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研究生： 李孟榛
Meng-Zhen Li
論文名稱： 高穿透式有機太陽能電池
Highly transparent organic photovoltaic
指導教授： 李志堅
Chih-Chien Lee
口試委員: 劉舜維
Shun-Wei Liu
張志豪
Chih-Hao Chang
范慶麟
Ching-Lin Fan
學位類別： 碩士
Master
系所名稱： 電資學院 - 電子工程系
Department of Electronic and Computer Engineering
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 77
中文關鍵詞： 穿透式有機太陽能電池 、高穿透電極 、高平均明視覺穿透度 、高演色性
外文關鍵詞： Highly transparent organic photovoltaic, highly transparent electrode, high average visible transmission, high color rendering index
相關次數： 點閱：277  下載：0 
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    • 目錄 碩士學位論文指導教授推薦書 I 碩士學位考試委員審定書 II 中文摘要 III ABSTRACT IV 誌謝 V 目錄 VI 圖目錄 IX 表目錄 XII 第一章 緒論 1 1.1 前言 1 1.2 太陽能電池介紹 2 1.3 有機太陽能電池結構介紹 3 1.3.1 單層結構 3 1.3.2 雙層異質接面結構 4 1.3.3 混合層異質接面結構 5 1.3.4 平面混合層異質接面結構 7 1.4 材料介紹 8 1.4.1 電洞傳輸材料 8 1.4.2 施體材料 8 1.4.3 受體材料 9 1.4.4 激子阻擋材料 9 1.5 穿透式OPV文獻回顧 9 1.6 實驗動機 10 第二章 理論基礎 12 2.1有機太陽能電池工作原理 12 2.2等效電路 15 2.3特性曲線 16 2.3.1 開路電壓(Voc) 16 2.3.2 短路電流(Jsc) 17 2.3.3 填充因子(FF) 18 2.3.4 功率轉換效率(PCE) 18 2.3.5 串聯電阻(Rs)與並聯電阻(Rsh) 18 第三章 實驗方法 20 3.1 實驗設備 20 3.1.1 超音波清洗機 20 3.1.2 烤盤 20 3.1.3 旋轉塗佈機 21 3.1.4 紫外光曝光機 22 3.1.5 材料純化系統 22 3.1.6 高真空熱蒸鍍機 23 3.1.7 氮氣循環手套箱 24 3.2 實驗前置作業 25 3.2.1 有機材料純化 25 3.2.2 黃光微影製程 26 3.3 實驗步驟 28 3.3.1 基板清洗 28 3.3.2 高真空熱蒸鍍製程 28 3.3.3 元件封裝 30 3.4 量測設備 30 3.4.1 膜厚儀 30 3.4.2 橢圓偏振儀 31 3.4.3 太陽光模擬器 32 3.4.4 外部量子效率量測系統 32 3.4.5 UV-VIS光譜儀 33 3.4.6 原子力顯微鏡 34 3.4.7 四點探針 35 第四章 結果與討論 36 4.1元件材料 36 4.1.1 主動層材料 36 4.1.2主動層材料吸收頻譜 36 4.2穿透電極 37 4.2.1 穿透電極之比較 37 4.2.2 不同比例下銅銀合金特性 41 4.2.3 Capping layer調變 42 4.3有機太陽能電池元件特性 43 4.3.1 主動層比例調變 43 4.3.2 主動層厚度調變 45 4.3.3 穿透電極厚度調變 48 4.4串座有機太陽能電池 