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研究生: 張育賢
Yu-hsien Chang
論文名稱: 冷卻條件對SUS 316L被覆Inconel 52M之機械與腐蝕性質影響
The Effect of Cooling Condition on Mechanical and Corrosion Properties for Inconel 52M Cladded on Stainless Steel 316L
指導教授: 蔡顯榮
Hsien-Lung Tsai
口試委員: 王朝正
Chaur-Jeng Wang
鄭慶民
Cing-Min Jheng
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 90
中文關鍵詞: 鎳基合金316L腐蝕
外文關鍵詞: Inconel 52M, stainless steel 316L, corrosion
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  • 本研究以惰性氣體鎢極電弧銲接(GTAW)將Inconel 52M被覆於SUS316L上,研究在不同冷卻速率下,母材與被覆層間的微觀組織、機械與腐蝕性質之差異,作為未來核電廠銲補管件時參考用。
    實驗結果顯示,在稀釋率方面,有水冷卻對母材的稀釋率較無水冷卻時低。在金相觀察方面,有水冷卻時銲接試片之銲道晶粒大小較無水冷卻小,導致強度硬度之提升。在拉伸試驗方面,發現有水冷卻時破斷位置在母材處,而無水冷卻時是在銲道內,表示有水冷卻之銲件具有較高的抗拉強度。在抗蝕性方面,由於有水冷卻時之冷卻速率快、晶粒小、晶界面積較大,且因晶界為一缺陷,附近能量較高,較易與電解液中的離子反應,而造成抗蝕性較無水冷卻低。


    This study is to investigate the influence of cooling condition Inconel 52M for cladding SUS 316L on mechanical and corrosion properties by Gas Tungsten Arc Welding. It could be observed that the microstructure of the region between base and filler metal and the properties of mechanical and corrosion which can serve as a reference for further welding for nuclear power plant in the future.
    The results show that welding with water cooling backing has lower dilution ratio of matrix than without water cooling backing. It could be observed that the grain size of weld zone with water cooling backing was smaller than that without water cooling backing by using microscope. This phenomenon promoted the hardness of weld zone. In tensile test, the crack of weldment with water backing appeared in matrix. On the other hand, the crack of weldment without water cooling backing was observed in the weld zone. These phenomena implied that the weldment with water cooling backing has higher tensile strength than that without water cooling backing. In electrochemical test, the corrosion resistance of weldment with water cooling backing was lower than that without water cooling backing. Because of grain boundary is one kind of defects, which increases the free energy. These would led more ion to react with grain boundary and decreased the corrosion resistance.

    目錄 摘 要 I ABSTRACT II 誌 謝 III 第一章 前言 1 第二章 文獻回顧 3 2. 1 INCONEL 52M簡介 3 2. 2 不銹鋼簡介 4 2.2. 1 不銹鋼的分類 5 2.2. 2合金元素的添加對不銹鋼的影響 9 2. 3 銲接理論 12 2.3. 1 組成過冷與凝固 12 2.3. 2 沃斯田鐵不銹鋼凝固過程 17 2.3. 3肥粒鐵組織對沃斯田鐵不銹鋼的影響 21 2. 4 腐蝕與電化學反應 24 2.4. 1 腐蝕[40] 24 2.4. 2 電化學反應 25 2.4. 3 Nernst Equation 29 2.4. 4 極化現象 29 2.4. 5 混合電位(Mixed Potential) 31 第三章 實驗方法 34 3. 1 實驗流程 34 3. 2 實驗材料 35 3. 3 銲接參數 36 3. 4 覆銲層製作與稀釋率測定 38 3. 5 微硬度量測 39 3. 6 金相觀察 40 3. 7 彎曲試驗 40 3. 8 拉伸試驗 42 3. 9 電化學試驗 43 3. 10 電子顯微鏡觀察 44 第四章 實驗結果與討論 45 4. 1 銲道外觀及稀釋率觀察 45 4. 2 金相觀察 50 4. 3 SEM觀察與EDS分析 59 4. 5 彎曲試驗 71 4. 6 拉伸試驗 73 4. 7 電化學試驗 77 第五章 結論 84 參考文獻 85 作者簡介 91

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