe離子自結構中釋出以改善電容量衰退之情形。
由OES電漿物種分析結果得知電漿內部物種有許多氫氧官能基及Ar物種。在水接觸角實驗結果顯示，LiFePO4電極於水接觸角角度為未處理(original)>常壓射頻電漿改質掃描次數3次(PA3)>常壓射頻電漿改質掃描次數10次(PA10)>常壓射頻電漿改質掃描次數次(PA6)。經過常壓電漿改質次數6次的試片(PA6)，具有最親水之水接觸角角度。從Raman分析中可得知，此電極的石墨化比例些微下降，故確認常壓射頻電漿處理6次的LiFePO4具有較多之親水官能基之接枝於正極表面。在高溫充放電後之TEM影像顯示，經過常壓射頻電漿改質6次之LiFePO4顆粒外表層，具有明顯的非晶相之含碳化合物形成，因此常壓射頻電漿成功改質LiFePO4正極以達保護效果，從高溫電性測試結果得知，在電容量之提升首圈放電電容量:original，161.4 mAh/g；PA6，165.9mAh/g及經高溫充放電35迴圈電容量:original，149.7 mAh/g；PA6，158.6mAh/g，衰退率為: original，7.24%；PA6，4.40%，本研究確實有效改善鋰離子電池於高溫下之電池性能。

The development of electric vehicle (EV) attracts lots of attention in the world owing to the criterions of energy conservation and carbon emission reduction. Lithium ion battery is used to consider an storage on EV because of its high energy density. LiFePO4 is one of the most popular cathode materials that applies to EV regarding several advantages, such as the low price, long cycle life, environmental safety and high specific energy, respectively. However, LiFePO4 is limited to its application on EV according to the low electric conductivity, which is around 10-9 Scm-1 compares to the LiCoO2 (10-3 Scm-1) and LiMn2O4 (10-5 Scm-1) at room temperature and low cycle ability at high temperature. In order to beyond those drawbacks, many efforts have been made to improve the electrochemical performance at high temperature and the electric conductivity of bulk material.
This research is demonstrates the LiFePO4 is treated by Atmospheric Pressure Plasma Jet (APPJ). TEM shows the APPJ surface modification generates a core-shell structure of LiFePO4, which the shell presents an amorphous layer. The shell is produced by the APPJ treatment via plasma-induced grafting hydrophilic functional groups. The contact angle measurement optical emission spectroscopy analysis and high temperature electrochemical test show that the core-shell structure of LiFePO4 can enhance the cycle life, discharge capacity and avoid Fe ion released from the structure at high temperature (55℃).

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