52 4.4.1 非穿透式串座元件 52 4.4.2 穿透式串座元件 54 第五章 結論與未來展望 56 參考文獻 57 圖目錄 圖1-1單層結構有機太陽能電池示意圖 3 圖1-2單層結構有機太陽能電池工作原理示意圖 4 圖1-3雙層異質接面結構有機太陽能電池示意圖 4 圖1-4雙層異質接面結構有機太陽能電池工作原理示意圖 5 圖1-5混合層異質接面結構有機太陽能電池示意圖 6 圖1-6混合層異質接面結構有機太陽能電池工作原理示意圖 6 圖1-7平面混合層異質接面結構有機太陽能電池 7 圖1-8平面混合層異質接面結構有機太陽能電池工作原理示意圖 8 圖2-1異質接面有機太陽能電池工作原理示意圖 12 圖2-2激子拆解示意圖 13 圖2-3有機太陽能電池等效電路示意圖 15 圖2-4有機太陽能電池光電流對電壓曲線 16 圖2-5施體與受體能階差算開路電壓示意圖 17 圖2-6有機太陽能電池串聯電阻與並聯電阻計算方式 19 圖3-1超音波清洗機 20 圖3-2烤盤 21 圖3-3旋轉塗佈機 21 圖3-4紫外光曝光機 22 圖3-5材料純化系統 23 圖3-6高真空熱蒸鍍機 23 圖3-7氮氣循環手套箱 25 圖3-8黃光微影示意圖 26 圖3-9金屬遮罩 29 圖3-10元件示意圖 29 圖3-11封裝示意圖 30 圖3-12膜厚儀 31 圖3-13橢圓偏振儀 31 圖3-14太陽光模擬器量測系統 32 圖3-15外部量子效率量測系統 33 圖3-16 UV-VIS光譜儀 34 圖3-17原子力顯微鏡 34 圖3-18四點探針 35 圖4-1有機材料之分子結構圖 36 圖4-2將ClAlPc與C60之吸收係數頻譜 37 圖4-3 Cu:Ag (1:60, 8 nm)與Ag (8 nm)之反射頻譜 38 圖4-4 (a) Cu:Ag (1:60, 8 nm)與(b) Ag (8 nm)之表面形貌 39 圖4-5在未退火下與分別退火100℃、時間為30、60與90分鐘之(a)Ag (8 nm)、(c) Cu:Ag (1:60, 8 nm)與(e) Cu (8 nm)穿透頻譜，(b) Ag (8 nm)、(d) Cu:Ag (1:60, 8 nm)與(f) Cu (8 nm)之反射頻譜 40 圖4-6 Cu:Ag (1:60, 8 nm)之穿透頻譜 41 圖4-7 8 nm厚度下，不同比例Cu:Ag之反射頻譜 41 圖4-8不同Capping layer厚度下之銅銀電極的穿透頻譜與反射頻譜 42 圖4-9將Cu:Ag (1:60, 8 nm)/WO3 (20 nm)做成大面積並最做為導線驅動LED 43 圖4-10不同比例主動層元件之光電流特性曲線 44 圖4-11不同比例主動層元件的外部量子效率曲線圖 45 圖4-12不同厚度主動層元件的光電流特性曲線 46 圖4-13不同厚度主動層元件的外部量子效率曲線圖 47 圖4-14不同厚度主動層薄膜之穿透頻譜 48 圖4-15不同厚度之穿透電極元件的光電流特性曲線 49 圖4-16不同厚度之穿透電極元件的外部量子效率曲線圖 50 圖4-17穿透式有機太陽能電池之穿透頻譜與明視覺頻譜圖 51 圖4-18最佳化元件之穿透頻譜、反射頻譜、EQE與明視覺頻譜圖 52 圖4-19穿透式有機太陽能電池元件圖 52 圖4-20非穿透式串座元件的光電流特性曲線 53 圖4-21穿透式串座元件的光電流特性曲線 55 表目錄 表1-1 穿透式OPV文獻回顧 10 表4-1 不同比例主動層元件特性整理 44 表4-2不同厚度主動層元件特性整理 47 表4-3不同厚度之穿透電極元件特性整理 49 表4-4穿透式有機太陽能電池之光學特性 51 表4-5非穿透式串座元件特性之整理 54 表4-6穿透式串座元件特性之整理， 55

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