本研究成功合成新型三苯胺的聚醯胺，這些三苯胺的聚醯胺是由新的二胺單體與二羧酸採直接聚合而成。其固有黏度介於0.42~1.03 dL/g之間，這些聚醯胺都可以塗佈成具韌性薄膜，且在極性有機溶劑具有良好的溶解性。它們的玻璃轉移溫度介於253~309°C之間、熱裂解溫度在熱重損失10%時的溫度超過400°C以上，且在800°C的殘餘率超過55%以上，顯示它們有良好的熱安定性。在電致變色性質方面CV圖均會顯示出三對可逆氧化還原峰，變色是由中性態無色變成黃色、淺藍色及深藍色，且都具有良好的電致變色穩定性。

The novel of aromatic polyamides containing pendent methoxy moieties were prepared. Polyamide were prepared from the new diamine monomer with various aromatic dicarboxylic acids. These polyamides had inherent viscosities of 0.42~1.03 dL/g. All the polyamides were readily soluble in polar organic solvents and could be cast into tough and flexible films. The polyamides exhibited thermal stability associated with their relatively high glass transition temperature (253~309°C), 10% weight loss temperature in excess of 400°C, and char yields at 800°C in nitrogen higher than 55%. Cyclic voltammograms of the polyamides showed three pair of reversible redox waves, with a color changing from colorless or pale yellowish neutral form to yellow, pale blue and deep blue oxidized forms. These polyamide all show excellent reversible electrochromic stability and high coloration efficiency

1. 吳和生、楊鴻銘 化學工程概論 高立圖書有限公司
2. 何國川，電變色智慧節能元件開發，國立台灣大學化工所
3. P. M. S. Monk, R. j. Mortimer, D. R. Rosseinsky, Electrochromism: Fundamentals and Applications, VCH, Weinheim (1995)
4. M. Green, Chem. Ind. 17 (1996) 641
5. R.J. Mortimer, Chem. Soc. Rev. 26 (1997) 147.
6. N. Leventis, Electrochromic devices, in: McGraw-Hill Encyclopedia of Science and Technology, 8th, vol. 6, McGraw-Hill, New Yok 153 (1997)
7. J. S. E. M. Svensson, C . G. Granqvist, solat energy Materials, 12 (1985) 392.
8. K. Yamanak, Japanese Journal of Appl. Phy., vol. 26 (1987) 1884.
9. B. P. Jelle, G. Hagen, Synth Mat., 54(1993) 315.
10. 吳嘉元，溶膠凝膠法合成以鉭元素為基礎的全固態電致變色元件，國立中央大學光電科學研究所(p.11)
11. 吳嘉元，溶膠凝膠法合成以鉭元素為基礎的全固態電致變色元件，國立中央大學光電科學研究所(p.16)
12. C. Harbordt, Ann. Chem. Pharm., 123, 287(1862)
13. S. Gabriel and T.A. Mass, Ber. Dtsch. Chem. Ges., 32, 1266(1899)
14. W.H.Carothers, U.S.Pat., 2, 130, 523(1938)
15. W.Michler and A.Zimmermann, Ber.Dtsch.Chem.Gesel., 14, 2117(1881)
16. MFrankel, Y.Liwschitzy and A.Zilkha, Experientia., 9, 179(1953)
17. E.L. Wittbecker and P.w.Morgan, J.Polym. Sci., 40, 289(1959)
18. P.W.Morgan and S.L.K wolek, J. Polym. Sci., 40, 299(1959)
19. R.G.Beaman, P.W.Morgan, C.R.Kroller, E.L.Wittbeaker and E.E. Magat, J.Polym.Sci., 40,39(1959).
20. J.R.Schaetgen, F.H.Koonntz and R.F.Tietz, J.Polym.Sci., 40, 377(1959)
21. D.J.Lyman and S.L.Jung, J.Polym.Sci., 40, 407(1959)
22. N. Bilow, AL. Landis and L.J. Millew, U.S. Patent., 3, 845, 018(1974)
23. C. W. Chang, G. S. Liou and S. H. Hsiao, J. Mater. Chem., 17,1007 (2007)
24. C. W. Chang, H. J. Yen, K. Y. Haung, J.M. Yeh and G.S. Liou J. Polym. Sci., 46,7937(2008)
25. 張群，合成新型含三苯胺及雜環結構之聚醯胺與聚醯亞胺及其性質研究，國立台灣科技大學化工研究所碩士論文，2009
26. Hager, F. D. Organic Syntheses 1941, 1, 544.
27. Liou, G.S.; Hsiao, S.H.; Wang H.M. J. Mater. Chem., 2009, 47, 2330-2343
28. Liou, G.S.; Chang C.W.; Chung C.W. Macromolecules 2008, 41, 8441
29. Liou, G.S.; Chang, C.W.; Hsiao, S.H. J. Mater. Chem., 2007, 17, 1007
30. Liou, G.S.; Chang, C.W. Macromolecules 2008, 41, 1667